EG-Safety Data Sheet 1907/2006EG (Reach)

Transcription

1 1 Substance/preparation and company name - Trading name - specified use cooling- and antifreeze fluid for welding machines - Company Conzelmann Schweißhandelsgesellschaft mbh von Roggensteinstr Kammeltal-Wettenhausen Tel. 0049(0)(8223) Fax 0049(0)(8223) Contact techn. Inf. do. - Emergency poison emergency number Berlin 030/ Hazard indentifications Description of risks: The product does not meet the classification criteria Irritant and Harmful under Directive 1999/45/EG Because of its content of hazardous substances are, however, certain effects is possible. Special indications of danger for humans and the environment: R10 Flammable. Product itself does not burn at room temperature. Can temperature increase at explosive vapor-air mixtures. When temperature rise is also disintegrate the vessels. In case of fire, possible formation of toxic gases (carbon Monoxide). 3 Composition/information on ingredients Chemical composition Description: 1.2-Ethanediol, 1-propanol, deionized water, inhibitor, <1% Dangerous incredients EG-Nr. CAS-Nr. Bezeichnung Anteil Gew. % Symbol R-Sätze ,2-Ethanediol < 25 Xn propanol < 15 F/Xi 11, 41, 67 4 First aid measures General advice: Remove contaminated clothing Inhalation: Remove to fresh air injured when complaints doctor. Skin Contact: Wash with soap and water, crème skin. After eye contact: with plenty of water for several minutes with open eyelid rinse under running water, with persistent symptoms consult doctor. Ingestion: Rinse mouth and spit out drink plenty of water. Immediate medical attention. 5 Fire fighting measures Adapted extinguishing agent: CO², extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. unsuitable extinguishing agent: Water jet Special hazards caused by the substance, the preparation itself, combustion products or resulting gases: Seite 1 von 6

2 Product itself does not burn at room temperature. Can temperature increase at explosive vapor-air mixtures. When temperature rise is also disintegrate the vessels. In case of fire, possible formation of toxic gases (carbon Monoxide) Special protective equipment: Independent of ambient air breathing apparatus. Additional Information: Collect contaminated fire fighting water separately. 6 Accidental release measures People related precautions: Do not inhale steams. Avoid skin and eye contact. Keep away ignition sources. Environmental Protection Measures: Collect contaminated fire water separately. Do not allow to enter drainage system, surface or ground water. Procedure for cleaning / absorption: Absorb leaked material with liquid-binding material (sand, diatomite, acid binders, universal binder, sawdust). Provide sufficient ventilation. 7 Handling and storage Handling Information on save handling: Provide for good ventilation, exhaust on the job. Do not inhale steams. Avoid skin and eye contact. Observe the AGW of values/(s) and/or other limit values. Information on fire and explosion protection: Steams can form a combustible mixture with air. In the emptied bundles, explosive mixtures can form. Keep away ignition sources. - Do not smoke -. Storage Requirements on storage rooms and containers: Consider legal regulations related to water. Consider regulations for the storage of combustible liquids. Information on joint storage: Consider regulations for the storage of combustible liquids. Further information on storage conditions: Keep containers tightly closed. Protect against heat and direct sun exposure. Keep containers at a well-ventilated place. Storage class: Classification acc. to plant safety regulation (BetrSichV): inflammable VbF-Class: Not applicable. Additional information about design of technical systems: Measures against electrostatic charges take 8 Exposure controls and personal protection AGW ,2-Ethanediol 26 mg/m³ 10 ml/m³ AGW propanol f. TRGS 900 not defined Additional remarks: Basis were the lists valid at the time of preparation. Seite 2 von 6

3 Personal protective equipment General protective and hygienic measures: Wash hand with water and soap after work or before breaks. Do not inhale gases, steams, aerosols. Respiratory protection: Normally, in case of continuously reliable observation of the AGE value, other limitation values and with sufficient ventilation no special measures have to be taken. Do not inhale aerosols wear breathing protection, if necessary. Hand protection: Safety gloves. The glove material has to be impermeable and resistant against the material prepared. As corresponding test results are not available, no recommendation can be given regarding the glove material for the preparation of the product. Selection of the glove material in consideration of the fabric cells, penetration rates and degradation. Glove material: The choice of suitable gloves is not only depending on the material but also on further quality features and varies from manufacturer to manufacturer. As the product is a preparation out of several substances, the resistance of glove material cannot be anticipated and has there for be tested prior to use. Penetration time of the glove material: The exact penetration time has to be inquired at the manufacturer of the gloves and has to be observed. Eye protection: Tightly closing protective glasses. 9 Physical and chemical properties Shape: fluid Colour: colourless Smell: alcohol like Change of state Valvue(s) Tested acc. To Melting point: <-15 C (breaking effect only below about C) Boiling point/boiling range: Approx C Flashpoint: Approx 42 C DIN51755 Ignitation temperature: 400 C Self-in flammability: Product is not self-inflammable Risk of explosion: Product is not explosive, however the formation combustible steam, air mixtures is possible Explosion limit lower: upper: Vapeur pressure (20 C): 20 hpa (mbar) Density (20 C): 0,9847 g/cm³ calculated Solubility in / miscibility with Solubility (20 C): Completely mixable ph-value (20 C): 9,0-10,0 Electrical conductance (25 C): µs/cm 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No use in properly. Avoid high temperatures Dangerous reaction: Strong oxidizers, alkali metals with hydrogen, acids Seite 3 von 6

4 Dangerous decomposition products: No use in properly. In case of fire, carbon monoxide Seite 4 von 6

5 11 Toxicological data Acute toxicity: not available, oral LD 50 values (rat) relative to the concentrates of the raw materials 1.2 Ethanediol mg / kg, 1-propanol 8000 mg / kg Primary irritation: Of the skin: Continuous and/or repeated skin contact can lead to skin irritations Of the eyes: Short, reversible irritation. Sensitization: No sensitizing effect known. Additional toxicological indications: Inhaling of concentrated steams can lead to narcose-similar conditions and to headache, swindles, etc. 12 Ecological information General information: Water hazard class (WGK): Readily biodegradable 1 Self-assessment Vulnerability to water 13 Disposal considerations Product: Waste key number.: Disposal reference: Waste key number: Uncleaned packing: Well with water Recommendation: exact key with the Waste Disposal deny Disposal according to official regulations plastics Recommended cleaning agent: Water 14 Transport information Not dangerous goods according to ADR/RID, IMDG-Code:, IATA (Flash point> 35 C, the product has no self-combustion, see ADR Bem.1 15 Regulatory information Labelling acc. to EEC guidelines: Marking according to EC-guidelines/Regulation for Hazardous Goods. R- clauses: R10 inflammable S- clauses: S2 Keep out of the reach of children S16 Ignition sources keep away - do not smoke - National Regulations: Classification acc. to VbF: inflammable Water hazard class: weakly water-endangering 16 Further information Seite 5 von 6

6 The above information is correct at the present state of our knowledge and do not constitute property assurances in the legal sense dar. Legislation are on their own responsibility to consider. The Company is not responsible for any Damage resulting from handling or contact with the above product are be held responsible. Seite 6 von 6