SAFETY DATA SHEET Prepared by Duro Dyne December 20, 2013

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1 SAFETY DATA SHEET Prepared by Duro Dyne December 20, 2013 HEALTH 1 FLAMMABILITY 0 REACTIVITY 1 SPECIAL HAZARD NONE 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade name: DURO DYNE ADHESIVE Product Identifier: PAW40 (LEED Compliant) Item #: 5091 Supplier Details: DURO DYNE CORPORATION 81 Spence Street Bay Shore, NY Information Phone No: Emergency Phone No: 2. HAZARDS IDENTIFICATIONS (CHEMTREC) 2.1 Emergency Overview: Immediate Health, Physical and Environmental Hazards: 2.2 Potential Health Effects: Eye Contact: Skin Contact: Inhalation: Ingestion: Closed containers exposed to heat from fire may build pressure and explode. Mild Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat and pain. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. 3. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT C.A.S. No. % by Wt. Acrylic Polymer Not Determined ,1,1,2-Tetrafluoroethane <10% Nitrogen <3% Page 1 of 5

2 4. FIRST AID MEASURES 4.1 First Aid Procedures The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed: Eye Contact: Skin Contact: Inhalation: If Swallowed: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Remove person to fresh air. If signs/symptoms develop, get medical attention. Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 5. FIRE FIGHTING MEASURES 5.1 Flammable Properties Flammability: Auto ignition Temperature: Flash Point: Flammable Limits-LEL: Flammable Limits-UEL: Non-Flammable per industry standard flame projection test. >743ºC (>1369ºF) 5.2 Extinguishing Media: Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 Protection of Fire Fighters: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Firefighters and other exposed to vapors should wear self-contained breathing apparatus. Water spray may be used for cooling to prevent possible pressure build-up when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURE Page 2 of 5

3 Accidental Release Measures: Evacuate non-essential personnel. Ventilate the area. Dike around spilled material. Collect material in approved containers, and dispose of in accordance with local, state and federal laws and regulations. For Small Quantities: Mop up or absorb inert material and place in containers. 7. HANDLING AND STORAGE 7.1 Handling: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid eye contact with vapors, mists, or spray. Keep out of reach of children. Use general ventilation. If ventilation is not adequate, use respiratory protection equipment. 7.2 Storage: Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing agents. Keep from freezing. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Engineering Controls: Use with appropriate local exhaust ventilation. Use general ventilation and/or local exhaust ventilation or if ventilation is not adequate, use protection equipment. 8.2 Personal Protective Equipment (PPE): Eye/Face Protection: Skin Protection: Respiratory Protection: Prevention of Swallowing: Avoid eye contact with vapors, mists or spray. The following eye protection(s) are recommended: Safety Glasses. Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Gloves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA), Polyethylene/Ethylene Vinyl Alcohol. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 Exposure Guidelines: Ingredient: 1,1,1,2-Tetrafluoroethane Authority: AIHA Type: TWA Limit: 1000 ppm Page 3 of 5

4 Sources of Exposure Limit Data: AIHA: American Industrial Hygience Association Workplace Environmental Exposure Level (WEEL) 9. PHYSICAL AND CHEMICAL PROPERTIES Odor, Color: Typical acrylic odor, white color. Boiling Point: -15ºF (-26ºC) Vapor Density: Not Determined Vapor Pressure: Not Determined Specific Gravity: 1.00 to 1.04 gms/cc (8.3 to 8.7 lbs/gal) Solubility in Water: Soluble Percent Volatile: <50% Volatile Organic Compounds: 0 gm/l 10. STABILITY AND REACTIVITY Stability: Materials and Conditions to Avoid: Hazardous Polymerization : Stable. Sparks and/or flames. Hazardous polymerization will not occur. Hazardous Decomposition or By-Products: Substances Hydrocarbons Formaldehyde Carbon Monoxide Carbon Dioxide Hydrogen Fluoride Condition 11. TOXICOLOGICAL INFORMATION Carcinogenicity: No data available. 12. ECOLOGICAL INFORMATION Not determined. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in accordance with local, state and federal laws and regulations. Page 4 of 5

5 14. TRANSPORTATION INFORMATION ***** HAZ MAT ***** UN3500 CHEMICAL UNDER PRESSURE, N.O.S., (1,1,1,2-Tetrafluoroethane) REAGULATORY INFORMATION US Regulatory Information 311/312 Hazard Categories: Fire Hazard: No Pressure Hazard: Yes Reactivity Hazard: No Immediate Hazard: Yes Delayed Hazard: Yes State Regulations California Proposition 65:. 16. OTHER INFORMATION Hazard Rating: Health: 1 Flammability: 0 Reactivity: 1 Special Hazard: Date SDS Prepared: 8/21/2012 THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO BE ACCURATE. BECAUSE SOME OF THE INFORMATION IS DERIVED FROM INFORMATION PROVIDED TO DURO DYNE CORPORATION FROM ITS SUPPLIERS, DURO DYNE CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SINCE THE USE OF THIS INFORMATION AND THE CONDITIONS AND USE OF THIS PRODUCT ARE CONTROLLED BY THE USER, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. THE INFORMATION IS SUPPLIED FOR YOUR INFORMATION AND CONSIDERATION AND DURO DYNE CORPORATION ASSUMES NO RESPONSIBILITY FOR USE OR RELIANCE THEREON. IT IS THE RESPONSIBILITY OF THE USER OF DURO DYNE CORPORATION PRODUCTS TO COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS. Page 5 of 5

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