SAFETY DATA SHEET ALPHA COATING TECHNOLOGIES, LLC. PRODUCT SAFETY/MSDS INFORMATION: 1735 W Cortland court Addison Il 60101

Transcription

1 SAFETY DATA SHEET ALPHA COATING TECHNOLOGIES, LLC SECTION 1 - IDENTIFICATION PRODUCT CODE/IDENTITY: ACT S0-305 PRODUCT TRADE NAME: RAL 2002 VERMILION USE OF SUBSTANCE: COATINGS SUPPLIER: ALPHACOATING TECHNOLOGIES EMERGENCY MEDICAL/SPILL INFO: (630) TECHNICAL INFORMATION: (630) PRODUCT SAFETY/MSDS INFORMATION: 1735 W Cortland court Addison Il DATE OF MSDS PREPARATION: 8/23/2016 SECTION 2: HAZARD IDENTIFICATION OSHA/HCS STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) CLASSIFICATION OF THE MIXTURE: Combustible Dust Acute Toxicity: Category 3 Skin Sensistization: category 1 Germ Cell Mutagenity: Category 1B Carcigenity: Category 2 Specific Target organ toxicity: Respiratory tract irritation (single exposure) category 3 Specific Target organ toxicity: Respiratory tract irritation (repeated exposure) category 2 Percentage of the mixture consisting of ingredients of unkwn toxicity: 80% Hazard Pictograms Signal Word: Danger Hazard Statements: May form combustible dust in air Toxic if swallowed. May cause allergic skin reaction.

2 May cause genetic defects May cause respiratory irritation May cause damage to organs through prolonged or repeated exposure Precautionary Statements: Dusts generated during application of powder coatings harmful if inhaled. May be harmful if swallowed. May cause slight skin irritation. Causes severe eye irritation. Prolonged or repeated contact may cause an allergic skin reaction. SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS PERCENT CAS NUMBER POLYESTER RESIN 50-<75 BARIUM SULFATE 10-< TRIGLYCIDYL ISOCYANURATE 1 -< TITANIUM DIOXIDE 20- < There are additional ingredients present which within the current kwledge of the supplier and in the concentrations applicable are classified as hazardous to health or environment and hence require reporting in this section SECTION 4 - FIRST AID MEASURES INGESTION: If swallowed, give one to two eight ounce glasses of water, but do t induce vomiting. Gently wipe out inside mouth to remove any residual material. EYE CONTACT: In case of eye contact, remove contact lenses and flush eyes immediately with a gentle stream of lukewarm water for at least 15 minutes. SKIN CONTACT: In case of skin contact, flush immediately with plenty of water for at least 15 minutes followed by washing with soap and water. INHALATION: If affected by inhalation of powder coating dust, remove to fresh air. Apply artificial respiration and other support measures as required. OTHER: If ingestion, any type of overexposure or symptoms of overexposure occur during or following the use of this product, contact a poison control center, emergency room or physician immediately; have Material Safety Data Sheet information available. SECTION 5 - FIRE FIGHTING MEASURES FLASHPOINT: Not applicable FLAMMABLE LIMITS: Lower explosion limit (LEL): 1.5 Upper explosion limit (UEL): Not available EXTINGUISHING MEDIA: Use extinguishers appropriate for surrounding fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: Dust can form explosive mixture in air.

3 SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Water spray may be used to cool closed containers that are exposed to extreme heat. If water is used, fog zzles are preferable. Firefighters should wear self-contained breathing apparatus and full protective clothing. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Return material to container. WASTE DISPOSAL METHOD: Waste material must be disposed of in accordance with federal, state, provincial, and local environmental control regulations. Empty containers should be recycled or disposed of through an approved waste management facility. SECTION 7 - HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: PROTECTIVE MEASURES: Put on appropriate personal protective equipment (see section 8). Persons with a history of skin sensitization problems should t be employed in any process in which this product is used. Do t use until all safety precautions are read and understood. HANDLING AND STORAGE PRECAUTIONS: For better shelf life, do t store above 80 degrees Fahrenheit (26 degrees C.). OTHER PRECAUTIONS: Store in cool dry place. SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS INGREDIENT NAME POLYESTER RESIN BARIUM SULFATE Triglycidyl Isocyaurate Titanium Dioxide EXPOSURE LIMITS NONE ACGIH TLV (United States 4/2014) TWA: 5 mg/m3 8 hours. Form: inhalable fraction OSHA PEL (United States 2/2013) TWA: 5 mg/m3 8 hours Form: Inhalable fraction TWA 15 mg/m3 8 hours Form: Total dust ACGIH TLV (United States 4/2014) TWA: 0.05 mg/m3 8 hours OSHA PEL (US 2/2013) TWA 15 mg/m3 8 hours Form: Total dust ACGIH TLV (US 4/2014) TWA: 10 mg/m3 8 hours PERSONAL PROTECTIVE EQUIPMENT FOR: EYE PROTECTION: Wear sufficient eye protection to prevent contact with powdered materials.

4 SKIN PROTECTION: Chemically resistant impervious gloves should be worn at all times when handling chemical products. RESPIRATORY PROTECTION: Use an appropriate NIOSH-approved particulate filter respirator. Read the respirator manufacturer's instructions and literature carefully to determine the type of airborne contaminants against which the respirator is effective, its limitations, and how it is to be properly fitted and used. OTHER EQUIPMENT: Clean contaminated clothing and shoes. VENTILATION REQUIREMENTS: Overexposure to powder coatings dust may be prevented by ensuring ventilation controls, dust exhaust, or fresh air entry. Provide general dilution or local exhaust ventilation in volume and pattern to keep the concentration of ingredients listed in Section 2 below the lowest suggested exposure limits, the LEL below the stated limit, and to remove decomposition products during welding or flame cutting. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES % VOLATILE/VOLUME:.090 % SOLIDS BY WEIGHT: SPECIFIC GRAVITY: / EVAPORATION RATE(BuOAc=100): 37 ODOR/APPEARANCE: Free flowing powder with minimal odor. SECTION 10 - STABILITY AND REACTIVITY This product is rmally stable and will t undergo hazardous reactions. INCOMPATIBILITY (MATERIALS AND CONDITIONS TO AVOID): High concentrations of airborne dust may ignite explosively. All ignition sources should be eliminated when this product is dispersed in air. Avoid contact with strong alkalies, strong mineral acids, or strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: May produce the following hazardous decomposition products when exposed to extreme heat: carbon moxide ; carbon dioxide ; lower molecular weight polymer fractions; oxides of nitrogen ; Extreme heat includes, but is t limited to, flame cutting, brazing, and welding. SECTION 11: TOXICOLOGICAL INFORMTAION INGREDIENT RESULT SPECIES DOSE EXPOSURE TRIGLYCIDYL ISOCYANOURATE LC 50 Inhalation Rat female 650 mg/m3 4 hours dust and mists Ld 50 oral Rat 138mg/m3 Titanium dioxide LD 50 oral Rat >10g/kg

5 IRRITATION: SKIN EYES AND RESPIRATORY: There are data available on the mixture itself. SENSITIZATION: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF. MUTAGENITY: There are data available on the mixture itself. CARCINOGENITY: There are data available on the mixture itself CLASSIFICATION INGREDIENT OSHA IARC NTP Titanium dioxide - 2B - IARC:1, 2A, 2B,3,4 NTP: Kwn to be a human carcigen; reasonably anticipated to be a human carcigen OSHA: + Not listed /Not regulated: - REPRODUCTIVE TOXICITY: There are data available on the mixture itself SPECIFIC TARGET ORGAN TOXICITY (Single exposure) Name Category polyester 3 SPECIFIC TARGET ORGAN TOXICITY (REPATED EXPOSURE) NAME CATEGORY Triglycidyl isocyaurate 2 Target organs: Contains material which causes damage to the following organs: upper respiratory tract, skin, eyes Contains material which may cause damage to the following organs: kidneys, lungs, the reproductive system, testes Potential acute health effects Eye contact: may cause eye irritation Inhalation: may cause respiratory irritation Skin contact: may cause allergic skin reaction Ingestion: toxic if swallowed SHORT TERM EXPOSURE: There are data available on the mixture itself LONG TERM EXPOSURE: There are data available on the mixture itself POTENTIAL CHRONIC HEALTH EFFECTS: GENERAL: May cause damage to organs through prolonged exposure. Repeated or prolonged exposure may lead to respiratory irritation. Severe allergic reaction may occur when exposed low levels Carcigenity: Suspected of causing cancer Mutagenity: May cause genetic defects

6 Tetragenity: No kwn effects Developmental effects: No kwn effects Acute Toxicity estimates Route oral ATE value mg/kg Toxicity ingredient result species Exposure Titanium dioxide Acute LC50>100 Daphnia Daphnia 48 hours mg/l fresh water magna SECTION 13: DISPOSAL CONSIDERATION: The disposal of this product should comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. SECTION 14: TRANSPORT INFORMATION DOT IMDG IATA UN NUMBER NOT REGULATED NOT REGULATED NOT REGULATED UN PROPER SHIPPING NAME TRANSPORT HAZARD CLASS PACKING GROUP EVVIRONMENTAL NO NO NO HAZARD MARINE POLLUTANT SUBSTANCES NA NA NA SECTION 15: REGULATORY INFORMATION United States: (TSCA 8b : All components are listed or exempted SARA 302/304: Not applicable SARA 311/312 Classification: INFORMATION ON INGREDIENTS Fire Hazard Immediate acute health hazard Delayed chronic health hazard NAME FIRE HAZARD SUDDEN RELEASE OF PRESSURE POLYESTER RESIN Triglycidyl isocyaurate YES Yes NO No REACTIVE NO No IMMEDIEATE ACUTE HEALTH HAZARD YES Yes DELAYED CHRONIC HEALTH HAZARD NO Yes Titanium dioxide yes

7 SECTION 16: OTHER INFORMATION Hazardous Materials Identification System (HMIS) and National Fire Protection Association (NFPA) Ratings: HMIS Rating NFPA Rating HEALTH 2* HEALTH 2 FLAMMABILITY 1(a) FLAMMABILITY 1(a) REACTIVITY 0 INSTABILITY 0 Rating System:0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic Effects. (a) The flammability rating printed above applies to this product during rmal transportation and storage. However, theoretically, this product can form explosive mixtures at high concentrations of airborne dust. Per NFPA 704 (1996 edition) criteria, such products would be assigned a "flammability" hazard rating of "3" if they are "readily dispersed in air". Safe handling of this product requires that all of the information on the SDS be evaluated for specific work environments and conditions of use. THIS IS THE END OF THE SDS FOR: ACT S0-305 Manufactured and Supplied by: Alpha Coating Techlogies, LLC W.CORTLAND COURT ADDISON IL 60101