CHEMICAL PRODUCT SAFETY DATA SHEET DRAFT VERSION

Transcription

1 CHEMICAL PRODUCT SAFETY DATA SHEET DRAFT VERSION Prepared in accordance with GB/T and GB/T Issue date: Version #: 00 SECTION 1 Chemical product and company identification Product name Product code Manufacturer/Supplier Address: Gap Filler 4000 Part A; GB 7 mils; Potlife 240 mins The Bergquist Company West 78th Street Chanhassen, MN Non-Emergency calls: Contact person: Chemical Emergency AEHMSDS@henkel.com Call CHEMTREC Day or Night Within USA and Canada: Outside USA and Canada: (Collect Calls Accepted) Recommended use and Limitations on use Thermally Conductive Silicone Gap Filler Material used together with Part B. Recommended use Issue date Revision date Supersedes date SECTION 2 Hazards identification Emergency overview Low hazard under normal conditions. Hazard categories Label elements Pictograms Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Physical and chemical hazards Health hazards Environmental hazards Supplemental information The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash thoroughly after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. The product is stable and non-reactive under normal conditions of use, storage and transport. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. This product is not hazardous according to United Nations Globally Harmonized System, therefore a hazard label does not apply. SECTION 3 Composition/information on ingredients Substance/mixture Mixture The components are not hazardous or are below required disclosure limits. SECTION 4 First aid measures Inhalation Skin contact Eye contact Ingestion Move to fresh air. Get medical attention if symptoms occur. Wash skin with soap and water. Get medical attention if irritation persists after washing. Flush thoroughly with water. If irritation occurs, get medical assistance. Rinse mouth thoroughly. Get medical attention if any discomfort occurs. 1 / 5

2 Most important symptoms and health effects Personal protection for first-aid responders Notes to physician SECTION 5 Fire-fighting measures Extinguishing media Extinguishing media to avoid Specific hazards Special fire fighting procedures Protection of fire-fighters General fire hazards Get medical attention if any discomfort develops. Treat symptomatically. Use fire-extinguishing media appropriate for surrounding materials. Move containers from fire area if you can do so without risk. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. This product is not flammable. SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency Avoid contact with skin and eyes. For personal protection, see section 8 of the SDS. personnel For emergency responders Environmental precautions Clean-up methods and materials and containment measures Prevention of secondary hazards SECTION 7 Handling and storage Handling Storage Keep unnecessary personnel away. Environmental manager must be informed of all major spillages. Sweep up or gather material and place in appropriate container for disposal. For waste disposal, see Section 13 of the SDS. Avoid release to the environment. SECTION 8 Exposure controls/personal protection Exposure limits No exposure limits noted for ingredient(s). Biological limit values Exposure guidelines Monitoring methods Engineering measures Personal protective equipment Respiratory protection Hand protection Eye protection Skin and body protection Hygiene measures Provide adequate ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Wear appropriate personal protective equipment (See Section 8). Store in closed original container in a dry place. Store away from incompatible materials. No biological exposure limits noted for the ingredient(s). No exposure standards allocated. Follow standard monitoring procedures. SECTION 9 Physical and chemical properties Appearance Odor Physical state Form Color Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. In case of inadequate ventilation, use respiratory protection. Use suitable protective gloves if risk of skin contact. Suitable gloves can be recommended by the glove supplier. Risk of contact: Wear approved safety goggles. If prolonged or repeated contact is likely, chemical resistant clothing is recommended. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Liquid. Liquid. Blue. Slight / 5

3 Odor threshold ph Melting point/freezing point Boiling point, initial boiling point, and boiling range Flash point Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Evaporation rate Flammability (solid, gas) Other data Bulk density Explosive properties Oxidizing properties Viscosity VOC 3.10 g/cc (25 C) Insoluble in water. Not available. Not explosive. Not oxidizing. 50 Pa s Not available. SECTION 10 Stability and reactivity Reactivity Stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. No hazardous decomposition products are known. SECTION 11 Toxicological information Acute toxicity Routes of exposure Symptoms Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitizer Germ cell mutagenicity Carcinogenicity Toxic to reproduction Specific target organ toxicity following single exposure Not expected to be acutely toxic. Eye contact. Skin contact. Ingestion. Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. Not a respiratory sensitizer. This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Not classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects / 5

4 Specific target organ toxicity following repeated exposure Aspiration hazard Chronic effects Other information Not an aspiration hazard. SECTION 12 Ecological information Ecotoxicity Persistence and degradability Bioaccumulation Mobility in soil Other hazardous effects The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product. No data available. SECTION 13 Disposal considerations Residual waste Contaminated packaging Local disposal regulations SECTION 14 Transport information CNDG IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The product is insoluble in water. Expected to have low mobility in soil. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Since emptied containers retain product residue, follow label warnings even after container is emptied. Dispose of contents/container in accordance with local/regional/national/international regulations. Not applicable. SECTION 15 Regulatory information Inventory of Existing Chemical Substances in China Country(s) or region Inventory name On inventory (yes/no)* China Inventory of Existing Chemical Substances in China (IECSC) Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Applicable regulations This safety data sheet conforms to the following laws, regulations and standards: Regulations on the Control over Safety of Dangerous Chemicals Regulations on Labor Protection in Workplaces Where Toxic Products Are Used Measures for the Safe Use of Chemicals in Workplaces Safety Data Sheet for Chemical Products - Content and Order of Sections (GB/T ) General Rules for Preparation of Precautionary Labels for Chemicals (GB ) Packing Symbol of Dangerous Goods(GB ) Packing - Pictorial Marking for Handling of Goods (GB/T ) Occupational exposure limits for hazardous agents in the workplace (GBZ ) Not listed. Restricted Import/Export Toxic Chemical List (MEP and GCA Announcement No , Dec. 1, 2008, amended through MEP and Customs Notice No , December 30, 2013) Classification and code of dangerous goods (GB ) UN Recommendations on the Transport of Dangerous Goods (UN RTDG) / 5

5 SECTION 16 Other information References Disclaimer HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits / 5

6 CHEMICAL PRODUCT SAFETY DATA SHEET DRAFT VERSION Prepared in accordance with GB/T and GB/T Issue date: Version #: 00 SECTION 1 Chemical product and company identification Product name Product code Manufacturer/Supplier Address: Gap Filler 4000 Part B; GB 7, 10 mils; Potlife 240 mins The Bergquist Company West 78th Street Chanhassen, MN Non-Emergency calls: Contact person: Chemical Emergency AEHMSDS@henkel.com Call CHEMTREC Day or Night Within USA and Canada: Outside USA and Canada: (Collect Calls Accepted) Recommended use and Limitations on use Thermally Conductive Silicone Gap Filler Material used together with Part A. Recommended use Issue date Revision date Supersedes date SECTION 2 Hazards identification Emergency overview Low hazard under normal conditions. Hazard categories Label elements Pictograms Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Physical and chemical hazards Health hazards Environmental hazards Supplemental information The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash thoroughly after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. The product is stable and non-reactive under normal conditions of use, storage and transport. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. This product is not hazardous according to United Nations Globally Harmonized System, therefore a hazard label does not apply. SECTION 3 Composition/information on ingredients Substance/mixture Mixture The components are not hazardous or are below required disclosure limits. SECTION 4 First aid measures Inhalation Skin contact Eye contact Ingestion Move to fresh air. Get medical attention if symptoms occur. Wash skin with soap and water. Get medical attention if irritation persists after washing. Flush thoroughly with water. If irritation occurs, get medical assistance. Rinse mouth thoroughly. Get medical attention if any discomfort occurs. 1 / 5

7 Most important symptoms and health effects Personal protection for first-aid responders Notes to physician SECTION 5 Fire-fighting measures Extinguishing media Extinguishing media to avoid Specific hazards Special fire fighting procedures Protection of fire-fighters General fire hazards Get medical attention if any discomfort develops. Treat symptomatically. Use fire-extinguishing media appropriate for surrounding materials. Move containers from fire area if you can do so without risk. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. This product is not flammable. SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency Avoid contact with skin and eyes. For personal protection, see section 8 of the SDS. personnel For emergency responders Environmental precautions Clean-up methods and materials and containment measures Prevention of secondary hazards SECTION 7 Handling and storage Handling Storage Keep unnecessary personnel away. Environmental manager must be informed of all major spillages. Sweep up or gather material and place in appropriate container for disposal. For waste disposal, see Section 13 of the SDS. Avoid release to the environment. SECTION 8 Exposure controls/personal protection Exposure limits No exposure limits noted for ingredient(s). Biological limit values Exposure guidelines Monitoring methods Engineering measures Personal protective equipment Respiratory protection Hand protection Eye protection Skin and body protection Hygiene measures Provide adequate ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Wear appropriate personal protective equipment (See Section 8). Store in closed original container in a dry place. Store away from incompatible materials. No biological exposure limits noted for the ingredient(s). No exposure standards allocated. Follow standard monitoring procedures. SECTION 9 Physical and chemical properties Appearance Odor Physical state Form Color Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. In case of inadequate ventilation, use respiratory protection. Use suitable protective gloves if risk of skin contact. Suitable gloves can be recommended by the glove supplier. Risk of contact: Wear approved safety goggles. If prolonged or repeated contact is likely, chemical resistant clothing is recommended. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Liquid. Liquid. White. Slight / 5

8 Odor threshold ph Melting point/freezing point Boiling point, initial boiling point, and boiling range Flash point Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Evaporation rate Flammability (solid, gas) Other data Bulk density Explosive properties Oxidizing properties Viscosity VOC 3.10 g/cc (25 C) Insoluble in water. Not available. Not explosive. Not oxidizing. 50 Pa s Not available. SECTION 10 Stability and reactivity Reactivity Stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. No hazardous decomposition products are known. SECTION 11 Toxicological information Acute toxicity Routes of exposure Symptoms Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitizer Germ cell mutagenicity Carcinogenicity Toxic to reproduction Specific target organ toxicity following single exposure Not expected to be acutely toxic. Eye contact. Skin contact. Ingestion. Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. Not a respiratory sensitizer. This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Not classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects / 5

9 Specific target organ toxicity following repeated exposure Aspiration hazard Chronic effects Other information Not an aspiration hazard. SECTION 12 Ecological information Ecotoxicity Persistence and degradability Bioaccumulation Mobility in soil Other hazardous effects The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product. No data available. SECTION 13 Disposal considerations Residual waste Contaminated packaging Local disposal regulations SECTION 14 Transport information CNDG IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The product is insoluble in water. Expected to have low mobility in soil. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Since emptied containers retain product residue, follow label warnings even after container is emptied. Dispose of contents/container in accordance with local/regional/national/international regulations. Not applicable. SECTION 15 Regulatory information Inventory of Existing Chemical Substances in China Country(s) or region Inventory name On inventory (yes/no)* China Inventory of Existing Chemical Substances in China (IECSC) Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Applicable regulations This safety data sheet conforms to the following laws, regulations and standards: Regulations on the Control over Safety of Dangerous Chemicals Regulations on Labor Protection in Workplaces Where Toxic Products Are Used Measures for the Safe Use of Chemicals in Workplaces Safety Data Sheet for Chemical Products - Content and Order of Sections (GB/T ) General Rules for Preparation of Precautionary Labels for Chemicals (GB ) Packing Symbol of Dangerous Goods(GB ) Packing - Pictorial Marking for Handling of Goods (GB/T ) Occupational exposure limits for hazardous agents in the workplace (GBZ ) Not listed. Restricted Import/Export Toxic Chemical List (MEP and GCA Announcement No , Dec. 1, 2008, amended through MEP and Customs Notice No , December 30, 2013) Classification and code of dangerous goods (GB ) UN Recommendations on the Transport of Dangerous Goods (UN RTDG) / 5

10 SECTION 16 Other information References Disclaimer HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits / 5