PARVOCLEAR SAFETY DATA SHEET

Transcription

1 SAFETY DATA SHEET OSHA HCS (29 CFR ) & UN GHS Classification SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product identifier Chemical Name Trade Name CAS No. Not applicable. PARVOCLEAR Mixture Relevant identified uses of the substance or mixture and uses advised against Identified Use(s) Veterinary Use Uses Advised Against. Details of the supplier of the safety data sheet Company Identification Blending Technologies, llc 2880 North Star Road Columbus, OH Telephone +1 (614) (competent person) Emergency telephone number Emergency Phone No. +1 (614) ; 8:00 AM - 5:00 PM (EST); Not classified as dangerous for transport. SECTION 2: HAZARDS IDENTIFICATION Classification of the substance or mixture OSHA HCS (29 CFR ) / GHS Classification Skin Irrit. 2, Eye Dam. 1 Label elements Hazard Symbol Signal Word(s) Hazard Statement(s) Precautionary Statement(s) Other hazards DANGER H315: Causes skin irritation. H318: Causes serious eye damage. P280: Wear protective eyewear (goggles, face shield, or safety glasses). P264: Wash (hands and exposed skin) thoroughly after handling. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P332+P313: If skin irritation occurs: Get medical advice/attention. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical attention. H401: Toxic to aquatic life. H411: Toxic to aquatic life with long lasting effects. Revision: 10 May 2016 Page: 1/6

2 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredient(s) %W/W CAS No. Hazard Statement(s) Alkyl dimethyl benzyl ammonium chloride (C12-18) Alkyl dimethyl ethyl benzyl ammonium chloride (C12-14) < < Ethanol < Harmful if swallowed. Harmful in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Highly flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Other Substances in the product which may present a health or environmental hazard, or which have been assigned occupational exposure limits, are detailed below.: Additional Information - SECTION 4: FIRST AID MEASURES Description of first aid measures Inhalation Skin Contact Eye Contact Ingestion Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed Remove person to fresh air and keep comfortable for breathing. If breathing is laboured, administer oxygen. If symptoms develop, obtain medical attention. Wash affected skin with soap and water. If irritation (redness, rash, blistering) develops, get medical attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. Do not give anything by mouth to an unconscious person. Do not induce vomiting. Get immediate medical attention. Causes skin irritation. Causes serious eye irritation. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media -Suitable Extinguishing Media -Unsuitable Extinguishing Media Special hazards arising from the substance or mixture Advice for fire-fighters Non-combustible. As appropriate for surrounding fire. anticipated. Fire fighters should wear complete protective clothing including self-contained breathing apparatus. Revision: 10 May 2016 Page: 2/6

3 SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up Reference to other sections Additional Information Avoid contact with skin and eyes. Wear protective gloves/eye protection/face protection. Avoid breathing mist/vapours/spray. Prevent substance entering sewers. Contain and cover spilled substance with dry sand or earth or other suitable dry material. Transfer to a container for disposal or recovery. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Wear protective gloves/eye protection/face protection. Avoid breathing mist/vapours/spray. Conditions for safe storage, including any incompatibilities -Storage temperature Store at room temperature. -Incompatible materials Specific end use(s) Veterinary Use SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Occupational Exposure Limits (8hr TWA) (STEL) SUBSTANCE. CAS No. OSHA (PEL) TLV (ACGIH) OSHA (PEL) TLV (ACGIH) Note: Ethanol ppm ppm Recommended monitoring method NIOSH 1400 (Alcohols I) Exposure controls Appropriate engineering controls Personal protection equipment Eye/face protection Use only with adequate ventilation to keep exposures (airborne levels of dust, fume, vapor etc) below recommended exposure limits. Wear protective eye glasses for protection against liquid splashes. Skin protection (Hand protection/ Other) Gloves (PVC, Neoprene, or Natural rubber). Respiratory protection Not normally required. Thermal hazards Not normally required. Revision: 10 May 2016 Page: 3/6

4 Environmental Exposure Controls Avoid release to the environment. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Liquid Color. Clear, colourless to straw coloured. Odor Slight Odor Threshold (ppm) ph (Value) Melting Point ( C) / Freezing Point ( C) ~0 (32 F) Boiling point/boiling range ( C): ~100 (212 F) Flash Point ( C) Non-combustible Evaporation Rate ~ that of water Flammability (solid, gas) Not applicable Explosive Limit Ranges Not applicable Vapor Pressure (mm Hg) ~ that of water Vapor Density (Air=1) ~ that of water Density (g/ml) 1.06 Solubility (Water) Soluble Solubility (Other) Not known Partition Coefficient (n-octanol/water) Auto Ignition Point ( C) Non-combustible Decomposition Temperature ( C) Kinematic Viscosity 40 C Explosive properties Not explosive. Oxidizing properties Not oxidizing. Other information SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition product(s) Stable under normal conditions. Stable. anticipated. known Carbon monoxide, Carbon dioxide, Other SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes: Inhalation, Skin Contact, Eye Contact Information on toxicological effects Alkyl dimethyl benzyl ammonium chlorides (CAS No & ): Acute toxicity (calculated / estimated) Oral LD50 = 30.4 mg/kg Dermal LD50 = 930 mg/kg Inhalation LC50 = mg/l (4-hr.) Irritation / Corrosivity Causes severe skin burns and eye damage. Concentrations <10% are not corrosive to skin. Sensitization Repeated dose toxicity It is not a skin sensitiser. Not to be expected Revision: 10 May 2016 Page: 4/6

5 Carcinogenicity Mutagenicity It is unlikely to present a carcinogenic hazard to man. NTP IARC ACGIH OSHA No. No. No. No. Toxicity for reproduction Other information Not to be expected Not to be expected known. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Alkyl dimethyl benzyl ammonium chlorides (CAS No & ): Acute toxicity (calculated / estimated) Long Term Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects LC50 (96 hour): mg/l (Fish) EC50 (48 hour): mg/l (crustacea) LOAEC (34 day): mg/l (Fish) LOAEC (21 day): mg/l (crustacea) Biodegradable The product has no potential for bioaccumulation. The product has low mobility in soil. Not classified as PBT or vpvb. known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Additional Information Disposal should be in accordance with local, state or national legislation. Consult an accredited waste disposal contractor or the local authority for advice. known. SECTION 14: TRANSPORT INFORMATION Land transport (U.S. DOT) Sea transport (IMDG) Air transport (ICAO/IATA) UN number UN 3082 UN 3082 Proper Shipping Name Not regulated for ground shipments in the U.S. in non-bulk packaging (<119 gallons). Environmentally hazardous substance, liquid, n.o.s. (contains Alkyl benzyl ammonium chlorides) Environmentally hazardous substance, liquid, n.o.s. (contains Alkyl benzyl ammonium chlorides) Transport hazard class(es) Packing group III III Hazard label(s) Marine Pollutant Marine Pollutant Environmental hazards Yes Yes Special precautions for user Assigned Assigned Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: TSCA (Toxic Substance Control Act) - Inventory Status: All components listed or exempt. Revision: 10 May 2016 Page: 5/6

6 Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4): Chemical Name CAS No. Typical %wt. RQ (Pounds) SARA 311/312 - Hazard Categories: Fire Sudden Release Reactivity Immediate (acute) Chronic (delayed) SARA Toxic Chemicals (40 CFR 372): Chemical Name CAS No. Typical %wt SARA Extremely Hazardous Substances(40 CFR 355): Chemical Name CAS No. Typical %wt Proposition 65 (California): Chemical Name CAS No. Typical %wt. Hazards SECTION 16: OTHER INFORMATION The following sections contain revisions or new statements: 16. Date of preparation: May 10, 2016 Additional Information: HMIS (Hazardous Material Information System) NFPA (National Fire Protection Association) Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose. Blending Technologies, LLC gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. Blending Technologies, LLC accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information. Freedom under Patents, Copyright and Designs cannot be assumed. Revision: 10 May 2016 Page: 6/6