1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Transcription

1 SAFETY DATA SHEET Preparation Date 12-Dec-2013 Revision Date 16-Dec-2013 Revision Number 2 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Identifier Product Name ACETOSTAB 326 Other means of identification Product Code CAS Number Formula C17H18ClN3O Synonyms 2-(5-chloro-2H-benzotriazol-2-yl)-6-(1,1-dimethylethyl)-4-methyl-(9Cl); 2-(2'-Hydroxy-3'-tert-butyl-5'-methyl phenyl)-5-chlorobenzotriazole Recommended use of the chemical and restrictions on use Recommended Use Uses advised against Coatings Repeated contact with food. Avoid prolonged contact with eyes, skin, and clothing. Details of the supplier of the safety data sheet Supplier Address ACETO CORPORATION 4 Tri Harbor Court Port Washington, NY Phone: (516) Fax: (516) aceto@aceto.com Emergency Telephone Number(s) ChemTrec: Outside of the United States: Classification 2. HAZARDS IDENTIFICATION Skin Corrosion/Irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview Page 1 / 9

2 Signal Word Warning Hazard statements Causes skin irritation Causes serious eye irritation May cause respiratory irritation. May cause drowsiness or dizziness Appearance Light yellow Physical State Powder Odor Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None known Other Information 100 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Formula 2-(5-chloro-2H-benzotriazol-2-yl)-6-(1,1-dimethylethyl)-4-methyl-(9Cl); 2-(2'-Hydroxy-3'-tert-butyl-5'-methyl phenyl)-5-chlorobenzotriazole C17H18ClN3O Page 2 / 9

3 Chemical Name CAS-No Weight % North American Hazard Indicator True 2-(5-chloro-2H-benzotriazol-2-yl)-6-(1,1-dimethyleth yl)-4-methyl- First Aid Measures 4. FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Protection of First-aiders Show this safety data sheet to the doctor in attendance. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician if necessary. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Consult a physician if necessary. Move to fresh air. If breathing is difficult, give oxygen. Consult a physician if necessary. Rinse mouth. Never give anything by mouth to an unconscious person. Consult a physician. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Most important symptoms and effects, both acute and delayed Main Symptoms Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Unsuitable Extinguishing Media Hazardous Combustion Products Water spray. Carbon dioxide (CO2). Dry powder. Foam. Thermal decomposition or combustion may produce hazardous gases and/or materials. Explosion Data Sensitivity to mechanical impact Not available. Sensitivity to static discharge Not available. Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Page 3 / 9

4 Personal precautions, protective equipment and emergency procedures Personal Precautions Environmental Precautions Evacuate personnel to safe areas. Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Local authorities should be advised if significant spillages cannot be contained. Methods and material for containment and cleaning up Methods for Cleaning up Evacuate personnel to safe areas. Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Precautions for Safe Handling Handling Use only in an area equipped with a safety shower. Ensure adequate ventilation. Do not breathe vapours/dust. Avoid contact with skin and eyes. Conditions for safe storage, including any incompatibilities Storage Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. Strong oxidizing agents. Strong acids. Strong bases. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical Name 2-(5-chloro-2H-benzotriazol-2-yl)-6-(1,1-dim ethylethyl)-4-methyl ACGIH TLV OSHA PEL NIOSH IDLH Appropriate engineering controls Individual protection measures, such as personal protective equipment Eye/face Protection Skin and body protection Respiratory Protection General Hygiene Considerations Tightly fitting safety goggles. Face-shield. Wear protective gloves and protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Light yellow Physical State Powder Odor Odor Threshold Page 4 / 9

5 ACETOSTAB 326 Revision Date 16-Dec-2013 Property Values ph No data available Melting/freezing point C Boiling Point/Range Flash Point > 150 C Evaporation Rate Not available Flammability Limits in Air upper flammability limit lower flammability limit Not available Vapor Pressure Vapor Density Not available Specific Gravity 1.32 Water Solubility C Solubility in other solvents Partition coefficient: n-octanol/waternot available Autoignition temp ( C) 400 C Decomposition temperature No data available Viscosity, kinematic Viscosity, dynamic Not available Explosive Properties Oxidizing Properties Remarks Method Literary Reference Estimated Other Information Softening Point Molecular Weight VOC Content Density Bulk Density STABILITY AND REACTIVITY Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Not applicable. Stable under recommended storage conditions Heat, flames and sparks. Strong oxidizing agents. Strong acids. Strong bases. Carbon Dioxide (CO2) Carbon Monoxide Nitrogen Oxides (NOx) Hydrogen Chlorides Possibility of Hazardous Reactions None under normal processing 11. TOXICOLOGICAL INFORMATION Product Information To the best of our knowledge, the complete toxicological properties have not been thoroughly investigated. Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation (5-chloro-2H-benzotriazol-2-yl)-6-( 1,1-dimethylethyl)-4-methyl Page 5 / 9

6 ACETOSTAB 326 Revision Date 16-Dec-2013 Information on likely routes of exposure Eyes Skin Inhalation Ingestion Irritating to eyes. Avoid contact with eyes. May be harmful by skin contact. Irritating to skin. Avoid contact with skin. May be harmful by inhalation. Irritating to mucous membranes. Irritating to respiratory system. Avoid breathing dust. May be harmful if swallowed. Do not ingest. Information on toxicological effects Symptoms Delayed and immediate effects as well as chronic effects from short and long-term exposure Eye damage/irritation Skin Corrosion/Irritation Sensitization Reproductive Effects Mutagenic Effects Developmental Effects STOT - single exposure STOT - Repeated Exposure Chronic Toxicity Aspiration Hazard Avoid repeated exposure. Numerical measures of toxicity - Product Information Acute Toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Avoid release to the environment. 100 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence / Degradability Bioaccumulation / Accumulation Page 6 / 9

7 Mobility in Soil 13. DISPOSAL CONSIDERATIONS Waste treatment methods Waste Disposal Method Contaminated Packaging Contact waste disposal services. Dispose of in accordance with local regulations. Dispose of in accordance with local regulations. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION DOT TDG MEX ICAO IATA IMDG/IMO RID ADR ADN International Inventories U.S.A. (TSCA) Canada (DSL) EU (EINECS) EU (ELINCS) Japan (ENCS) China Korea (KECL) Philippines (PICCS) Australia (AICS) 15. REGULATORY INFORMATION Does not Comply Chemical Name U.S.A. (TSCA) Canada (DSL) EU (EINECS) EU (ELINCS) Present Present Present - 2-(5-chloro-2H-benzotriazol- 2-yl)-6-(1,1-dimethylethyl)-4- methyl- Chemical Name Japan (ENCS) China Korea (KECL) Philippines (PICCS) Australia (AICS) Page 7 / 9

8 Present (5)-545 Present Present Present Present 2-(5-chloro-2H-benzotriazol- 2-yl)-6-(1,1-dimethylethyl)-4- methyl- Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes No No No No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. State Right-to-Know This product does not contain any State Right-to-Know chemicals. U.S. EPA Label Information EPA Pesticide Registration Number Not applicable Page 8 / 9

9 Canada WHMIS Statement This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION NFPA Health 1 Flammability 0 Instability 0 Physical Hazard 0 Preparation Date 12-Dec-2013 Revision Date 16-Dec-2013 Revision Summary Not available Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 9 / 9