Page: 1/14 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 Date / Revised: Version: 1.3 Product: Tinopal NFW Liquid

Transcription

1 Safety data sheet Page: 1/14 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Tinopal NFW Liquid 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: fluorescent brightener 1.3. Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Regional Business Unit Dispersions and Resins Europe Telephone: address: 1.4. Emergency telephone number International emergency number: Telephone: SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Eye Dam./Irrit. 2 STOT RE 2

2 Page: 2/14 According to Directive 67/548/EEC or 1999/45/EC Possible Hazards: Irritating to eyes. For the classifications not written out in full in this section the full text can be found in section Label elements Globally Harmonized System, EU (GHS) Pictogram: Signal Word: Warning Hazard Statement: H319 H373 Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary Statements (Prevention): P280d Wear eye/face protection. P260i Do not breathe dust/gas/mist/vapours. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P311 Call a POISON CENTER or doctor/physician. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. According to Directive 67/548/EEC or 1999/45/EC Directive 1999/45/EC ('Preparation Directive') Hazard symbol(s) Xi Irritant. R-phrase(s) R36 Irritating to eyes. S-phrase(s)

3 Page: 3/14 S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 Wear eye/face protection Other hazards According to Regulation (EC) No 1272/2008 [CLP] No specific dangers known, if the regulations/notes for storage and handling are considered. SECTION 3: Composition/Information on Ingredients 3.1. Substances 3.2. Mixtures Chemical nature Derivative based on: distyryl biphenyl compound, anionic Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 Disodium 2,2'-([1,1'-biphenyl]-4,4'-diyldivinylene)bis(benzenesulphonate) Content (W/W): >= 15 % - < 20 % Eye Dam./Irrit. 2 CAS Number: H319 EC-Number: REACH registration number: ethanediol; ethylene glycol Content (W/W): >= 10 % - < 15 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Acute Tox. 4 (oral) STOT RE 2 STOT RE (Kidney) 2 (oral) H302, H373, H373 Hazardous ingredients according to Directive 1999/45/EC

4 Page: 4/14 Disodium 2,2'-([1,1'-biphenyl]-4,4'-diyldivinylene)bis(benzenesulphonate) Content (W/W): >= 15 % - < 20 % CAS Number: EC-Number: REACH registration number: Hazard symbol(s): Xi R-phrase(s): 36 ethanediol; ethylene glycol Content (W/W): >= 10 % - < 15 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Hazard symbol(s): Xn R-phrase(s): 22 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16. SECTION 4: First-Aid Measures 4.1. Description of first aid measures Remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Immediately rinse mouth and then drink ml of water, seek medical attention Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

5 Page: 5/14 SECTION 5: Fire-Fighting Measures 5.1. Extinguishing media Suitable extinguishing media: water spray, foam, dry powder, carbon dioxide 5.2. Special hazards arising from the substance or mixture carbon oxides, nitrogen oxides 5.3. Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: Contaminated extinguishing water must be disposed of in accordance with official regulations. SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Information regarding personal protective measures see, section Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater Methods and material for containment and cleaning up For large amounts: Dike spillage. Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. Dispose of absorbed material in accordance with regulations Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. SECTION 7: Handling and Storage 7.1. Precautions for safe handling No special measures necessary provided product is used correctly. Check peroxide content before use Protection against fire and explosion: No special precautions necessary Conditions for safe storage, including any incompatibilities Further information on storage conditions: Keep container tightly closed and in a cool place. Storage stability:

6 Page: 6/14 Storage temperature: C The packed product is destroyed at low temperatures or by frost Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Components with occupational exposure limits : polyethylene glycol : Urea : ethanediol; ethylene glycol TWA value 52 mg/m3 ; 20 ppm (OEL (EU)) indicative STEL value 104 mg/m3 ; 40 ppm (OEL (EU)) indicative Skin Designation (OEL (EU)) The substance can be absorbed through the skin : Sodium chloride 8.2. Exposure controls Personal protective equipment Respiratory protection: Respiratory protection not required. Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust).

7 Page: 7/14 General safety and hygiene measures Wearing of closed work clothing is recommended. No eating, drinking, smoking or tobacco use at the place of work. Handle in accordance with good industrial hygiene and safety practice. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Form: liquid Colour: yellow-green Odour: amine-like, slight odour Odour threshold: not applicable ph value: (200 g/l, 25 C) Melting point: not applicable Boiling point: approx. 100 C Flash point: > 110 C Evaporation rate: Flammability: not flammable Lower explosion limit: Study does not need to be conducted. Ignition temperature: Vapour pressure: Density: g/cm3 (other) Relative vapour density (air): Solubility in water: miscible Partitioning coefficient n-octanol/water (log Kow): not applicable Self ignition: Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: 310 mpa.s (23 C) Explosion hazard: not explosive Fire promoting properties: not fire-propagating 9.2. Other information Grain size distribution: The substance / product is marketed or used in a non solid or granular form. Other Information: If necessary, information on other physical and chemical parameters is indicated in this section.

8 Page: 8/14 SECTION 10: Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated Chemical stability The product is stable if stored and handled as prescribed/indicated Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions Conditions to avoid No conditions to avoid anticipated Incompatible materials Substances to avoid: No substances known that should be avoided Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. SECTION 11: Toxicological Information Information on toxicological effects Acute toxicity Experimental/calculated data: LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401) LC50 rat (by inhalation): LD50 rat (dermal): Irritation Assessment of irritating effects: Eye contact causes irritation. Not irritating to the skin. Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)

9 Page: 9/14 Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405) Analogous: Assessment derived from products with similar chemical character. Respiratory/Skin sensitization Assessment of sensitization: No data available. Experimental/calculated data: guinea pig: Non-sensitizing. (OECD Guideline 406) Germ cell mutagenicity Assessment of mutagenicity: The substance was not mutagenic in bacteria. Developmental toxicity Assessment of teratogenicity: No data available. Specific target organ toxicity (single exposure) Remarks: No data available. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: No data available. Information on: ethanediol; ethylene glycol Assessment of repeated dose toxicity: The substance may cause damage to the kidney after repeated ingestion. The substance may cause damage to the kidney after repeated skin contact with high doses Aspiration hazard No aspiration hazard expected. Other relevant toxicity information The product has not been tested. The statements on toxicology have been derived from the properties of the individual components. SECTION 12: Ecological Information Toxicity

10 Page: 10/14 Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. Toxicity to fish: LC50 > 100 mg/l (OECD Guideline 203) Aquatic invertebrates: LC50 (48 h), daphnia Aquatic plants: EC50 (72 h), algae Microorganisms/Effect on activated sludge: EC50 (3 h) > 100 mg/l, activated sludge (internal method) Chronic toxicity to fish: No data available. Chronic toxicity to aquatic invertebrates: No data available. Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity Persistence and degradability Assessment biodegradation and elimination (H2O): Moderately/partially eliminated from water. Elimination by adsorption onto activated sludge Elimination information: 35 % (31 d) (OECD 303A; ISO 11733; 92/69 EEC,V, C.10) Bioaccumulative potential Assessment bioaccumulation potential: The product has not been tested Mobility in soil Assessment transport between environmental compartments: No data available Results of PBT and vpvb assessment According to Annex XIV of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria. Self classification

11 Page: 11/ Other adverse effects The product does not contain substances that are listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer Additional information Sum parameter Chemical oxygen demand (COD): 1,110 mg/g Biochemical oxygen demand (BOD) Incubation period 5 d: approx. 220 mg/g Adsorbable organically-bound halogen (AOX): 0 % Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. Other ecotoxicological advice: Do not discharge product into the environment without control. The product has not been tested. The statements on ecotoxicology have been derived from the properties of the individual components. SECTION 13: Disposal Considerations Waste treatment methods Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. SECTION 14: Transport Information Land transport ADR Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards:

12 Page: 12/14 Special precautions for None known user RID Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user Inland waterway transport ADN Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user Transport in inland Not evaluated waterway vessel: Sea transport IMDG Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user Air transport IATA/ICAO Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es):

13 Page: 13/14 Packing group: Environmental hazards: Special precautions for None known user UN number See corresponding entries for UN number for the respective regulations in the tables above UN proper shipping name See corresponding entries for UN proper shipping name for the respective regulations in the tables above Transport hazard class(es) See corresponding entries for Transport hazard class(es) for the respective regulations in the tables above Packing group See corresponding entries for Packing group for the respective regulations in the tables above Environmental hazards See corresponding entries for Environmental hazards for the respective regulations in the tables above Special precautions for user See corresponding entries for Special precautions for user for the respective regulations in the tables above Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment Chemical Safety Assessment not yet performed due to registration timelines. Exposure scenarios for the mixture can not be provided at the moment because exposure scenarios are not yet available for all relevant substances due to registration timelines. For advice on essential measures see sections 7 and 8 of this safety data sheet.

14 Page: 14/14 SECTION 16: Other Information Information on intended use: This product is of industrial quality and unless otherwise specified or agreed intended exclusively for industrial use. This includes the mentioned and recommended usage. Any other intended applications should be discussed with the manufacturer. In particular this concerns the application for products that are the object of special standards and regulations. Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3: Xi Irritant. Xn Harmful. 36 Irritating to eyes. 22 Harmful if swallowed. Eye Dam./Irrit. Serious eye damage/eye irritation STOT RE Specific target organ toxicity repeated exposure Acute Tox. Acute toxicity H319 Causes serious eye irritation. H302 Harmful if swallowed. H373 May cause damage to organs () through prolonged or repeated exposure. H373 May cause damage to organs (Kidney) through prolonged or repeated exposure (oral). The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.