SAFETY DATA SHEET. Revision Date 08-Dec-2014 Revision Number Identification. No information available.;

Transcription

1 SAFETY DATA SHEET Revision Number 1 1. Identification Product Name Malachite Green 5% Cat No. : Synonyms Recommended Use R40023.; Laboratory chemicals. Uses advised against No Information available Details of the supplier of the safety data sheet Company Remel Santa Fe Drive Lenexa, KS United States Telephone: Fax: Emergency Telephone Number INFOTRAC - 24 Hour Number: Outside of the United States, call 24 Hour Number: (Call Collect) 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Acute oral toxicity Category 4 Serious Eye Damage/Eye Irritation Category 1 Reproductive Toxicity Category 2 Label Elements Signal Word Danger Hazard Statements Harmful if swallowed Causes serious eye damage Suspected of damaging fertility or the unborn child Precautionary Statements Page 1 / 7

2 Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Response IF exposed or concerned: Get medical attention/advice Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Storage Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Toxic to aquatic life with long lasting effects 3. Composition / information on ingredients Component CAS-No Weight % Ammonium, (4-(p-(dimethylamino)-.alpha.-phenylbenzylidene)-2, 5-cyclohexadien-1-ylidene)- dimethyl-, oxalate (2:1), oxalate (1:1) First-aid measures General Advice Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention. Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention. Clean mouth with water and drink afterwards plenty of water. Breathing difficulties. Causes eye burns. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting Treat symptomatically 5. Fire-fighting measures Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Flash Point C / F Method - Autoignition Temperature Explosion Limits Upper Page 2 / 7

3 Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical. Non-combustible. Flammable. Hazardous Combustion Products Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. Should not be released into the environment. Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Up Handling Storage Exposure Guidelines 7. Handling and storage Ensure adequate ventilation. Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Keep containers tightly closed in a dry, cool and well-ventilated place. 8. Exposure controls / personal protection Engineering Measures Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Tightly fitting safety goggles. Face-shield. Long sleeved clothing. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Liquid Appearance Dark green Odor Odor Threshold ph 5-7 Melting Point/Range Boiling Point/Range C / F Flash Point C / F Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Page 3 / 7

4 Lower Vapor Pressure Vapor Density Relative Density Solubility Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity 10. Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials, based on information available Stable under normal conditions. Incompatible products. Excess heat. Hazardous Decomposition Products Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Oral LD50 Category 4. ATE = mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Vapor LC50 Based on ATE data, the classification criteria are not met. ATE > 20 mg/l. Component Information Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity Irritating to eyes, respiratory system and skin The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Ammonium, (4-(p-(dimethylamino)-. alpha.-phenylbenzylide ne)-2,5-cyclohexadien- 1-ylidene)- dimethyl-, oxalate (2:1), oxalate (1:1) Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure... Page 4 / 7

5 STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation The toxicological properties have not been fully investigated. 12. Ecological information. Mobility. Waste Disposal Methods DOT TDG IATA IMDG/IMO 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information 15. Regulatory information All of the components in the product are on the following Inventory lists: X = listed International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Ammonium, - X X X X X X (4-(p-(dimethylamino)-.alpha. -phenylbenzylidene)-2,5-cycl ohexadien-1-ylidene)- dimethyl-, oxalate (2:1), oxalate (1:1) Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. Page 5 / 7

6 U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes No No No Clean Water Act Clean Air Act OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 State Right-to-Know This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Moderate risk, Grade 2 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class D2B Toxic materials D1B Toxic materials E Corrosive material Prepared By 16. Other information Regulatory Affairs Remel Tel: Page 6 / 7

7 Revision Date Print Date Revision Summary 08-Dec Dec-2014 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 7 / 7