Material Safety Data Sheet Lithium nitrate. Section 1 - Chemical Product and Company Identification

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1 ISO9001:2000 Certified Material Safety Data Sheet Section 1 - Chemical Product and Company Identification MSDS Name: Lithium Nitrate Catalog Numbers: LC16250 Synonyms: Nitric acid, lithium salt. Company Identification: LabChem Inc 200 William Pitt Way Pittsburgh, PA Company Phone Number: (412) Emergency Phone Number: (800) CHEMTREC Phone Number: (800) Section 2 Composition, Information on Ingredients CAS# Chemical Name: Percent Section 3 - Hazards Identification Emergency Overview Appearance: White solid. Danger! Strong oxidizer. Contact with other material may cause a fire. Causes eye, skin, and respiratory tract irritation. May cause central nervous system effects. May cause cardiac disturbances. May cause kidney damage. May cause methemoglobinemia. Hygroscopic (absorbs moisture from the air). Target Organs: Blood, kidneys, central nervous system, cardiovascular system. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause muscle tremor and impaired motor function. May cause circulatory system failure. May cause cardiac disturbances. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient - 1 -

2 oxygenation of the blood), rapid heart rate and chocolate-brown colored blood. May cause tremors and convulsions. Inhalation: Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, tachycardia, dyspnea (labored breathing), and death. Chronic: Chronic ingestion may cause dizziness, ringing in the ears, visual disturbances, tremors, and mental confusion. Prolonged absorption may affect electrolyte balance and impair kidney function. Dehydration, weight loss, skin effects, and thyroid disturbances have been reported. Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Extinguishing Media: Use water only! Do NOT use carbon dioxide. Do NOT use dry chemical. Autoignition Temperature: Not available. Flash Point: Not available. NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 1; Special Hazard: OX Explosion Limits: Lower: n/a Upper: n/a - 2 -

3 Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. Keep combustibles (wood, paper, oil, etc.,) away from spilled material. Section 7 - Handling and Storage Handling: Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not ingest or inhale. Keep from contact with clothing and other combustible materials. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits: Chemical Name: ACGIH NIOSH OSHA none listed none listed none listed OSHA Vacated PELs: : No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced

4 Section 9 - Physical and Chemical Properties Physical State: Solid Color: White Odor: Not available ph: Not available Vapor Pressure: Not available Vapor Density: 2.4 Evaporation Rate: Not available Viscosity: Not available Boiling Point: 760 mmhg Freezing/Melting Point: 251ºC Decomposition Temperature: > 600ºC Solubility in water: 90 g/l (28 C) Specific Gravity/Density: g/cm3 Molecular Formula: LiNO3 Molecular Weight: Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Dust generation, moisture. Incompatibilities with Other Materials: Combustible materials. Hazardous Decomposition Products: Nitrogen oxides, lithium oxide. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS: CAS# unlisted. LD50/LC50: Not available. Carcinogenicity: CAS# : Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: Teratogenicity: Reproductive: Mutagenicity: - 4 -

5 Neurotoxicity: Section 12 - Ecological Information Section 13 - Disposal Considerations Dispose of in accordance with Federal, State, and local regulations. Section 14 - Transport Information US DOT Shipping Name: Hazard Class: 5.1 UN Number: UN2722 Packing Group: III Section 15 - Regulatory Information US Federal TSCA: CAS# is listed on the TSCA inventory. SARA Reportable Quantities (RQ): None of the chemicals in this material have an RQ. CERCLA/SARA Section 313: This material contains (listed as Water Dissociable Nitrate Compounds), 100%, (CAS# ) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. OSHA - Highly Hazardous: None of the chemicals in this product are considered highly hazardous by OSHA. US State State Right to Know: CAS# can be found on the following state right to know lists: New Jersey. California Regulations: None. European/International Regulations Canadian DSL/NDSL: CAS# is listed on Canada's DSL List. Canada Ingredient Disclosure List: CAS# is not listed on the Canadian Ingredient Disclosure List

6 Section 16 - Other Information MSDS Creation Date: November 13, 2007 Revision Date: December 11, 2007 Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application

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