1.2. Relevant identified uses of the substance or mixture and uses advised against (INT)

Size: px

Start display at page:

Download "1.2. Relevant identified uses of the substance or mixture and uses advised against (INT)"

Tyrone Thomas
5 years ago
Views:

SECTION 1: Identification of the substance/mixture 1.1. Product identifier Product form Substance name Formula Molecular weight : Substance Sodium Hydroxide Revision date: 02/26/2015 : Sodium Hydroxide : NaOH : 40.

1 SECTION 1: Identification of the substance/mixture 1.1. Product identifier Product form Substance name Formula Molecular weight : Substance Sodium Hydroxide Revision date: 02/26/2015 : Sodium Hydroxide : NaOH : g/mol CAS No. : Product code Synonyms : LW-NAOH : Caustic Soda 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Emergency telephone number Emergency number : Manufacture of substances : (USA) (INT) SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Corrosive to metals (Category 1), H290 Skin corrosion (Category 1A), H314 Serious eye damage (Category 1), H318 Acute aquatic toxicity (Category 3), H402 For the full text of the H-Statements mentioned in this Section, see Section Label elements GHS Label elements, including precautionary statements Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS US) H290 H314 H318 : Danger : May be corrosive to metals. : Causes severe skin burns and eye damage. : Causes serious eye damage. 02/26/2015 EN (English) 1

2 H402 Precautionary statement(s) : P234 P260 P264 P273 P280 P301 + P330 + P331 P303 + P361 + P353 P304 + P340 + P310 P305 + P351 + P338 + P310 P363 P390 P405 P406 P501 : Harmful to aquatic life. : Keep only in original container. : Do not breathe dust or mist. : Wash skin thoroughly after handling. : Avoid release to the environment. : Wear protective gloves/ protective clothing/ eye protection/ face protection. : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. : Wash contaminated clothing before reuse. : Absorb spillage to prevent material damage. : Store locked up. : Store in corrosive resistant stainless steel container with a resistant inner liner Hazards not otherwise classified (HNOC) or not covered by GHS none : Dispose of contents/ container to an approved waste disposal plant. SECTION 3: Composition/information on ingredients 3.1. Substances Component Classification Concentration Sodium Hydroxide Met. Corr. 1; Skin Corr. 1A; Eye Dam. 1; Aquatic Acute 3; H290, H314, H318, H402 For the full text of the H-Statements mentioned in this Section, see Section 16. <= 100 % SECTION 4: Description of first aid measures 02/26/2015 EN (English) 2

3 4.1. Description of first aid measures General advice First aid measures after inhalation First aid measures after skin contact First aid measures after eye contact First aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed : Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. : If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during transport to hospital. : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult physician. The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section Indication of any immediate medical attention and special treatment needed. SECTION 5: Firefighting measures 5.1. Extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide Special hazards arising from the substance or mixture 5.3. Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary More Information SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section Environmental precautions 02/26/2015 EN (English) 3

4 Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided Methods and material for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal Reference to other sections For disposal see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection 8.1. Control parameters Component CAS-No. Value Control parameters Sodium hydroxide TWA mg/m3 Remarks C mg/m3 Upper Respiratory Tract irritation Eye irritation Skin irritation Basis USA. Occupational Exposure Limit (OSHA) - Table Z-1 Limits for Air Contaminants USA. ACGIH Threshold Limit Values (TLV) C 2 mg/m3 USA. ACGIH Threshold Limit Values (TLV) C 2 mg/m3 California permissible exposure 02/26/2015 EN (English) 4

5 limits for chemical contaminants (Title 8, Article 107) Application Area Exposure routes Health effect Value Workers Inhalation Long-term local effects 1 mg/m3 Consumers Inhalation Long-term local effects 1 mg/m Exposure controls Appropriate engineering controls 8.3. Personal protective equipment Eye protection Skin Protection : Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. : Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). : Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested: Dermatril (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested: Dermatril (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D Eichenzell, phone +49 (0) , sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and 02/26/2015 EN (English) 5

6 Body protection Respiratory protection Environmental exposure controls must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. : Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. : Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). : Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Odor Odor Threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapor pressure : Form: pellets Color: white : odorless : 14 at 50 g/l at 20 C (68 F) : Melting point/range: 318 C (604 F) : 1,390 C (2,534 F) : Not applicable Vapor density : (Air = 1.0) Relative density : < hpa (< mmhg) at 20 C (68 F) 4.00 hpa (3.00 mmhg) at 37 C (99 F) : g/cm3 02/26/2015 EN (English) 6

7 Water solubility Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information Bulk density : g/cm3 : ca.1,260 g/l at 20 C (68 F) : ca.1,150 kg/m3 Relative vapor density : (Air = 1.0) SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials Strong oxidizing agents, Strong acids, Organic materials Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Sodium oxides Other decomposition products - In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Inhalation Dermal 02/26/2015 EN (English) 7

8 Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: NTP: OSHA: Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Additional Information : Skin - Rabbit Result: Causes severe burns h : Eyes - Rabbit Result: Corrosive - 24 h : Will not occur : No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. : No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. : No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. : RTECS: WB Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. SECTION 12: Ecological information Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Persistence and degradability : LC50 - Gambusia affinis (Mosquito fish) mg/l - 96 h LC50 - Oncorhynchus mykiss (rainbow trout) mg/l - 96 h : Immobilization EC50 - Daphnia (water flea) mg/l - 48 h The methods for determining the biological degradability are not applicable to inorganic substances Bioaccumulative potential 02/26/2015 EN (English) 8

9 12.4. Mobility in soil Results of PBT and vpvb assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life. SECTION 13: Disposal considerations Waste treatment methods Product Contaminated Packaging : Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. : Dispose of as unused product. SECTION 14: Transport information DOT (US) UN number : 1823 Class : 8 Packing group : II Proper shipping name : Sodium Hydroxide, solid Reportable Quantity (RQ) : 1000 lbs Poison Inhalation Hazard : No IMDG UN number : 1823 Class : 8 Packing group : II EMS-No : F-A, S-B Proper shipping name : SODIUM HYDROXIDE, SOLID IATA UN number : /26/2015 EN (English) 9

10 Class : 8 Packing group Proper shipping name : II : Sodium Hydroxide, solid SECTION 15: Regulatory information SARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Reactivity Hazard, Acute Health Hazard Massachusetts Right To Know Components Sodium Hydroxide Pennsylvania Right To Know Components Sodium Hydroxide New Jersey Right To Know Components Sodium Hydroxide California Prop. 65 Components CAS-No CAS-No CAS-No Revision Date Revision Date Revision Date This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16: Other information Full text of H-Statements referred to under sections 2 and 3. Aquatic Acute : Acute aquatic toxicity Eye Dam. : Serious eye damage H290 : May be corrosive to metals. H314 : Causes severe skin burns and eye damage. H318 : Causes serious eye damage. H402 : Harmful to aquatic life. Met. Corr. : Corrosive to metals 02/26/2015 EN (English) 10

11 HMIS Rating Health Hazard : 3 Chronic Health Hazard : Flammability : 0 Physical Hazard : 0 NFPA Rating Health hazard : 3 Fire Hazard : 0 Reactivity Hazard : 0 Special Hazard : Further Information Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and Loudwolf Holdings Ltd. assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his/her application. 02/26/2015 EN (English) 11

: Strontium Carbonate

Revision date: 06/25/2014 SECTION 1: Identification of the substance/mixture 1.1. Product identifier Product form Substance name Formula Molecular weight : Substance : Strontium Carbonate : SrCO3 : 147.63