Nubifer Iron Oxide Red

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Nubifer R-2500, R-2501, R-2512, R-2513, R-2521, R-2530, R-2541, R-2581, Nubifer R-4511, R-4520, R-4521, R-4530, R-4540, R-5501, R-5510, R-5511, Nubifer R-5520, R-5530, R-5531, R-5540, R-5580 Chemical description : Diiron trioxide REACH nr. : Relevant identified uses of the substance or mixture and uses advised against Use : Colouring agents, pigments Details of the supplier of the safety data sheet Company identification : NUBIOLA GROUP Gran Vía Corts Catalanes Barcelona SPAIN Tel nuproducts.safety@nubiola.com 1.4. Emergency telephone number Phone nr : UK National Poisons Emergency Hazards identification 2.1. Classification of the substance or mixture Classification [Regulation (EC) No 1272/2008 (CLP/GHS)] Classification [67/548/EEC or 1999/45/EC] 2.2. Label elements Labelling [Regulation (EC) No 1272/2008 (CLP/GHS)] Labelling [67/548/EEC or 1999/45/EC] 2.3. Other hazards Revised edition no : 2 Page : 1 / 7

2 2. Hazards identification (continued) Other hazards : None under normal conditions. 3. Composition/information on ingredients Substance / Mixture Hazardous component(s) Composition : Substance. Diiron trioxide, Pigment Red 101, CI CAS No : EC No : Index No :--- REACH Ref. : : This product is not hazardous. : Fe2O3 Substance name Contents CAS No EC No Index No REACH Ref. Classification Diiron trioxide, : Not classified (DSD/DPD) Pigment Red 101, CI Not classified (GHS) Contains no other components or impurities which will influence the classification of the product. 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Do not induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms relating to use : Not expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Surrounding fires : Foam. Water spray. Dry powder. Carbon dioxide. Sand. : Do not use a heavy water stream. : Use water spray or fog for cooling exposed containers Special hazards arising from the substance or mixture Revised edition no : 2 Page : 2 / 7

3 5. Fire-fighting measures (continued) Hazardous combustion products : Under fire conditions, hazardous fumes will be present Advice for fire-fighters Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders Special precautions For non-emergency personnel : Ventilate area. Equip cleanup crew with proper protection. : Recover the cleaning water for later disposal. : Evacuate unnecessary personnel Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters Methods and material for containment and cleaning up Clean up methods : Ventilate area. On land, sweep or shovel into suitable containers. Minimize generation of dust Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling Handling Technical protective measures : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. : Provide adequate ventilation to minimize dust and/or vapour concentrations Conditions for safe storage, including any incompatibilities Storage Storage - away from : Keep only in the original container in a cool, dry, well-ventilated place. Keep container closed when not in use. : Strong acids. Strong bases Specific end use(s) Specific end use(s) : No data available. Revised edition no : 2 Page : 3 / 7

4 8. Exposure controls / personal protection 8.1. Control parameters Occupational Exposure Limits : TWA: 10 mg Fe/m3 (8 hours, Inhalable Dust) TWA: 3 mg Fe/m3 (8 hours, Respirable Dust) 8.2. Exposure controls Personal protection Respiratory protection Hand protection Eye protection Others : Avoid all unnecessary exposure. : Where excessive dust may result, wear approved mask. FFP2 (EN149) : In case of repeated or prolonged contact wear gloves. : Chemical goggles or safety glasses. : Do not eat, drink or smoke when using this product. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C : Powder. Colour : Red. Odour : Odourless. Odour threshold : No data available. ph : 3-6 (10% w/w) [ASTM D ] Melting point [ C] : > 1000 C Critical temperature [ C] Auto-ignition temperature [ C] Flammability (solid, gas) : Not flammable. [UN Test 1] Flash point [ C] Boiling point [ C] (Solid) Evaporation rate Vapour density Density at 20ºC [g/cm3] : g/cm3 [ASTM D ] Solubility in water : Insoluble. Log Pow octanol / water at 20 C : No data available. Viscosity at 40 C [mm2/s] (Solid) 9.2. Other information Explosive properties Explosion limits - upper [%] Explosion limits - lower [%] Oxidising properties : Not explosive. : Not oxidizing. Revised edition no : 2 Page : 4 / 7

5 10. Stability and reactivity Reactivity Reactivity : Stable under normal conditions Chemical stability Chemical stability : Stable under normal conditions Possibility of hazardous reactions Hazardous reactions : Stable under recommended storage conditions Conditions to avoid Conditions to avoid : Decomposes at temperatures above 1000 ºC Incompatible materials Materials to avoid : Strong acids. Strong bases Hazardous decomposition products Hazardous decomposition products : None under normal conditions. 11. Toxicological information Information on toxicological effects Acute toxicity - LD50 Oral (rat) [mg/kg] : > 5000 mg/kg - LC50 Rat inhalation [mg/m³/6h] : > 210 mg/m3 Irritation : Non-irritating. Sensitization : No sensitizing potential. Mutagenicity : No experimental or epidemiological evidence exists. Carcinogenicity : No experimental or epidemiological evidence exists. Reproductive toxicity : No experimental or epidemiological evidence exists. Specific target organ toxicity (STOT) : No experimental or epidemiological evidence exists. single exposure Specific target organ toxicity (STOT) : No experimental or epidemiological evidence exists. repeated exposure Aspiration hazard 12. Ecological information Toxicity Acute toxicity Revised edition no : 2 Page : 5 / 7

6 12. Ecological information (continued) - EC50 48 h - Daphnia [mg/l] : > 100 mg/l - LC50 96 h - Fish [mg/l] : > mg/l (Danio rerio) Persistence - degradability Persistence - degradability Bioaccumulative potential Bioaccumulative potential Mobility in soil Mobility in soil Results of PBT and vpvb assessment Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH Other adverse effects Environmental precautions : Avoid release to the environment. WGK class (Germany) :0 13. Disposal considerations Waste treatment methods General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. 14. Transport information Land transport (ADR-RID) : Not regulated Sea transport (IMDG) : Not regulated Air transport (ICAO-IATA) : Not regulated. Revised edition no : 2 Page : 6 / 7

7 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII : None Chemical Safety Assessment Chemical Safety Assessment : It has been carried out. 16. Other information Revision : Revision - See : * Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Recommended uses and restrictions : See product bulletin for detailed information. Further information : For professional use only. The contents and format of this safety data sheet are in accordance with REACH Regulation (EC) No 1907/2006 and Regulation ( EU) No 453/2010. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document Revised edition no : 2 Page : 7 / 7