PURITY TM/MC FG SILICONE SPRAY

Transcription

1 PURITY /MC FG SILICONE SPRAY SECTION 1. IDENTIFICATION Product name : PURITY /MC FG SILICONE SPRAY Product code : PFSI, PFSIB12 Manufacturer or supplier's details Petro-Canada Lubricants 2310 Lakeshore Road West Mississauga ON L5J 1K2 Canada Emergency telephone number Petro-Canada Lubricants : ; CHEMTREC Transport Emergency: ; Poison Control Centre: Consult local telephone directory for emergency number(s). Recommended use of the chemical and restrictions on use Recommended use : Aerosol spray lubricant. NSF H1 Registered. All components comply with FDA 21 CFR "Lubricants with Incidental Food Contact". It is intended for application on industrial and food equipment. It should not be added directly to the food product. Prepared by : Product Safety: SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour aerosol Clear, water-white Mild Petroleum/Solvent GHS Classification Flammable aerosols : Category 1 Skin irritation : Category 2 Reproductive toxicity : Category 2 Specific target organ toxicity - single exposure : Category 3 (Central nervous system) Specific target organ toxicity : Category 2 Internet: lubricants.petro-canada.com/sds Page: 1 / 11

2 PURITY /MC FG SILICONE SPRAY - repeated exposure GHS label elements Hazard pictograms : Signal word Hazard statements Precautionary statements : Danger : Extremely flammable aerosol. Causes skin irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. IF exposed or concerned: Get medical advice/ attention. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash it before reuse. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Disposal: Dispose of contents/ container to an approved waste disposal plant. Potential Health Effects Primary Routes of Entry Aggravated Medical Condition : Eye contact Inhalation Skin contact : None known. Internet: lubricants.petro-canada.com/sds Page: 2 / 11

3 PURITY /MC FG SILICONE SPRAY Other hazards None known. IARC ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration naphtha (petroleum), hydrotreated light % 1,1-difluoroethane % 2-methylpentane % Siloxane, dimethyl % n-hexane < 3 % 2,2-dimethylbutane < 0.2 % SECTION 4. FIRST AID MEASURES If inhaled In case of skin contact In case of eye contact : Move to fresh air. Artificial respiration and/or oxygen may be necessary. Seek medical advice. : In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash contaminated clothing before reuse. Seek medical advice. : Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Internet: lubricants.petro-canada.com/sds Page: 3 / 11 If swallowed : Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice.

4 PURITY /MC FG SILICONE SPRAY Most important symptoms and effects, both acute and delayed : First aider needs to protect himself. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Further information Special protective equipment for firefighters : Dry chemical Carbon dioxide (CO2) Water spray Water fog. Foam Sand : Do NOT use water jet. : If the product release cannot be shut off safely, allow the product to burn itself out. Cool closed containers exposed to fire with water spray. : Carbon oxides (CO, CO2), smoke and irritating vapours as products of incomplete combustion. : Prevent fire extinguishing water from contaminating surface water or the ground water system. : Wear self-contained breathing apparatus and full protective wear. Wear a positive-pressure supplied-air respirator with full facepiece. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Remove all sources of ignition. : If the product contaminates rivers and lakes or drains inform respective authorities. Do not allow uncontrolled discharge of product into the environment. Ensure adequate ventilation. Internet: lubricants.petro-canada.com/sds Page: 4 / 11 Methods and materials for containment and cleaning up : Remove all sources of ignition. Non-sparking tools should be used. Use explosion-proof ventilation equipment. Prevent entry into basements or confined areas. Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material.

5 PURITY /MC FG SILICONE SPRAY Contact the proper local authorities. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Do not ingest. Do not swallow. Avoid contact with skin, eyes and clothing. Use only with adequate ventilation. Do not breathe vapours or spray mist. Keep away from heat and sources of ignition. Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. Take measures to prevent the build up of electrostatic charge. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration 2-methylpentane TWA 500 ppm 1,760 mg/m3 STEL 1,000 ppm 3,500 mg/m3 Basis CA AB OEL CA AB OEL TWA 500 ppm ACGIH STEL 1,000 ppm ACGIH TWA 500 ppm ACGIH STEL 1,000 ppm ACGIH n-hexane TWA 50 ppm CA AB OEL 176 mg/m3 TWA 20 ppm CA BC OEL TWAEV 50 ppm CA QC OEL 176 mg/m3 TWA 50 ppm ACGIH Engineering measures : Adequate ventilation to ensure that Occupational Exposure Limits are not exceeded. Use explosion-proof ventilation equipment. Internet: lubricants.petro-canada.com/sds Page: 5 / 11 Personal protective equipment

6 PURITY /MC FG SILICONE SPRAY Respiratory protection Filter type Hand protection Material : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : organic vapour filter : neoprene, nitrile, polyvinyl chloride (PVC), Viton(R). Remarks Eye protection Skin and body protection Protective measures Hygiene measures : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Safety glasses with side-shields Safety goggles : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. : Wash contaminated clothing before re-use. : Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold ph Melting point Initial boiling point and boiling range Flash point Fire Point Auto-Ignition Temperature : aerosol : Clear, water-white : Mild Petroleum/Solvent : : : : estimated 48 C (118 F) : C (-0.0 F) Method: Tag closed cup : : estimated 254 C (489 F) Internet: lubricants.petro-canada.com/sds Page: 6 / 11

7 PURITY /MC FG SILICONE SPRAY Evaporation rate Flammability Upper explosion limit Lower explosion limit : : Extremely flammable aerosol. Extremely flammable in presence of open flames, sparks, and heat. Vapours are heavier than air and may travel considerable distance to sources of ignition and flash back. : estimated 9.5 %(V) : estimated 1.8 %(V) Vapour pressure : estimated 3,083.3 hpa Relative vapour density : Relative density : estimated 0.81 Density Solubility(ies) Water solubility Partition coefficient: n- octanol/water Viscosity Viscosity, kinematic Explosive properties : : insoluble : : : Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Container explosion may occur under fire conditions or when heated. Ruptured cylinders may rocket. SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Hazardous polymerisation does not occur. Stable under normal conditions. : Heat, flames and sparks. : Reactive with oxidising agents. : May release COx, smoke and irritating vapours when heated to decomposition. SECTION 11. TOXICOLOGICAL INFORMATION Internet: lubricants.petro-canada.com/sds Page: 7 / 11 Information on likely routes of exposure Eye contact Inhalation Skin contact

8 PURITY /MC FG SILICONE SPRAY Acute toxicity Product: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : Remarks: : Remarks: : Remarks: Components: 1,1-difluoroethane: Acute inhalation toxicity n-hexane: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : LC50 (Rat): ppm Exposure time: 4 h Test atmosphere: gas : LD50 (Rat): 15,840 mg/kg, : LC50 (Rat): ppm Exposure time: 4 h Test atmosphere: dust/mist : LD50 (Rabbit): > 3,295 mg/kg, Skin corrosion/irritation Product: Remarks: Internet: lubricants.petro-canada.com/sds Page: 8 / 11 Serious eye damage/eye irritation Product: Remarks: Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure

9 PURITY /MC FG SILICONE SPRAY SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : Remarks: Toxicity to daphnia and other aquatic invertebrates : Remarks: Toxicity to algae : Remarks: Toxicity to bacteria : Remarks: Components: n-hexane : Toxicity to fish Toxicity to daphnia and other aquatic invertebrates : LC50 (Fish): 4.12 mg/l Exposure time: 96 h : EC50 (Daphnia (water flea)): 3.87 mg/l Exposure time: 48 h Persistence and degradability Product: Biodegradability : Remarks: Bioaccumulative potential Mobility in soil Other adverse effects SECTION 13. DISPOSAL CONSIDERATIONS Internet: lubricants.petro-canada.com/sds Page: 9 / 11 Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Offer surplus and non-recyclable solutions to a licensed disposal company. Waste must be classified and labelled prior to recycling or disposal. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and

10 PURITY /MC FG SILICONE SPRAY national regulations. Dispose of product residue in accordance with the instructions of the person responsible for waste disposal. SECTION 14. TRANSPORT INFORMATION International Regulations IATA-DGR UN/ID No. : UN 1950 Proper shipping name : Aerosols, flammable Class : 2.1 Packing group : Not assigned by regulation Labels : Class 2 - Gases: Flammable (Division 2.1) Packing instruction (cargo : 203 aircraft) IMDG-Code UN number : UN 1950 Proper shipping name : AEROSOLS LIMITED QUANTITY Class : 2.1 Packing group : Not assigned by regulation Labels : 2.1 EmS Code : F-D, S-U Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code National Regulations TDG UN number : UN 1950 Proper shipping name : AEROSOLS LTD. QTY. Class : 2.1 Packing group : Not assigned by regulation Labels : 2.1 ERG Code : 126 Marine pollutant : no SECTION 15. REGULATORY INFORMATION Internet: lubricants.petro-canada.com/sds Page: 10 / 11 This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. The components of this product are reported in the following inventories: DSL TSCA IECSC On the inventory, or in compliance with the inventory On TSCA Inventory On the inventory, or in compliance with the inventory

11 PURITY /MC FG SILICONE SPRAY EINECS On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION For Copy of SDS : Internet: lubricants.petro-canada.com/sds Western Canada, telephone: ; fax: Ontario & Central Canada, telephone: ; fax: Quebec & Eastern Canada, telephone: ; fax: For Product Safety Information: Prepared by : Product Safety: Revision Date : 2017/03/06 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Internet: lubricants.petro-canada.com/sds Page: 11 / 11