SAFETY DATA SHEET Adhesion Promoter

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Leather Finishing Chemical 1.3. Details of the supplier of the safety data sheet Supplier Gliptone Unit 29, Hunt End Industrial Estate, Dunlop Road, Redditch, B97 5XP Emergency telephone number Emergency telephone +44 (0) ( Mon-Fri) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Health hazards Environmental hazards 2.2. Label elements Hazard statements EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction Other hazards This product does not contain any substances classified as PBT or vpvb. SECTION 3: Composition/information on ingredients 3.2. Mixtures Di(ethylene glycol) ethyl ether 1-5% CAS number: EC number: Classification 1/6

2 1,2-benzisothiazol-3(2H)-one <1% CAS number: EC number: M factor (Acute) = 1 Classification Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Eye contact Move affected person to fresh air at once. Get medical attention if any discomfort continues. Keep affected person warm and at rest. Do not induce vomiting unless under the direction of medical personnel. Rinse mouth thoroughly with water. Give plenty of water to drink. Get medical attention if any discomfort continues. If in doubt, get medical attention promptly. Remove contamination with soap and water or recognised skin cleansing agent. Get medical attention if any discomfort continues. Get medical attention if symptoms are severe or persist after washing. Remove any contact lenses and open eyelids wide apart. Rinse cautiously with water for several minutes. Get medical attention immediately. Continue to rinse Most important symptoms and effects, both acute and delayed Ingestion Skin contact Eye contact There may be soreness and redness of the mouth and throat There may be irritation and redness at site of contact May cause irritation and redness 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Use water spray to keep containers cool Use fire-extinguishing media suitable for the surrounding fire Special hazards arising from the substance or mixture Specific hazards Hazardous combustion products May give off noxious and toxic fumes in a fire Toxic gases or vapours Advice for firefighters Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 2/6

3 Personal precautions Avoid inhalation of vapours. Avoid contact with eyes and prolonged skin contact. Wear protective clothing and gloves. Keep unnecessary and unprotected personnel away from the spillage Environmental precautions Environmental precautions Not considered to be a significant hazard due to the small quantities used. Avoid discharge into drains or watercourses or onto the ground. Contain the spillage using bunding 6.3. Methods and material for containment and cleaning up Methods for cleaning up Absorb into dry earth or sand. Transfer to a suitable container. Transfer to closable, labelled salvage container for disposal 6.4. Reference to other sections Reference to other sections For personal protection, see Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid contact with eyes and prolonged skin contact. Avoid inhalation of vapours and spray/mists. Provide adequate ventilation. Do not use in confined spaces without adequate ventilation and/or respirator Conditions for safe storage, including any incompatibilities Storage precautions Keep container tightly closed, in a cool, well ventilated place. Keep out of the reach of children. The storage area floor should be leak-tight, jointless and not absorbent Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits Di(ethylene glycol) ethyl ether Long-term exposure limit (8-hour TWA): WEL 25 WEL = Workplace Exposure Limit 8.2. Exposure controls Protective equipment Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Environmental exposure controls Avoid inhalation of vapours and spray/mists. Wear eye protection. Wear protective gloves. Wear protective clothing. Ensure all engineering measures mentioned in section 7 of this SDS are in place SECTION 9: Physical and Chemical Properties 3/6

4 9.1. Information on basic physical and chemical properties Appearance Colour Opaque liquid. Off-white. ph ph (concentrated solution): 8.5 Initial boiling point and range 102 C Flash point 96 C Viscosity non-viscous 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reactivity Stable under recommended transport or storage conditions Chemical stability Stability Under normal conditions of storage and use the product is stable Possibility of hazardous reactions Possibility of hazardous reactions Hazardous reactions will not occur under normal transport or stoarage conditions Conditions to avoid Conditions to avoid Avoid heat Incompatible materials Materials to avoid Strong oxidising agents. Strong acids Hazardous decomposition products Hazardous decomposition products In combustion emits toxic fumes SECTION 11: Toxicological information Information on toxicological effects Toxicological effects No data recorded. Toxicological information on ingredients. Di(ethylene glycol) ethyl ether Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg) Species 10,502.0 Rat ATE oral (mg/kg) 10,502.0 SECTION 12: Ecological Information Ecotoxicity The product contains a substance which may have hazardous effects on the environment Toxicity Ecological information on ingredients. 4/6

5 Di(ethylene glycol) ethyl ether Acute toxicity - fish Acute toxicity - aquatic invertebrates LC₅₀, 96 hours: 9650 mg/l, Pimephales promelas (Fat-head Minnow) LC₅₀, 48 hours: 3340 mg/l, Daphnia magna Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Disposal methods No specific disposal method required. Collect and place in suitable waste disposal containers and seal securely. Dispose of waste via a licensed waste disposal contractor. SECTION 14: Transport information UN number Non Hazardous UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended) Chemical safety assessment SECTION 16: Other information Revision date 07/11/2016 Revision 2 Supersedes date 25/10/2016 SDS number /6

6 Hazard statements in full H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H400 Very toxic to aquatic life. EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction. 6/6