SAFETY DATA SHEETS (SDS)

Transcription

1 1 SAFETY DATA SHEETS (SDS) 1. PRODUCT IDENTIFICATION PRODUCT NAME: SYNONYMS: FORMULA: RECOMMENDED USES: SODIUM BICARBONATE Baking Sda NaHCO3 Fd Ingredient, Pharmaceutical, Husehld and Persnal Care Prduct, Water Treatment, General Industrial Use. COMPANY: CRYSTAL MARK INC. ADDRESS: 613 Justin Ave. Glendale CA, PHONE: HAZARD IDENTIFICATION The cnsumer variant f this prduct is labeled in accrdance with regulatins administered by the Cnsumer Prduct Safety Cmmissin (CPSC) and the fd and Drug Administratin (FDA). The use pattern and expsure in the wrkplace are generally nt cnsistent with thse experienced by the cnsumers. The requirements f the Occupatinal Safety and Health Administratin applicable t this SDS differ frm the labeling requirements f the CPSC and FDA, as a result, this SDS may cntain additinal health hazard infrmatin nt pertinent t cnsumer use and nt fund n the prduct label. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: Classificatin (GHS-US) Nt classified LABEL ELEMENTS: GHS-US Labeling- N labeling applicable OTHER HAZARDS: Expsure may aggravate thse with pre-existing eye, skin, r respiratry cnditins. Prlnged cntact with dust can prduce mechanical irritatin. UNKNOWN ACUTE TOXICITY (GHS-US): 3. COMPOSITION / INFORMATION ON INGREDIENTS Substances Name Sdium Bicarbnate CAS N Name Prduct Identifier % (w/w) Classificatin (GHS-US) Sdium Bicarbnate (CAS N) Nt Classified 4. FIRST-AID MEASURES Descriptin f First Aid Measures GENERAL: Never give anything by muth t an uncnscius persn. If yu feel unwell, seek medical advice. EYES: Rinse cautiusly with water fr at least 15 minutes. Remve cntact lenses, if present and easy t d s. Cntinue rinsing. Obtain medical attentin if irritatin persists.

2 SKIN: Brush ff lse particles frm skin. Rinse immediately with plenty f water. Obtain medical attentin if irritatin develps r persists. INHALATION: When symptms ccur: g int pen air and ventilate suspected area. INGESTION: Rinse muth. D NOT induce vmiting. Seek medical attentin if a large amunt is swallwed. Mst Imprtant Symptms and Effects Bth Acute and Delayed General: Nne expected under nrmal cnditins f use. Inhalatin: Prlnged inhalatin f dust may cause respiratry irritatin. Skin Cntact: Skin cntact with large amunts f dust may cause mechanical irritatin. Eye Cntact: Cntact may cause irritatin due t mechanical abrasin. Ingestin: Large dses may prduce systemic alkalsis and expansin in extracellular fluid vlume with edema. Chrnic Symptms: Nne expected under nrmal cnditins f use. 5. FIRE FIGHTING MEASURES EXTIGUISHING MEDIA SUITABLE EXTINGUISHING MEDIA: Use extinguishing media apprpriate fr surrunding fire. UNSUITABLE EXTINGUISHING MEDIA: Fr surrunding fire: Use f heavy f water may spread fire. Special hazards Arising Frm the Substance r Mixture FIRE HAZARD: NOT FLAMMABLE. Under fire cnditins, hazardus fumes will be present. EXPLOSION HAZARD: Prduct is nt explsive. REACTIVITY: Hazardus reactins will nt ccur under nrmal cnditins. FIRE FIGHTING INSTRUCTIONS: Wear self-cntained breathing apparatus when entering area unless atmsphere is prvided t be safe. Exercise cautin when fighting any chemical fire. PROTECTIONS DURING FIREFIGHTING: D nt enter area withut prper prtective equipment, including respiratry prtectin. HAZARDOUS COMBUSTION PRODUCTS: Carbn xides (CO, CO2). Sdium xides. REFERENCE TO OTHER SECTIONS: Refer t sectin 9 flammability prperties. 6. ACCIDENTAL RELEASE MEASURES GENERAL MEASURES: Handle in accrdance with gd industrial hygiene and safety practice. D nt breathe dust r fumes. Avid skin and eye cntact. FOR EMERGENCY PERSONNEL PROTECTIVE EQUIPMENT: Equip cleanup crew with prper prtectin EMERGENCY PROCEDURES: Ventilate area. ENVIRONMENTAL PRECAUTIONS: Prevent entry t sewers and public waters. Avid release t the envirnment. METHODS AND MATERIAL FOR CONTAINMENT AND CLEAN UP: Fr cntainment cntain and cllect as any slid. Methds fr cleaning up- clean up spills immediately and dispse f waste safely. Avid generatin f dust during clean-up f spills. Keep in suitable, clsed cntainers fr dispsal. Cntact cmpetent authrities after aspill. REFERENCE TO OTHER SECTIONS: See heading 8, Expsure and Persnal Prtectin. 7. HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING Additinal Hazards When Prcessed: When heated, Material emits irritating fumes. Hygiene Measures: Handle in accrdance with gd industrial hygiene and safety prcedures. Wash hands and ther expsed areas with mild sap and water befre eating, drinking, r smking and again when leaving wrk. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES Strage Cnditins: Stre in a dry, cl and well-ventilated place. Keep cntainer clsed when nt in use. Incmpatible Materials: Acids. Water. Lime. 2

3 3 Strage Temperature: < 65 C (150 F) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Cntrl Parameters Particulates nt therwise classified (PNOC) USA ACGIH ACGIH TWA (mg/m³) 3 mg/m3 Respirable fractin 10 mg/m3 Ttal Dust USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m3 Respirable fractin 15 mg/m3 Ttal Dust Alberta OEL TWA (mg/m³) 10 mg/m³ (ttal) British Clumbia OEL TWA (mg/m³) 10 mg/m³ (ttal dust) Manitba OEL TWA (mg/m³) 10 mg/m³ (inhalable particles, recmmended) New Brunswick OEL TWA (mg/m³) 3 mg/m³ (particulate matter cntaining n Asbests and <1% Crystalline silica, respirable fractin) Newfundland & Labradr OEL TWA (mg/m³) 10 mg/m³ (inhalable particles, recmmended) Nva Sctia OEL TWA (mg/m³) 10 mg/m³ (inhalable particles, recmmended) Nunavut OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Nrthwest Territries OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Ontari OEL TWA (mg/m³) 10 mg/m³ (inhalable) Prince Edward Island OEL TWA (mg/m³) 10 mg/m³ (inhalable particles, recmmended) Québec VEMP (mg/m³) 10 mg/m³ (including dust, inert r nuisance particulates; cntaining n Asbests and <1% Crystalline silica-ttal dust) Saskatchewan OEL STEL (mg/m³) 20 mg/m³ (insluble r prly sluble-inhalable fractin) 6 mg/m³ (insluble r prly sluble-respirable fractin) Saskatchewan OEL TWA (mg/m³) 10 mg/m³ (insluble r prly sluble-inhalable fractin) 3 mg/m³ (insluble r prly sluble-respirable fractin) Apprpriate Engineering Cntrls: Fr ccupatinal/wrkplace settings: Emergency eye wash funtains and safety shwers shuld be available in the immediate vicinity f any ptential expsure. Ensure adequate ventilatin, especially in cnfined areas. Ensure all natinal/lcal regulatins are bserved. PERSONAL PROTECTIVE EQUIPMENT: Fr ccupatinal r bulk quantities: Glbes. Safety glasses. Dust frmatin: dust mask. RESPIRATORY PROTECTION: Use a NIOSH-apprved respiratr r self-cntained breathing apparatus whenever expsure may exceed established Occupatinal Expsure Limits. EYE PROTECTION: Fr ccupatinal r bulk quantities: Chemical gggles r safety glasses. HAND PROTECTION: Fr ccupatinal r bulk quantities: wear chemically resistant prtective glves. OTHER INFORMATION: When using, d nt eat, drink r smke. 9. PHYSICAL AND CHEMICAL PROPERTIES Infrmatin n Basic Physical and Chemical Prperties Physical State Slid Appearance/Odr White, crystalline pwder/drless Odr Threshld Nt Available ph 8.2 (1%Slutin) Evapratin Rate

4 4 Melting Pint Freezing pint Biling Pint Flash Pint Flammability (slid,gas) Specific gravity/density Slubility Explsin Data-Sensitivity t Mechanical Impact Explsin Data-Sensitivity t Static Discharge 62 lb/ft³ Water: C (68 F) Nt expected t present an explsin due t mechanical impact. Nt Expected t present an explsin due t static discharge. 10. STABILITY AND REACTIVITY REACTIVITY: Stable under nrmal ambient cnditins f temperature and pressure. CHEMICAL STABILITY: Decmpses slwly n expsure t water (misture). POSIBLE HAZARDOUS REACTIONS: Hazardus plymerizatin will nt ccur. CONDITIONS TO AVOID: Expsure t misture r mist air. Temperatures abve 150 F (65 C). INCOMPATIBLE MATERIALS: Acids. Water. Lime. HAZARDOUS DECOMPOSITION PRODUCTS: Nne knwn. At high temperature may liberate txic gases. 11. TOXICOLOGICAL INFORMATION EYE: SKIN: INHALATION: INGESTION: Particulate matter may cause physical injury t the eye. May cause minr irritatin. May cause respiratry irritatin thrugh single use. May cause damage t lungs r pulmnary disease thrugh prlnged/repeated expsure t dust. Ingestin f large quantities may result in gastrintestinal irritatin and eventually interference with phsphate absrptin which results in rickets. 12. ECOLOGICAL INFORMATION Txicity N additinal infrmatin available Sdium Bicarbnate LC50 Fish mg/l Bluegill EC50 Daphnia mg/1 LC 50 FISH mg/1 Rainbw trut Sdium bicarbnate ( ) LC50 Fish mg/1 (Expsure time: 96h Species: Lepmis macrchirus [static]) EC50 Daphnia mg/1 (expsure time:48 h Species: Daphnia magna) Persistence & Degradability: Nt Established Biaccumulative Ptential: Nt established Mbility In Sil: Other Infrmatin: Avid release t the envirnment. 13. DISPOSAL CONSIDERATIONS Waste Dispsal Recmmendatins: Dispse f waste material in accrdance with all lcal, reginal, natinal, prvincial, territrial and internatinal regulatins. 14. TRANSPORT INFORMATION In Accrdance with DOT

5 5 In Accrdance with IMDG In Accrdance with IATA In Accrdance with TDG 15. REGULATORY INFORMATION US Federal & Internatinal Regulatins Sdium Bicarbnate ( ) Listed n the AICS (Australian Inventry f Chemical Substances) Listed n the Canadian DSL (Dmestic Substances List) Listed n IECSC (Inventry f Existing Chemical Substances Prduced r Imprted in China) Listed n the EEC inventry EINECS (Eurpean Inventry f Existing Cmmercial Chemical Substances) Listed n the Japanese ENCS (Existing & New Chemical Substances) inventry Listed n the Krean ECL (Existing Chemicals List) Listed n NZIC (New Zealand Inventry f Chemicals) Listed n PICCS (Philippines Inventry f Chemicals and Chemical Substances) Listed n the United States TSCA (Txic Substances Cntrl Act) inventry US State Regulatins: Neither this prduct nt its chemicals cmpnents appear n any US state lists. Canadian Regulatins Sdium Bicarbnate ( ) Listed n the Canadian DSL (Dmestic Substances List) WHMIS Classificatin Uncntrlled prduct accrding t WHMIS classificatin criteria This prduct has been classified in accrdance with the hazard criteria f the Cntrlled Prducts Regulatins (CPR) and the SDS cntains all f the infrmatin required by CPR. 16. OTHER INFORMATION & LAST REVISION DATE This dcument has been prepared in accrdance with the SDS requirements f the OSHA Hazard cmmunicatin Standard 29 CFR DISCLAIMER: Althugh reasnable care has been taken in the preparatin f the infrmatin cntained herein, the riginatr and CrystalMarkInc extends n warranties, makes n representatin and assumes n respnsibility as t the accuracy f suitability f such infrmatin fr applicatin t the purchaser s intended purpses r fr cnsequences f its use. LAST REVISION DATE: 10/21/15