RUBBEDIN PTY LTD MATERIAL SAFETY DATA SHEET

Transcription

1 Classified as non-hazardous according to criteria of Worksafe Australia SECTION 1 PRODUCT IDENTIFICATION Product Name: Other Names: Manufacturer s Product Code: WASHING MACHINE MAGIC 100g sachet Distributor: Rubbedin Pty Ltd Emergency Phone No: Regular Phone No: Fax: rubbedin@rubbedin.com.au Address: Unit 1/43 Neumann Road Capalaba QLD 4157 SECTION 2 HAZARDS IDENTIFICATION This material is classified as non-hazardous according to criteria of NOHSC. This product is NOT classified as Dangerous Goods according to the Australian Dangerous Goods (ADG) Code. This product is classified as a Scheduled 5 Poison according to the SUSDP. Approved Criteria Classification Not hazardous UN Number ADG Classification Shipping Name ADG Subsidiary Risk Hazchem Code Packing Group SUSDP Classification S5 CAUTION EMERGENCY OVERVIEW Colour white Odour Fragrant Physical Description Uniform granules Viscosity solid Major Health Hazards None known SECTION 3 INGREDIENTS Ingredients determined not to be hazardous are present in concentrations that do not exceed the relevant cut-off concentrations as found from NOHSC publication List of Designated Hazardous Substances or have been found NOT to meet the criteria of a hazardous substance as defined in the NOHSC publication Approved Criteria for Classifying Hazardous Substances. Ingredients: CAS Number: Proportion: Exposure Standards TWA Exposure Standards STEL Sulfamic acid < 10 % w/w not set not set Citric acid > 60% w/w 1 mg/m 3 2 mg/m 3 Ingredients determined to be Various non-hazardous 10-30% w/w not set not set The TWA exposure value is the Time Weighted Average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term peak is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly. MSDS Washing Machine Magic Date of Issue: 11/05/2009 Page 1 of 7

2 SECTION 4 FIRST AID MEASURES Scheduled Poisons Poisons Information Centre in each Australian State capital city or in Christchurch, New Zealand can provide additional assistance for scheduled poisons. (Phone Australia or New Zealand ). First Aid Facilities Normal washroom facilities. Skin contact Wash skin with plenty of water. Remove contaminated clothing and wash before re-use. Seek medical advice (e.g. doctor) if irritation, burning or redness develops. Eye contact Immediately irrigate with copious quantities of water for at least 20 minutes. Eyelids to be held open. Seek medical advice (e.g. ophthalmologist). Ingestion Do NOT induce vomiting. Do NOT attempt to give anything by mouth to an unconscious person. Rinse mouth thoroughly with water immediately. Give water to drink. If vomiting occurs, give further water to achieve effective dilution. Seek medical advice (e.g. doctor). Inhalation Remove victim to fresh air away from exposure. Obtain medical attention if symptoms occur. Advice to Doctor Aggravated Medical Conditions Treat symptomatically. All treatments should be based on observed signs and symptoms of distress of the patient. Poisons Information Centre in each Australian State capital city or in Christchurch, New Zealand can provide additional assistance for scheduled poisons. None known. SECTION 5 FIRE AND EXPLOSION DATA Fire and Explosion Hazards Extinguishing Media Fire Fighting Flash Point Not combustible. However if involved in a fire will emit toxic fumes. Use an extinguishing media suitable for surrounding fires. Keep containers exposed to extreme heat cool with water spray. Fire fighters to wear self-contained breathing apparatus if risk of exposure to products of combustion or decomposition. Evacuate area - move upwind of fire. None does not support combustion. SECTION 6 ACCIDENTAL RELEASE MEASURES Emergency Procedures Occupational Release Waste Disposal: No HAZCHEM code. Minor spills do not normally need any special clean-up measures. In the event of a major spill, prevent spillage from entering drains or water courses. Wear protective equipment to prevent skin and eye contact and breathing in dust. Work up wind or increase ventilation. Cover with damp absorbent (inert material, sand or soil). Sweep or vacuum up, but avoid generating dust. Collect and seal in properly labelled containers or drums for disposal. Wash area down with excess water. Refer to State Land Waste Management Authority. MSDS Washing Machine Magic Date of Issue: 11/05/2009 Page 2 of 7

3 SECTION 7 HANDLING AND STORAGE Handling Storage Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers closed at all times. Avoid physical damage to containers. Always wash hands with water after handling. Store in a cool, dry, place with good ventilation. Avoid storing in aluminium and light alloy containers. Store away from incompatible materials (Section 10). Keep containers closed at all times check regularly for leaks. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limits Biological Limit Value Engineering Controls Personal Protective Equipment Eye Protection Skin Protection Protective Material Types National Occupational Exposure Limits, as published by National Occupational Health & Safety Commission: Time-weighted Average (TWA): None established for specific product. See SECTION 3 for Exposure Limits of individual ingredients. Short Term Exposure Limit (STEL): None established for specific product. See SECTION 3 for Exposure Limits of individual ingredients. Nuisance dust: 8hr TWA = 10 mg/m3 as published by the National Occupational Health and Safety Commission. None established for product. Ensure ventilation is adequate to maintain air concentrations below exposure standards. Avoid generating dusts or mists of the product. Use only in a well-ventilated area. Ensure airflow, where this product is used, is directed away from the operators. This product is not classified as hazardous according to the criteria of Worksafe Australia. Use good occupational work practice. The use of protective clothing and equipment depends upon the degree and nature of exposure. Final choice of appropriate protection will vary according to individual circumstances i.e. methods of handling or engineering controls and according to risk assessments undertaken. The following protective equipment should be available; Generally not required to handle the product as per label directions. The use of safety glasses with side shield protection, goggles or face shield is recommended to handle in quantity, cleaning up spills, decanting, etc. Contact lenses pose a special hazard ; soft lenses may absorb irritants and all lenses concentrate them. Generally not required to handle the product as per label directions. Overalls, work boots and elbow length gloves are recommended for handling the concentrated product (as per AS/NZS 2161, or as recommended by supplier) to handle in quantity, cleaning up spills, decanting, etc. Material suitable for detergent contact Butyl rubber, Natural Latex, Neoprene, PVC, and Nitrile. MSDS Washing Machine Magic Date of Issue: 11/05/2009 Page 3 of 7

4 Respirator RUBBEDIN PTY LTD Not required for normal cleaning operations. If dust exists, wear dust mask/respirator meeting the requirements of AS/NZS 1715 and AS/NZS SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Physical State powder Colour white Odour fragrant odour Specific Gravity 25 C Boiling Point Not available Freezing Point Not available Vapour Pressure Not available Vapour Density Not available Flash Point Not flammable Flammable Limits None Water Solubility Volatile Organic Compounds (VOC) Miscible in all proportions 0 % v/v ph Coefficient of Water/Oil Distribution 1.5 1% sol n Not available Viscosity solid Odour Threshold Not available Evaporation Rate Not available Per Cent Volatile Ca 4 % v/v SECTION 10 STABILITY AND REACTIVITY DATA Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Reactions Stable at normal temperatures and pressure. Moisture keep container closed. Alkalis. Product can decompose on combustion (burning) to form Carbon Monoxide, Carbon Dioxide, and other possibly toxic gases and vapours. None known. SECTION 11 - TOXICOLOGICAL INFORMATION PRODUCT MIXTURE INFORMATION Local Effects May be an irritant: eye, skin, inhalation and ingestion. Target Organs None known. POTENTIAL HEALTH EFFECTS No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Ingestion short term exposure Ingestion of large amounts may irritate the gastric tract causing nausea and vomiting. long term exposure No information available. Skin contact short term exposure Contact with skin may result in irritation. long term exposure No known effects. Eye contact short term exposure long term exposure Inhalation short term exposure long term exposure Carcinogen Status NOHSC NTP Eye contact may cause mild stinging, blurring, tearing. No information available. Breathing in dust may result in respiratory irritation. No information available. No significant ingredient is classified as carcinogenic by NOHSC. No significant ingredient is classified as carcinogenic by NTP. MSDS Washing Machine Magic Date of Issue: 11/05/2009 Page 4 of 7

5 IARC No significant ingredient is classified as carcinogenic by IARC. Medical conditions aggravated by exposure No information available. CLASSIFICATION OF INDIVIDUAL INGREDIENTS NOTE : This information relates to each individual ingredient, when evaluated as pure undiluted chemical. See SECTION 3 for actual proportions of ingredients present in this product. Ingredients R-Phrases. Sulfamic acid R36/38 when >20% Non hazardous ingredients to 100% None allocated 100% Sulfamic acid Irritation Data Toxicity Data Local Effects Chronic Toxicity Target Organs Acute Toxicity Reproductive Effects Mutagenic Data Carcinogenic Data SECTION 12 - ECOLOGICAL INFORMATION Causes skin irritation. May cause redness and pain. Severe burns may occur. Destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation and irritation symptoms in the respiratory tract, coughing, wheezing, laryngitis, dyspnoea, headache, nausea and vomiting. Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Causes eye irritation. May cause blurred vision, redness, pain and severe tissue burns and eye damage. Toxic by ingestion. May cause severe burns of the mouth, throat, and stomach leading to death. Causes irritations of mucous membranes in the mouth, pharynx, oesophagus, gastrointestinal tract. May cause sore throat, vomiting and diarrhea. LD50 oral (mus): 1312 mg/kg LD50 oral (rat): 3160 mg/kg Corrosive and harmful: inhalation, skin, eye, ingestion Skin, mucous membranes, eyes. Slightly Toxic: ingestion Fish toxicity Algae toxicity Invertebrates toxicity Toxicity to Bacteria OECD Biological degradation None available for specific product. For ingredient: SULFAMIC ACID; Fish toxicity: P. promelas LC50: 70.3 mg/l/96 h. None available. None available. None available for specific product. For ingredient: SULFAMIC ACID; Bacterial toxicity: Ps. putida EC10 > 1000 mg/l/16 h. Individual components stated to be biodegradable. Biological effects: Harmful effect on aquatic organisms -harmful effect due to ph shift. SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of material according to Local Authority Regulations or through a licensed waste contractor. SECTION 14 TRANSPORT INFORMATION UN Number ADG Classification Shipping Name ADG Subsidiary Risk Hazchem Code Packing Group Packaging Method Special Provisions Segregation MSDS Washing Machine Magic Date of Issue: 11/05/2009 Page 5 of 7

6 SECTION 15 REGULATORY INFORMATION RUBBEDIN PTY LTD AICS All ingredients present on AICS. Labeling Details HAZARD Not hazardous RISK PHRASES None allocated SAFETY PHRASES None allocated SUSDP S5 CAUTION (SULFAMIC ACID <10%) ADG Code SECTION 16 OTHER INFORMATION Acronyms SUSDP Standard for the Uniform Scheduling of Drugs and Poisons. ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail. CAS Number Chemical Abstracts Service Registry Number. UN Number United Nations Number. R-Phrases Risk Phrases. HAZCHEM An emergency action code of numbers and letters which gives information to emergency services. NOHSC National Occupational Health and Safety Commission. NTP National Toxicology Program (USA). IARC International Agency for Research on Cancer. AICS Australian Inventory of Chemical Substances. TWA Time Weighted Average STEL Short Term Exposure Limit Literature References List of Designated Hazardous Substances [NOHSC:10005(1999)] Australian Code For The Transport Of Dangerous Goods By Road And Rail Sixth Edition. Standard for the Uniform Scheduling of Drugs and Poisons. National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC:2011(2003)] Approved Criteria for Classifying Hazardous Substances [NOHSC:1008(1999)] Material Safety Data Sheets individual raw materials Suppliers. HSIS Hazardous Substance Information System National Worksafe Data Base. Revision Information New Issue to standard : 2nd Edition [NOHSC:2011(2003)]. Note Safety Data Sheets are updated frequently. Please ensure that you have a current copy. Contact Point Manager Telephone (07) Issue Date Supersedes Issue May 2009 Date 1 st issue The MSDS is valid for five years from date of issue but may be withdrawn and revised at any time prior to that date. All information contained in the Data Sheet is as accurate as possible at the time of issue. It is meant to describe the safety requirements of our products and should not be construed as guaranteeing specific properties. As per the Worksafe Guidance Note NOHSC 3017, each used should review the information in the specific context of the intended application. No expressed or implied warranties nor any responsibility for damages resulting from use of the information are given other than those implied mandatory by Commonwealth, State or Territory Legislation. If this product is to be re-packaged by others, it will be necessary for a new MSDS to be generated by the re-packer. MSDS Washing Machine Magic Date of Issue: 11/05/2009 Page 6 of 7

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