3. COMPOSITION / INFORMATION ON INGREDIENTS 4. FIRST AID MEASURES 5. FIRE FIGHTING MEASURES
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2 Aggravated medical condition Symptoms : None : Exposures to oxygen deficient atmosphere may cause the following symptoms: Dizziness. Salivation. Nausea. Vomiting. Loss of mobility/ conciousness. Environmental Effects Not harmful. 3. COMPOSITION / INFORMATION ON INGREDIENTS Substance/Preparation : Substance Components EINECS / ELINCS Number CAS Number Concentration Classification (Volume) Helium % Concentration is nominal. For the exact product composition, please refer to Global Gases Group s technical specifications. 4. FIRST AID MEASURES General advice Eye and Skin Contact Ingestion Inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped. : Immediately flush eyes with water for at least 15 minutes. In case of frostbite spray with water for at least 15 minutes. Apply sterile dressing. Obtain medical assistance. : Ingestion is not considered a potential route of exposure. : Remove to fresh air. If breathing has stopped or is laboured, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. In case of shortness of breath, give oxygen. 5. FIRE FIGHTING MEASURES Suitable extinguishing media Specific hazards Special protective equipment for fire-fighters : All known extinguishing media can be used. : Upon exposure to intense heat or flame, cylinders will vent rapidly and/or rupture violently. Product is non-flammable and does not support combustion. Move away from the container and cool with water from a protected position. Keep containers and surroundings cool with water spray. : Wear self contained breathing apparatus for fire fighting if necessary. Page 2 of 6
3 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Additional advice : Evacuate personnel to safe areas. Wear self contained breathing apparatus when entering area unless atmosphere is proved to be safe. Monitor oxygen level. Ventilate the area. : Prevent further leakage or spillage. Do not discharge into any place where its accumulation could be dangerous. : Ventilate the area. : If possible, stop flow of product. Increase ventilation to the release area and monitor oxygen level If leak is from cylinder or cylinder valve, call the Global Gases emergency telephone number. If the leak is in the user s system, close the cylinder valve and safely vent the pressure before attempting repairs. 7. HANDLING AND STORAGE Handling Storage : Use safe work practices to avoid eye or skin contact and inhalation. Observe good personal hygiene. Prohibit eating, drinking and smoking in contaminated areas. Wash hands before eating. : Do not store near sources of ignition or incompatible materials. Cylinders should be stored below 45 C in a secure area, upright and restrained to prevent cylinders from falling. Cylinders should also be stored in a dry, well ventilated area constructed of non-combustible material with firm level floor (preferably concrete), away from areas of heavy traffic and emergency exits. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below 19.5% oxygen. Personal protective equipment Respiratory protection Hand protection : Self contained breathing apparatus (SCBA) or positive pressure airline with mask are to be used in oxygen-deficient atmosphere. Air purifying respirators will not provide protection. Users of breathing apparatus must be retained. : Sturdy work gloves are recommended for handling cylinders. The breakthrough time of the selected glove(s) must be greater than the intended use period. Page 3 of 6
4 Eye protection Skin and body protection Special instructions for protection and hygiene Remarks : Protect from liquid splashes. Safety glasses are recommended when handling cylinders. : Protect from liquid splashes. Safety shoes are recommended when handling cylinders. : Ensure adequate ventilation, especially in confined areas. : Simple asphyxiant. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Compressed gas. Colour : Colourless gas. Odour : No odour warning properties. Molecular Weight : 4 g/mol Relative vapour density : (air = 1) Vapour pressure : Not applicable. Density : g/cm3 (0.012lb/ft3) at 21C (70F) Specific volume : m3/kg (96.68 ft3/lb) at 21 degree C (70 degree F) Boiling point/range : degree C ( -302 degree F ) Critical temperature : degree C ( -188 degree F ) Water solubility : g/l 10. STABILITY AND REACTIVITY Stability : stable under normal conditions. Hazardous decomposition products : None. 11. TOXICOLOGICAL INFORMATION Acute Health Hazard Ingestion Inhalation Skin COLOGICAL Ecotoxicity effects Aquatic toxicity Toxicity to other organisms Persistence and degradability Mobility Bioaccumulation : No data is available on the product itself : No data is available on the product itself : No data is available on the product itself 12. ECOLOGICAL INFORMATION : No data is available on the product itself. : No data available. : No data available : No data is available on the product itself. Further information This product has no known eco-toxicological effects. Page 4 of 6
5 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Contaminated packaging : Contact supplier if guidance is required. Return unused product in original cylinder to supplier : Return cylinder to supplier. 14. TRANSPORT INFORMATION ADR IATA UN/ID No. : UN 1963 Class : 3A ADR/RID Hazard ID no : 22 UN/ID No. : UN1963 IMDG RID UN/ID No. : UN1963 UN/ID No. : UN1963 Further Information Avoid transport on vehicles where the load space is not separated from the driver s compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of accident or an emergency. The transportation information is not intended to convey all specific regulatory data relating to this material. For complete transportation information, contact Global Gases customer service representative. Page 5 of 6
6 15. REGULATORY INFORMATION Labelling according to EEC Direction R-phrase(s) : Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 1999/45/EC. No EC labelling required. Country Regulatory list Notification USA TSCA Included on Inventory EU EINECS Included on Inventory Canada DSL Included on Inventory Australia AICS Included on Inventory Japan ENCS Included on Inventory South Korea ECL Included on Inventory China SEPA Included on Inventory Philippines PICCS Included on Inventory WGK Identification Number : Not water endangering. 16. OTHER INFORMATION Ensure all national/local regulations are observed. Prepared by : Global Gases Group FZCO Product Technical Department. This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all countries that have translated the Directives in their national laws. Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted. Page 6 of 6
3. COMPOSITION / INFORMATION ON INGREDIENTS 4. FIRST AID MEASURES 5. FIRE FIGHTING MEASURES
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