SDS. GHS Safety Data Sheet. Wechem, Inc. AL 600 PRODUCT AND COMPANY IDENTIFICATION. Manufacturer HAZARDS IDENTIFICATION

Transcription

1 Page 1 of 6 1 PRODUCT A COMPANY IDENTIFICATION Manufacturer Wechem, Inc 5734 Susitna Dr Harahan, LA Contact: Phone: Fax: Web: Ligia M. Hernandez Product Name: Revision Date: Number: Product Code: Product Use: 5/8/2014 AC150G AC150 Aluminum Brightener and Cleaner 2 Route of Entry: Inhalation: Skin Contact: Eye Contact: Ingestion: HAZARDS IDENTIFICATION Inhalation, ingestion, skin absorption, eye Mists and/or vapors can cause burns and/ or respiratory irritation. Contains Hydrofluoric acid (HF). Can cause burns which may not be immediately painful or visible. Can cause burns Harmful or fatal if swallowed.

2 Page 2 of 6 GHS Signal Word: DANGER GHS Hazard Pictograms: GHS Classifications: Health, Specific target organ toxicity - Single exposure, 3 Health, Acute toxicity, 3 Dermal Health, Serious Eye Damage/Eye Irritation, 1 Health, Aspiration hazard, 2 GHS Phrases: H335 - May cause respiratory irritation H311 - Toxic in contact with skin H318 - Causes serious eye damage H305 - May be harmful if swallowed and enters airways GHS Precautionary Statements: P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P284 - Wear respiratory protection. P IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P363 - Wash contaminated clothing before reuse. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. 3 COMPOSITION/INFORMATION ON INGREDIENTS Ingredients: Cas # Perc. Chemical Name OSHA PEL ACGIH Carcin. (ppm) TLV(ppm) Ref Hydrofluoric acid 3 3 D Ethylene glycol D monobutyl ether Phosphoric acid 1MG/M3 1MG/M3 D

3 4 FIRST AID MEASURES Page 3 of 6 Inhalation: Skin Contact: Eye Contact: Ingestion: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical advice/attention. Immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical advice/attention. Immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get immediate medical advice/attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 5 FIRE FIGHTING MEASURES Flammability: Flash Point: Flash Point Method: Burning Rate: Autoignition Temp: LEL: UEL: Non flammable Extinguishing media: Foam, powder, carbon dioxide, water Special Fire fighting procedures: Use self-contained breathing apparatus and protective clothing if needed. Unusual Fire & Explosion Hazard: Hydrogen gas can be generated inside heated containers. 6 ACCIDENTAL RELEASE MEASURES Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment(PPE). Scoop up material and place in a disposal container. Provide ventilation. Spills of this material are a slipping hazard. 7 Handling Precautions: Storage Requirements: HALING A STORAGE Do not breathe gas/fumes/vapor/spray. Avoid contact with skin and eyes. Use only in well ventillated areas. Handle all open containers with care. Handle in accordance with good Industrial Hygiene and safety practice. Corrosive material. Can cause burns which may not be immediately painful or visible. Keep away from untrained personnel. Keep out of reach of children. Keep container tightly closed and in a well-ventilated place.

4 8 EXPOSURE CONTROLS/PERSOL PROTECTION Page 4 of 6 Engineering Controls: Personal Protective Equip: Ventilation Requirement: Local exhaust to keep concentration below TLV's. HMIS PP, B Goggles, Gloves Respiratory Protection: NIOSH- Approved respirator with acid cartridge. Protective gloves: Neoprene gauntlet type Eye protection: Safety goggles with plastic lenses and full face shield. Wear suitable protective clothing, including apron, appropriate boots, boot covers, overshoes etc., as may be appropriate. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. 9 PHYSICAL A CHEMICAL PROPERTIES Appearance: Physical State: Particle Size: Spec Grav./Density: Viscosity: Sat. Vap. Conc.: Boiling Point: Vapor Pressure: ph: Evap. Rate: Molecular weight: Clear reddish, purple liquid Liquid /- 0.1 < 1.5 Odor: Molecular Formula: Solubility: Softening Point: Percent Volatile: Heat Value: Freezing/Melting Pt.: Octanol: Vapor Density: VOC: Bulk Density: Characteristic Complete 10 STABILITY A REACTIVITY Stability: Conditions to Avoid: Materials to Avoid: Hazardous Decomposition: Hazardous Polymerization: Stable under normal storage conditions. Contact with alkaline, glass, ceramic or other silica containing material, extreme heat or freezing. Glass, leather, concrete, certain metals, natural rubber and many organic, silicon material, strong oxidizers Trace levels of hydrofluoric acid gas, oxides of carbon and phosphorus. Will not occur

5 11 TOXICOLOGICAL INFORMATION Page 5 of 6 Data for the components of this material is summarized as follows: Hydrofluoric acid ( ) Inhalation LC ppm 1h, (Rat) Inhalation LC mg/m3 1h, (Rat) Phosphoric acid ( ) Inhalation LC50 >850 mg/m3 1h, (Rat) Oral LD mg/kg (Rat) Dermal LD mg/kg ( Rabbit) Ethylene glycol monobutyl ether ( ) Inhalation LC mg/l 4h, (Rat) Inhalation LC ppm 4h, (Rat) Oral LD mg/kg (Rat) Dermal LD mg/kg (Rat) Dermal LD mg/kg (Rabbit) This product is not classified as a carcinogen. 12 ECOLOGICAL INFORMATION Data for the components of this material is summarized as follows: May cause long-term adverse effects in the aquatic environment. 13 DISPOSAL CONSIDERATIONS This material must be disposed of in accordance with all local, state, provincial and federal regulations. 14 TRANSPORT INFORMATION Proper Shipping Name: UN 2922, Corrosive Liquids, Toxic N.O.S. (Hydrofluoric Acid) (Phosphoric Acid), 8,PGII

6 15 REGULATORY INFORMATION COMPONENT / (CAS/PERC) / CODES *Hydrofluoric acid ( %) CERCLA, CSWHS, EHS302, EPCRAWPC, HAP, MASS, NJEHS, NJHS, OSHAPSM, OSHAWAC, PA, SARA313, TOXICRCRA, TXAIR, TXHWL *Phosphoric acid ( %) CERCLA, CSWHS, EPCRAWPC, MASS, NJHS, OSHAWAC, SARA313, TXAIR *Ethylene glycol monobutyl ether ( %) HAP, MASS, OSHAWAC, PA, SARA313, TXAIR REGULATORY KEY DESCRIPTIONS CERCLA = Superfund clean up substance CSWHS = Clean Water Act Hazardous substances EHS302 = Extremely Hazardous Substance EPCRAWPC = EPCRA Water Priority Chemicals HAP = Hazardous Air Pollutants MASS = MA Massachusetts Hazardous Substances List NJEHS = NJ Extraordinarily Hazardous Substances NJHS = NJ Right-to-Know Hazardous Substances OSHAPSM = OSHA Chemicals Requiring process safety management OSHAWAC = OSHA Workplace Air Contaminants PA = PA Right-To-Know List of Hazardous Substances SARA313 = SARA 313 Title III Toxic Chemicals TOXICRCRA = RCRA Toxic Hazardous Wastes (U-List) TXAIR = TX Air Contaminants with Health Effects Screening Level TXHWL = TX Hazardous Waste List Page 6 of 6 16 OTHER INFORMATION We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. ** Chemical listed as carcinogen or potential carcinogen. [a] NTP [b] IARC Monograph [c] OSHA [d] Not listed [e] Animal Data only N/A = Not available N/D = Not determined