Risalah Data Keselamatan Safety data sheet

Transcription

1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/21 1. Pengenalan bahan kimia dan pembekal Efka PL 5646 Nama bahan kimia: Nombor CAS: Kegunaan: Coating raw material for industrial applications Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Tidak memerlukan pengelasan menurut kriteria GHS untuk produk ini. Unsur label dan pernyataan berjaga-jaga: Produk tidak memerlukan label amaran bahaya menurut kriteria GHS. Bahaya lain yang tidak menyebabkan pengelasan:

2 Mukasurat (Page): 2/21 Jika berkenaan, maklumat yang diberikan dalam bahagian ini tentang bahaya lain tidak menyebabkan pengelasan tetapi mungkin menyumbang kepada bahaya bahan atau campuran secara keseluruhan. Lihat seksyen 12 - Keputusan PBT dan Penilaian vpvb 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia 1,2-Cyclohexanedicarboxylic acid, diisononyl ester Nombor CAS: Langkah-Langkah Pertolongan Cemas Nasihat am: Tanggalkan pakaian yang tercemar. Jika tersedut: Jika kesukaran berlaku selepas tersedut wap/aerosol, alihkan mangsa ke kawasan berudara bersih dan dapatkan rawatan perubatan. Apabila terkena kulit: Basuh bersih-bersih dengan sabun dan air. Apabila terkena mata: Basuh mata yang terkena produk selama sekurang-kurangnya 15 minit di bawah aliran air sambil membuka mata. Apabila tertelan: Segera basuh mulut dan kemudian minum air yang banyak. Nota kepada doktor: Gejala: Tiada gejala yang ketara dijangka oleh kerana pengelasan tidak diperlukan untuk produk ini. Nota kepada doktor: Bahaya: Tiada bahaya dijangkakan. Rawatan: Rawat mengikut gejala (nyahcemar, fungsi utama), tiada penawar khusus diketahui. 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: karbon dioksida, serbuk kering, semburan air, busa Bahaya tertentu: Produk mudah terbakar. Sejukkan bekas yang berbahaya dengan semburan air. Peralatan perlindungan khusus: Gunakan alat pernafasan serba lengkap.

3 Mukasurat (Page): 3/21 Maklumat lanjut: Lupuskan sisa kebakaran dan air pemadam api yang tercemar menurut peraturan rasmi. Kumpul air pemadam api yang tercemar secara berasingan, jangan biarkan ia mengalir ke dalam sistem pembetung atau efluen. 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Langkah berjaga-jaga untuk alam sekitar: Pelepasan ke alam sekitar mestilah dielakkan. Kaedah pembersihan atau penyerapan: Kutip dengan bahap penyerap yang sesuai. Lupuskan bahan yang diserap mengikut peraturan. 7. Pengendalian dan Penyimpanan; Pengendalian Pastikan pengalihudaraan menyeluruh di kawasan simpanan dan di tempat kerja. Penyimpanan Maklumat lanjut tentang keadaan penyimpanan: Bekas hendaklah disimpan tertutup rapat di tempat yang kering. 8. Kawalan pendedahan dan perlindungan diri Komponen dengan parameter kawalan tempat kerja tiada Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan tidak diperlukan. Perlindungan tangan: Sarung tangan pelindung kalis kimia (EN 374) getah nitril (NBR) mm ketebalan salutan Arahan penggunaan pengilang hendaklah dipatuhi kerana jenisnya yang pelbagai. Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374): Nota tambahan : Spesifikasi adalah berdasarkan ujian ujian, data penerbitan dan maklumat dari pengeluar sarung tangan atau diambil yang serupa secara analogi. Oleh sebab banyak keadaan yang perlu dipertimbangkan (misalnya suhu), perlulah diambil kira, bahawa secara praktikalnya

4 Mukasurat (Page): 4/21 tempoh penggunaan sarung tangan pelindung kimia mungkin lebih pendek daripada tempoh penelapan yang ditentukan menurut ujian. Perlindungan mata: Kaca mata keselamatan dengan pelindung sisi (gogal berbingkai) (contohnya EN 166) Perlindungan badan: Perlindungan badan mestilah dipilih berdasarkan tahap aktiviti dan pendedahan. Langkah kebersihan dan keselamatan am: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: Ambang bau: nilai ph: cecair Tidak berwarna hampir tiada bau tidak ditentukan Tidak boleh digunakan, keterlarutan yang sangat rendah takat tuang: -54 C (DIN ISO 3016) Suhu didih: dianggarkan 394 C (1,013 hpa) Tidak boleh disuling tanpa penguraian pada tekanan normal. (Arahan 92/69/EEC, A.2) Takat kilat: 224 C Apabila terdedah kepada suhu tinggi untuk tempoh masa yang panjang, penghasilan produk penguraian mudah terbakar akibat pengeluaran gas mungkin berlaku. (Arahan 92/69/EEC, A.9, cawan tertutup) Tahap penyejatan: Nilai boleh dianggarkan berdasarkan Pemalar Hukum Henry atau tekanan wap. Kemudahbakaran (pepejal/gas): tidak mudah tercucuh

5 Mukasurat (Page): 5/21 Had letupan bawah: Akibat tindakan penguraian terma (lihat Penguraian terma), angka bermakna yang dinyatakan dalam unit isipadu-% tidak dapat ditentukan jika menggunakan standard DIN EN 1839 untuk penentuan had letupan bawah.,berdasarkan penilaian secara teori, boleh diandaikan bahawa wap dan produk penguraian yang terhasil daripada cecair ini boleh membentuk campuran boleh meletup apabila bercampur dengan udara pada kepekatan >= 40 g/nm3 (suhu campuran 20 C) atau >= 33 g/nm3 (suhu campuran 200 C) (dianggarkan 170 C, dianggarkan 1013 hpa) Takat bawah letupan bahan/campuran telah ditentukan. Takat letupan ini menerangkan suhu bagi cecair mudah terbakar apabila kepekatan wap tepu bercampur dengan udara bersamaan dengan had bawah letupan. (, udara) Akibat tindakan penguraian terma (lihat Penguraian terma), penentuan titik letupan bawah menurut standard DIN EN tidak memberikan nilai yang bermakna secara menyeluruh. Had letupan atas: Akibat tindakan penguraian terma (lihat Penguraian terma), had letupan atas tidak dapat ditentukan menurut standard DIN EN Untuk cecair tiada kaitan untuk pengelasan dan pelabelan. Suhu pencucuhan: 330 C (Arahan 92/69/EEC, A.15) Penguraian terma: Apabila terdedah kepada suhu tinggi untuk tempoh masa yang panjang, penghasilan produk penguraian mudah terbakar akibat pengeluaran gas mungkin berlaku.

6 Mukasurat (Page): 6/21 pencucuhan sendiri: Bahan tidak memulakan tindak balas eksoterma di dalam keadaan ujian. Suhu: 20 C Tidak swacucuh. Jenis ujian: Pencucuhan sendiri pada suhu tinggi. (Kaedah: lain) Jenis ujian: Swanyalaan spontan pada suhu bilik. Bahaya letupan: tidak mudah meletup (lain) Sifat yang menggalakkan kebakaran: tidak merebakkan api (lain) Tekanan Wap: < hpa (20 C) (Arahan 92/69/EEC, A.4) Kepekatan: g/cm3 (20 C) Ketumpatan wap relatif (udara): tidak ditentukan Keterlarutan dalam air: < 0.02 mg/l (25 C) Keterlarutan (kualitatif) pelarut: pelarut organik terlarut Pekali petakan n-oktanol/air (log Pow): 10 (25 C) Penjerapan/air-tanah: log KOC: 6.59 Penjerapan kepada fasa tanah pejal dijangka Tegangan permukaan: Tidak boleh digunakan (DIN 51757) (Arahan 92/69/EEC, A.4) Kelikatan, dinamik: mpa.s (20 C) Nilai telah ditentukan melalui pengiraan daripada kelikatan kinematik Jisim molar: g/mol 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Tiada langkah waspada khas selain menyimpan bahan kimia dengan kemas Penguraian terma: Apabila terdedah kepada suhu tinggi untuk tempoh masa yang panjang, penghasilan produk penguraian mudah terbakar akibat pengeluaran gas mungkin berlaku. Bahan yang perlu dielakkan: agen pengoksida yang kuat

7 Mukasurat (Page): 7/21 Kakisan kepada logam: Tiada kesan mengakis pada logam Tindak balas berbahaya: Bertindak balas dengan agen pengoksida yang kuat. Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Bahan penguraian berbahaya: Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. 11. Maklumat Toksikologi Ketoksikan akut Penilaian ketoksikan akut: Tidak toksik selepas sekali ditelan. Tidak toksik selepas sekali terkena kulit Data eksperimen/dikira: LD50 tikus (melalui mulut): > 5,000 mg/kg (Garispanduan OECD 423) LD50 tikus (dermal): > 2,000 mg/kg (Garispanduan OECD 402) Kerengsaan Penilaian kesan merengsa: Boleh menyebabkan sedikit kerengsaan pada kulit. Tidak merengsakan mata. Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: merengsa sedikit (Garispanduan OECD 404) Kerosakkan/kerengsaan mata yang serius arnab: tidak merengsa (Garispanduan OECD 405) Pemekaan pernafasan/kulit Penilaian pemekaan: Kesan pemekaan kulit tidak diperhatikan dalam kajian haiwan. Data eksperimen/dikira: Ujian pemaksimum tikus kasturi marmut: Tidak memeka (Garispanduan OECD 406) Kemutagenan sel germa Penilaian kemutagenan: Tiada kesan mutagen didapati dalam pelbagai ujian dengan bakteria, Bahan tidak mutagen dalam kajian dengan mamalia. Kekarsinogenan Penilaian kekarsinogenan:

8 Mukasurat (Page): 8/21 Dalam kajian jangka panjang ke atas haiwan, apabila bahan, pada kepekatan yang tinggi, diberi makan kepada haiwan tersebut, tiada kesan karsinogen diperhatikan. Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Keputusan kajian haiwan tidak menunjukkan kesan gangguan kesuburan. Ketoksikan perkembangan Penilaian keteratogenan: Tiada petunjuk kesan ketoksikan/teratogen diperhatikan dalam kajian haiwan. Ketoksikan khusus organ sasaran (sekali pendedahan): Penilaian sekali STOT: Berdasarkan maklumat yang ada, ketoksikan organ sasaran yang khusus adalah tidak dijangka selepas sekali pendedahan. Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Kesan kepada ginjal tikus jantan dikesan selepas pendedahan berulang. Kesan tersebut adalah khusus kepada tikus jantan dan diketahui tidak berkaitan dengan manusia. Bahaya penyedutan Tidak boleh digunakan 12. Maklumat Ekologi Keekotoksikan Penilaian ketoksikan akuatik: Ada kemungkinan besar produk tidak memudaratkan organisma akuatik secara akut. Perencatan aktiviti degradasi di dalam enap cemar yang diaktifkan tidak dijangka akan berlaku semasa bahan berkepekatan rendah dimasukkan kedalam loji rawatan biologi. Ketoksikan kepada ikan: LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, statik) Diuji pada keterlarutan melebihi maksimum. Perincian kesan toksik berkaitan dengan kepekatan nominal. Invertebrat air: EC50 (48 h) > 100 mg/l, Daphnia magna (Garispanduan OECD 202, Bahagian 1, statik) Perincian kesan toksik berkaitan dengan kepekatan nominal. Keterlarutan produk adalah rendah dalam medium ujian. Eluat telah diuji. Tumbuhan akuatik:

9 Mukasurat (Page): 9/21 EC50 (72 h) > 100 mg/l (kadar pertumbuhan), Scenedesmus subspicatus (Garispanduan OECD 201, statik) Perincian kesan toksik berkaitan dengan kepekatan nominal. Keterlarutan produk adalah rendah dalam medium ujian. Eluat telah diuji. Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC20 (180 min) > 1,000 mg/l, Enap cemar diaktifkan, domestik, aerobik (DIN EN ISO 8192-OECD /302/EEC,P. C, akuatik) Ketoksikan kronik kepada invertebrata akuatik: Tiada kesan kepekatan yang diperhatikan (21 hari), >= mg/l, Daphnia magna (Garispanduan OECD 211, semistatik) Keterlarutan produk adalah rendah dalam medium ujian. Larutan akueus disediakan dengan pelarut telah diuji. Ujian kepekatan had sahaja (ujian HAD). Organisma hidupan tanah: LC50 (14 hari) > 1,000 mg/kg, Eisenia foetida (Garispanduan OECD 207, Tanah tiruan) Perincian kesan toksik berkaitan dengan kepekatan nominal. Tumbuhan darat: Tiada kesan kepekatan yang diperhatikan (20 hari) > mg/kg, Avena sativa (Garispanduan OECD 208) Tiada kesan kepekatan yang diperhatikan (21 hari) > mg/kg, Brassica napus (Garispanduan OECD 208) Tiada kesan kepekatan yang diperhatikan (21 hari) > mg/kg, Vicia sativa (Garispanduan OECD 208) Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Diikuti dengan pendedahan kepada tanah, penjerapan ke atas zarah tanah Keterusan dan boleh keterdegradasikan Maklumat penyingkiran: % Pembentukan CO2 relatif kepada nilai teori (60 hari) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobik, enap cemar diaktifkan, domestik, tidak disesuaikan) % Pembentukan CO2 relatif kepada nilai teori (28 hari) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobik, enap cemar diaktifkan, domestik, disesuaikan) Potensi Biotumpukan Potensi Biotumpukan: Faktor Kebiopekatan: 189 (30 hari), Brachydanio rerio (Garispanduan OECD 305 E) Tidak dijangka terakumulasi dalam organisma. Maklumat tambahan Nasihat ekotoksikologi lain: Jangan lepaskan sisa yang tidak dirawat ke dalam air semula jadi.

10 Mukasurat (Page): 10/ Maklumat Pelupusan Mestilah dibuang atau dibakar mengikut peraturan tempatan. Kod sisa menurut katalog sisa Eropah atau EWC (European waste catalog) tidak boleh ditentukan kerana ia bergantung pada penggunaannya. Pembungkusan tercemar: Bungkusan yang tercemar hendaklah dikosongkan sejauh yang boleh; kemudian ia boleh dihantar untuk dikitar semula setelah dibasuh bersih-bersih. 14. Maklumat Pengangkutan Pengangkutan domestik: Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan laut IMDG Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan udara IATA/ICAO Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan secara pukal menurut Lampiran II MARPOL73/78 dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan Peraturan lain Jika maklumat peraturan lain yang berkenaan tidak dinyatakan dibahagian lain didalam risalah data keselamatan ini, ianya akan dinyatakan bahagian ini.

11 Mukasurat (Page): 11/ Maklumat lain Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

12 Mukasurat (Page): 12/21 1. Identification of the chemical and of the supplier Efka PL 5646 Chemical name: 1,2-Cyclohexanedicarboxylic acid, diisononyl ester CAS Number: Use: Coating raw material for industrial applications Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: No need for classification according to GHS criteria for this product. Label elements and precautionary statement: The product does not require a hazard warning label in accordance with GHS criteria. Other hazards which do not result in classification: If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. See section 12 - Results of PBT and vpvb assessment. 3. Composition/information on ingredients Chemical nature 1,2-Cyclohexanedicarboxylic acid, diisononyl ester CAS Number:

13 Mukasurat (Page): 13/21 4. First-Aid Measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water. Note to physician: Symptoms: No significant symptoms are expected due to the non-classification of the product. Note to physician: Hazards: No hazards anticipated. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: carbon dioxide, dry powder, water spray, foam Specific hazards: The product is combustible. Cool endangered containers with water-spray. Special protective equipment: Wear a self-contained breathing apparatus. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. 6. Accidental Release Measures Personal precautions: Handle in accordance with good industrial hygiene and safety practice. Environmental precautions: Discharge into the environment must be avoided.

14 Mukasurat (Page): 14/21 Methods for cleaning up or taking up: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling Ensure thorough ventilation of stores and work areas. Storage Further information on storage conditions: Containers should be stored tightly sealed in a dry place. 8. Exposure controls and personal protection Components with occupational exposure limits none Personal protective equipment Respiratory protection: Respiratory protection not required. Hand protection: Chemical resistant protective gloves (EN 374) nitrile rubber (NBR) mm coating thickness Manufacturer's directions for use should be observed because of great diversity of types. Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

15 Mukasurat (Page): 15/21 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: ph value: liquid colourless almost odourless not determined not applicable, of very low solubility pour point: -54 C (DIN ISO 3016) boiling temperature: approx. 394 C (1,013 hpa) Cannot be distilled without decomposition at normal pressure. (Directive 92/69/EEC, A.2) Flash point: 224 C When exposed to high temperatures over a long period of time, formation of outgassing flammable decomposition products may occur. Evaporation rate: Value can be approximated from Henry's Law Constant or vapor pressure. Flammability (solid/gas): not readily ignited Lower explosion limit: As a consequence of the thermal decomposition behavior (see Thermal decomposition) it is not possible to determine meaningful figures expressed in units of volume- % when applying the standard DIN EN 1839 for determination of the lower explosion limit., Based on a theoretical assessment, it can be assumed that the vapours and decomposition products released from this liquid may form explosible mixtures upon mixing with air at concentrations >= 40 g/nm3 (temperature of mixture 20 C ) or >= 33 g/nm3 (temperature of mixture 200 C). (Directive 92/69/EEC, A.9, closed cup) (BASF expert judgement)

16 Mukasurat (Page): 16/21 (approx. 170 C, approx hpa) The lower explosion point of the substance/mixture has been determined. The explosion point describes the temperature of a flammable liquid at which the concentration of the saturated vapour mixed with air equals the lower explosion limit. (DIN EN 15794, air) Upper explosion limit: As a consequence of the thermal decomposition behaviour (see Thermal decomposition) the determination of the lower explosion point according to standard DIN EN does not generate a globally meaningful value. As a consequence of the thermal decomposition behavior (see Thermal decomposition) it is not possible to determine the upper explosion limit according to standard DIN EN For liquids not relevant for classification and labelling. Ignition temperature: 330 C (Directive 92/69/EEC, A.15) Thermal decomposition: When exposed to high temperatures over a long period of time, formation of outgassing flammable decomposition products may occur. Self ignition: The substance does not initiate an exothermic reaction under test conditions. Temperature: 20 C not self-igniting Test type: Self-ignition at high temperatures. (Method: other) Test type: Spontaneous selfignition at room-temperature. Explosion hazard: not explosive (other) Fire promoting properties: not fire-propagating (other) Vapour pressure: < hpa (20 C) (Directive 92/69/EEC, A.4) Density: g/cm3 (20 C) Relative vapour density (air): not determined (DIN 51757)

17 Mukasurat (Page): 17/21 Solubility in water: < 0.02 mg/l (25 C) Solubility (qualitative) solvent(s): organic solvents soluble Partitioning coefficient n-octanol/water (log Pow): 10 (25 C) Adsorption/water - soil: log KOC: 6.59 Adsorption to solid soil phase is expected. Surface tension: not applicable (Directive 92/69/EEC, A.8) (OECD Guideline 121) Viscosity, dynamic: mpa.s (20 C) The value was determined by calculation from the detected kinematic viscosity. (calculated (from kinemetic viscosity)) Molar mass: g/mol 10. Stability and Reactivity Conditions to avoid: No special precautions other than good housekeeping of chemicals. Thermal decomposition: When exposed to high temperatures over a long period of time, formation of outgassing flammable decomposition products may occur. Substances to avoid: strong oxidizing agents Corrosion to metals: No corrosive effect on metal. Hazardous reactions: Reacts with strong oxidizing agents. No hazardous reactions if stored and handled as prescribed/indicated. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact.

18 Mukasurat (Page): 18/21 Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg (OECD Guideline 423) LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402) Irritation Assessment of irritating effects: May cause slight irritation to the skin. Not irritating to the eyes. Experimental/calculated data: Skin corrosion/irritation rabbit: Slightly irritating. (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405) Respiratory/Skin sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. Experimental/calculated data: Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406) Germ cell mutagenicity Assessment of mutagenicity: No mutagenic effect was found in various tests with bacteria, microorganims and mammalian cell culture. The substance was not mutagenic in studies with mammals. Carcinogenicity Assessment of carcinogenicity: In long-term animal studies in which the substance was given in high concentrations by feed, a carcinogenic effect was not observed. Reproductive toxicity Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. Developmental toxicity Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

19 Mukasurat (Page): 19/21 Assessment of repeated dose toxicity: Effects on the kidney of male rats were detected after repeated exposure. These effects are specific for the male rat and are known to be of no relevance to humans. Aspiration hazard not applicable 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish: LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, static) Tested above maximum solubility. The details of the toxic effect relate to the nominal concentration. Aquatic invertebrates: EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An eluate has been tested. Aquatic plants: EC50 (72 h) > 100 mg/l (growth rate), Scenedesmus subspicatus (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An eluate has been tested. Microorganisms/Effect on activated sludge: EC20 (180 min) > 1,000 mg/l, activated sludge, domestic, aerobic (DIN EN ISO 8192-OECD /302/EEC,P. C, aquatic) Chronic toxicity to aquatic invertebrates: No observed effect concentration (21 d), >= mg/l, Daphnia magna (OECD Guideline 211, semistatic) The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has been tested. Limit concentration test only (LIMIT test). Soil living organisms: LC50 (14 d) > 1,000 mg/kg, Eisenia foetida (OECD Guideline 207, artificial soil) The details of the toxic effect relate to the nominal concentration. Terrestrial plants: No observed effect concentration (20 d) > mg/kg, Avena sativa (OECD Guideline 208) No observed effect concentration (21 d) > mg/kg, Brassica napus (OECD Guideline 208)

20 Mukasurat (Page): 20/21 No observed effect concentration (21 d) > mg/kg, Vicia sativa (OECD Guideline 208) Mobility Assessment transport between environmental compartments: Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected. Persistence and degradability Elimination information: % CO2 formation relative to the theoretical value (60 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobic, activated sludge, domestic, non-adapted) % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobic, activated sludge, domestic, adapted) Bioaccumulation potential Bioaccumulation potential: Bioconcentration factor: 189 (30 d), Brachydanio rerio (OECD Guideline 305 E) Accumulation in organisms is not to be expected. Additional information Other ecotoxicological advice: Do not release untreated into natural waters. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage. Contaminated packaging: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations

21 Mukasurat (Page): 21/21 Air transport IATA/ICAO Not classified as a dangerous good under transport regulations Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated 15. Regulatory Information Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. 16. Other Information Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.