MATERIAL SAFETY DATA SHEET

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1 Page: 1 Compilation date: 01/11/2010 Revision date: 17/01/2011 Revision No: 14 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: Product code: R , R Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Company name: Orbeco-Hellige, Inc Parkland Drive Sarasota Florida United States Tel: (941) Emergency telephone number Emergency tel: (703) Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CHIP: Xi: R36/38 Classification under CLP: Eye Irrit. 2: H319; Skin Irrit. 2: H315 Most important adverse effects: Irritating to eyes and skin Label elements Label elements under CLP: Hazard statements: Signal words: Hazard pictograms: H315: Causes skin irritation. H319: Causes serious eye irritation. Warning GHS07: Exclamation mark Precautionary statements: P280: Wear protective gloves/protective clothing/eye protection/face protection. P : If eye irritation persists: Get medical advice/attention.

2 Label elements under CHIP: Hazard symbols: MATERIAL SAFETY DATA SHEET P : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P : If skin irritation occurs: Get medical advice/attention. Irritant. Page: 2 Risk phrases: Safety phrases: 2.3. Other hazards PBT: R36/38: Irritating to eyes and skin. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39: Wear suitable protective clothing, gloves and eye / face protection. This substance is not identified as a PBT substance. Section 3: Composition/information on ingredients 3.2. Mixtures Hazardous ingredients: ACETIC ACID EINECS CAS CHIP Classification CLP Classification Percent : R10; C: R35 Flam. Liq. 3: H226; Skin Corr. 1A: H % Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Consult a doctor. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor Most important symptoms and effects, both acute and delayed Skin contact: Eye contact: Ingestion: Inhalation: Delayed / immediate effects: There may be irritation and redness at the site of contact. There may be irritation and redness. The eyes may water profusely. There may be soreness and redness of the mouth and throat. There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Immediate effects can be expected after short-term exposure.

3 Page: Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Eye bathing equipment should be available on the premises. Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers Special hazards arising from the substance or mixture Exposure hazards: 5.3. Advice for fire-fighters Advice for fire-fighters: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Sodium Oxides. Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: 6.2. Environmental precautions Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding Methods and material for containment and cleaning up Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method Reference to other sections Reference to other sections: Refer to section 8 of SDS. Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air Conditions for safe storage, including any incompatibilities Storage conditions: Suitable packaging: Store in cool, well ventilated area. Keep container tightly closed. Must only be kept in original packaging.

4 Page: Specific end use(s) Specific end use(s): Section 8: Exposure controls/personal protection 8.1. Control parameters Hazardous ingredients: ACETIC ACID...100% Workplace exposure limits: Respirable dust 8 hour TWA: 15 min. STEL: 8 hour TWA: 15 min. STEL: UK 25 mg/m3 37 mg/m Exposure controls Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: Environmental: Ensure there is sufficient ventilation of the area. Self-contained breathing apparatus must be available in case of emergency. Protective gloves (EN374). Safety glasses (EN166). Ensure eye bath is to hand. Protective clothing. Refer to specific Member State legislation for requirements under Community environmental legislation. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Liquid Colour: Colourless Odour: Vinegar. Solubility in water: Miscible Viscosity: Non-viscous Boiling point/range C: >35 Flash point C: >93 ph: Other information Section 10: Stability and reactivity Reactivity Chemical stability Reactivity: Chemical stability: Stable under recommended transport or storage conditions. Stable under normal conditions.

5 Page: Possibility of hazardous reactions Hazardous reactions: Conditions to avoid Conditions to avoid: Incompatible materials Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below. Heat. Materials to avoid: Strong bases Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Sodium Oxides. Section 11: Toxicological information Information on toxicological effects Relevant effects for mixture: Effect Route Basis Irritation OPT DRM Hazardous: calculated Symptoms / routes of exposure Skin contact: Eye contact: Ingestion: Inhalation: Delayed / immediate effects: There may be irritation and redness at the site of contact. There may be irritation and redness. The eyes may water profusely. There may be soreness and redness of the mouth and throat. There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Immediate effects can be expected after short-term exposure. Section 12: Ecological information Toxicity Persistence and degradability Persistence and degradability: Bioaccumulative potential Bioaccumulative potential: Mobility in soil Mobility:

6 Page: Results of PBT and vpvb assessment PBT identification: Other adverse effects Other adverse effects: This substance is not identified as a PBT substance. Section 13: Disposal considerations Waste treatment methods Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company. Recovery operations: Not applicable. Waste code number: Disposal of packaging: Arrange for collection by specialised disposal company. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. Section 14: Transport information UN number UN number: UN proper shipping name Shipping name: Transport hazard class(es) UN2790 ACETIC ACID, SOLUTION Packing group Transport class: 8 Packing group: Environmental hazards III Environmentally hazardous: No Marine pollutant: No Special precautions for user Special precautions: No special precautions. Tunnel code: E Transport category: 3 Section 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture

7 Page: Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. Section 16: Other information Other information Other information: Phrases used in s.2 and 3: Legal disclaimer: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * indicates text in the SDS which has changed since the last revision. H226: Flammable liquid and vapour. H314: Causes severe skin burns and eye damage. H315: Causes skin irritation. H319: Causes serious eye irritation. R10: Flammable. R35: Causes severe burns. R36/38: Irritating to eyes and skin. Alteration to this document is strictly prohibited. The format and formulas contained within this document comply with UK laws and legislation. Every effort has been made to ensure that the information in this MSDS is accurate. However some labels printed before the date on this document may have conflicting hazard information that can be disregarded in favour of the information as detaile above. [final page]

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