Substance key: Revision Date: 05/12/2015 Version : 2-1 / USA Date of printing :05/12/2015

Transcription

1 SILCARE SILICONE 41M15 Page 1 SECTION 1. IDENTIFICATION Identification of the company: Clariant Corporation 4000 Monroe Road Charlotte, NC, Telephone No.: Information of the substance/preparation: Product Safety Emergency tel. number: CHEMTREC Trade name: SILCARE SILICONE 41M15 Material number: CAS number: Primary product use: Chemical family: Raw material for cosmetics Caprylylmethylsiloxane SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR )., None under Title III of SARA SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact : Remove/Take off immediately all contaminated clothing. : Move the victim to fresh air. Give oxygen or artificial respiration if needed. Get immediate medical advice/ attention. Never give anything by mouth to an unconscious person. : Wash thoroughly with soap and water for 15 minutes. If skin irritation occurs, seek medical attention. : Rinse immediately with plenty of water, also under the eyelids,

2 SILCARE SILICONE 41M15 Page 2 for at least 15 minutes. Get medical attention immediately if irritation develops and persists. If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : Do NOT induce vomiting. Call a physician immediately. : The possible symptoms known are those derived from the labelling (see section 2). No additional symptoms are known. : None known. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Further information Special protective equipment for firefighters : Water spray jet Foam Carbon dioxide (CO2) Dry powder : High volume water jet : In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO) : Wear positive pressure self-contained breathing apparatus (SCBA) and full protective equipment. : Self-contained breathing apparatus SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Wear suitable protective equipment. Wear proper protective equipment. Contain spill. Spills should be collected as a liquid or absorbed on suitable absorbant and placed in proper containers for disposal. Do not discharge into storm drains or the aquatic environment. : Do not allow to enter drains or waterways : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). SECTION 7. HANDLING AND STORAGE Advice on protection against : Observe the general rules of industrial fire protection

3 SILCARE SILICONE 41M15 Page 3 fire and explosion Advice on safe handling Technical measures/precautions Materials to avoid : Provide good ventilation of working area (local exhaust ventilation if necessary). Avoid formation of aerosols. Keep container tightly closed in a cool, well-ventilated place. Keep container dry and in the original container. Store between 50 F and 77 F. : Store in original container. : Keep away from oxidizing agents. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Personal protective equipment Respiratory protection : If airborne concentrations pose a health hazard, become irritating or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29 CFR Hand protection Remarks Eye protection Skin and body protection Protective measures Hygiene measures : Butyl Rubber, PVC Or Neoprene. : Tightly fitting safety goggles : Protective clothing to minimize skin contact should be worn. Chemically resistant safety shoes. Wash contaminated clothing with soap and water and dry before reuse. Safety showers and eyewash stations should be provided in all areas where this material is handled. : Avoid contact with skin and eyes. Do not inhale aerosol. : Wash hands before breaks and at the end of workday. Use protective skin cream before handling the product. Take off immediately all contaminated clothing and wash it before reuse. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour : Liquid : colourless

4 SILCARE SILICONE 41M15 Page 4 Odour Odour Threshold ph : odourless : Not applicable Melting point : < -20 C Boiling point : 250 C (1,013 hpa) Flash point : > 107 C Evaporation rate Upper explosion limit Lower explosion limit Vapour pressure : < 0.1 mbar (20 C) Relative vapour density : > 1 Density : approx g/cm3 (20 C) Bulk density Solubility(ies) Water solubility : Not applicable : insoluble (20 C) Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature : soluble Solvent: fat : log Pow: 8.79 Decomposition temperature : C Viscosity Viscosity, dynamic Viscosity, kinematic Explosive properties Oxidizing properties : approx. 5 mpa.s : no data available : Not applicable

5 SILCARE SILICONE 41M15 Page 5 SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : No dangerous reaction known under conditions of normal use. : Stable under normal conditions. : Reactions with oxidising agents. : None known. : not known : When handled and stored appropriately, no dangerous decomposition products are known SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 423 : Remarks : Remarks Skin corrosion/irritation Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Serious eye damage/eye irritation Species: rabbit eye Result: No eye irritation Method: OECD Test Guideline 405 Respiratory or skin sensitisation Test Type: Buehler Test Species: Guinea pig Method: OECD Test Guideline 406 Result: non-sensitizing

6 SILCARE SILICONE 41M15 Page 6 Germ cell mutagenicity Germ cell mutagenicity - Assessment : Not mutagenic in Ames Test Carcinogenicity Carcinogenicity - Assessment IARC OSHA NTP : No information available. Not listed Not listed Not listed Reproductive toxicity Reproductive toxicity - Assessment : No information available. No information available. STOT - single exposure Remarks STOT - repeated exposure Remarks Repeated dose toxicity Remarks Experience with human exposure General Information : The possible symptoms known are those derived from the labelling (see section 2). Further information Remarks: The product can be toxic by inhalation in aerosol form. Avoid completely inhalation of spray mist.

7 SILCARE SILICONE 41M15 Page 7 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : Remarks Toxicity to algae : Remarks Toxicity to bacteria : Remarks Persistence and degradability Biodegradability : Biodegradation: < 30 % Exposure time: 28 d Method: OECD Test Guideline 301B Bioaccumulative potential Bioaccumulation : Remarks Mobility in soil Distribution among environmental compartments : Remarks Other adverse effects Environmental fate and pathways Results of PBT and vpvb assessment Additional ecological information : Remarks: no data available : Remarks: no data available : no data available

8 SILCARE SILICONE 41M15 Page 8 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods RCRA - Resource Conservation and Recovery Authorization Act Waste from residues Contaminated packaging : No -- Not as sold. : Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. : Packaging that cannot be cleaned should be disposed of as product waste SECTION 14. TRANSPORT INFORMATION DOT IATA IMDG not restricted not restricted not restricted SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards SARA 302 SARA 313 : No SARA Hazards : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This product does not contain any toxic chemical listed under Section 313 of the Emergency Planning and Community Right-To-Know Act of Clean Water Act Contains no known priority pollutants at concentrations greater than 0.1%. The components of this product are reported in the following inventories: TSCA : This product is not listed on the TSCA Inventory. It is to be used as a cosmetic ingredient only. Any other use will subject the user to penalties under the Toxic Substances Control Act and the regulations issued thereunder.

9 SILCARE SILICONE 41M15 Page 9 Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: Flammability 1 Health 1 0 Instability Special hazard. Observe national and local legal requirements Warning This product is not listed on the TSCA Inventory. It is to be used as a cosmetic ingredient only. Any other use will subject the user to penalties under the Toxic Substances Control Act and the regulations issued thereunder. Avoid inhalation of vapour or mist. Revision Date : 05/12/2015 This information is supplied under the OSHA Hazard Communication Standard, 29 CFR , and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume no responsibility for damage or injury from the use of the product described herein. Data provided here are typical and not intended for use as product specifications. US / USA