M A T E R I A L S A F E T Y D A T A S H E E T Page 1 of 5

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1 M A T E R I A L S A F E T Y D A T A S H E E T Page 1 of 5 1. Product And Company Identification Supplier Manufacturer Alliance Trading, Inc. Advantis Technologies, Inc. 109 Northpark Blvd., 4th Floor 1400 Bluegrass Lakes Parkway Covington, LA United States Alpharetta, GA United States Telephone Number: (985) Telephone Number: (770) FAX Number: (985) FAX Number: (770) Web Site: Issue Date: 12/15/2005 Product Name: Algaecide 60% Poly Chemical Name: Poly(oxyethylene(Dimethyliminio)Ethylene(Dimethyliminio)Ethylene Dichloride) Chemical Family: Polymeric Quaternary Ammonium Compound MSDS Number: 4 2. Composition/Information On Ingredients Ingredient CAS Percent Of Name Number Total Weight Poly{oxyethylene (dimethyliminio) Ethylene (dimethyliminio) ethylene dichloride} Ingredients listed in this section have been determined to be hazardous as defined in 29CFR Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% of more or the composition. Information on proprietary materials is available in 29CFR (i)(1). 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact, Eye Contact, Inhalation Eye Hazards Slightly hazardous in case of eye contact (irritant). Skin Hazards Slightly hazardous in case of skin contact (irritant). Non-sensitizer for skin. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Ingestion Hazards Ingestion is not expected to be a primary route of exposure. Inhalation Hazards Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure. Subchronic (Target Organ Effects) May cause damage to the following organs: upper respiratory tract, skin, eyes. Chronic/Carcinogenicity Effects Not tested by the manufacturer. Not shown as a carcinogen by OSHA, IARC, or NTP. A two year rat carcinogenicity study showed a slight increase in c-cell adenomas in female rats. Studies with male rats and male and female mice did not show any evidence of carcinogenic response. This product is not considered a carcinogen. Signs And Symptoms Irritation of Eyes and Respiratory Passages

2 M A T E R I A L S A F E T Y D A T A S H E E T Page 2 of 5 3. Hazards Identification - Continued Conditions Aggravated By Exposure None Known First Aid (Pictograms) 4. First Aid Measures Eye Flush immediately with copious amounts of tap water or normal saline (minimum of 15 minutes). Take exposed individual to a health care professional, preferably an opthalmologist, for further evaluation. Skin Wash exposed area with plenty of soap and water. Repeat washing. Remove contaminated clothing and wash thoroughly before reuse. If irritation persists consult a health professional. Ingestion DO NOT INDUCE VOMITING. Rinse with copious amounts of water or milk, first. Irrigate the esophogus and dilute stomach contents by slowly giving one to two glasses of water or milk. Avoid giving alcohol or alcohol related products. In cases where the individual is semi-comatose, comatose, or is convulsing, DO NOT GIVE FLUIDS BY MOUTH. In case of intentional ingestion of the product, seek medical assistance immediately; take individual to nearest medical facility. Inhalation If exposure by inhalation is suspected, immediately move exposed individual to fresh air. If individual experiences nausea, headache, dizziness, has difficulty breathing or is cyanotic, seek a health care professional immediately. Note To Physician No Specific Antidote is known. Treat Symptoms. Evaluate Principal Route of Entry, Seek appropriate medical attention. Never give anything by mouth to an unconscious person. Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: >212 F Flash Point Method: Closed Cup Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. 6. Accidental Release Measures Contain and/or absorb spill with inert material (e.g. sand, vermiculite). Avoid release to the environment. Do not flush to sewer.

3 M A T E R I A L S A F E T Y D A T A S H E E T Page 3 of 5 Handling & Storage (Pictograms) 7. Handling And Storage Handling Precautions Avoid contact with eyes. Wash thoroughly after handling. Wash hands before eating, drinking, or smoking. Storage Precautions Store in a cool dry place. Keep out of reach of children. Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presented by this material. Do not contaminate Water Food or Feed by storage or cleaning equipment. Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection General room ventilation is normally adequate. 9. Physical And Chemical Properties Appearance Clear, pale yellow liquid Odor Mild Chemical Type: Mixture Physical State: Liquid Melting Point: 32 F <0 C Boiling Point: 212 F >100 C Specific Gravity: 1.15 g/cm3 Percent Volitales: Not established Vapor Pressure: Not established ph Factor: 6-8 Sol ubility: Easily soluble in cold/hot water Vi scosity: Kinetic: 125cS Evaporation Rate: Not established

4 M A T E R I A L S A F E T Y D A T A S H E E T Page 4 of Stability And Reactivity Sta bility: Stable under normal conditions of use and storage Incompatible Materials Anionic Polymers Hazardous Decomposition Products Carbon monoxide may be formed upon burning. 11. Toxicological Information Skin Effects Dermal LD50 = >2000 mg/kg Rabbit Acute Oral Effects Oral LD50 = 1951 mg/kg Male rat Oral LD50 = 2587 mg/kg Female rat Acute Inhalation Effects Inhalation LD50 = 2.9ppm (4 hours) Rat 12. Ecological Information Acute Toxicity - Fish And Invertebrates LC50 = 0.37 mg/l 48 hours Invertebrate LC50 = 0.26 mg/l 96 hours Fathead Minnow LC50 = 0.21 mg/l 96 hours Bluegill sunfish LC50 = mg/l 96 hours Rainbow Trout LC50 = >600 mg/l 96 hours Sheepshead minnow LC50 = 13 mg/l 96 hours Mysid shrimp 13. Disposal Considerations Refer to applicable local, state and federal regulations as well as industry standards. 14. Transport Information Proper Shipping Name Environmentally Hazardous Substance, Liquid, n.o.s. (Poly[oxyethylene(dimethyliminio)ethylene(dimethyliminio)ethylene dichloride]), Marine Pollutant Hazard Class 9, PGIII DOT Identification Number UN3082 Additional Shipping Paper Description North American Emergency Response Guide No. 171 Not regulated by DOT for ground or air shipments [see exception for marine pollutants 49CFR171.4(c)]. 15. Regulatory Information State Regulations California Proposition 65: This product had been reviewed for Prop 65 components and the following applies: Warning: This product may contain substance(s) which are known to the State of California to cause cancer or reproductive harm. (Contents may contain trace levels of (<10 ppm) of Dichloroethyl ether, 1,4-Dioxane and (<20 ppb) N-nitrosodimethylamine). Trace contaminants from Poly[oxyethylene(diamethlyimino)ethylene(diethylimino) ethylene dichloride)

5 M A T E R I A L S A F E T Y D A T A S H E E T Page 5 of 5 NFPA HMIS HEALTH 1 FLAMMABILITY 1 REACTIVITY 1 PERSONAL PROTECTION B 16. Other Information Revision/Preparer Information MSDS Preparer: JHW Reference Documentation Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). Printed Using MSDS Generator 2000