Safety Data Sheet CARBOXANE 2000 PART A

Transcription

1 CARBOXANE 2000 PART A Safety Data Sheet dated , version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Trade name: CARBOXANE 2000 PART A Trade code: A0 Supplier: APSA S.p.A-Via Milano Cologno Monzese MI Emergency telephone number of the company and/or of an authorised advisory centre: APSA S.p.A. - Tel.: North Europe Carboline Tel South Europe Corroline France Tel COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components within the meaning of EEC directive 67/548 and corresponding classification: 2,5-10 % heptan-2-one; methyl amyl ketone N.67/548/EEC: CAS: EINECS: Xn R10 R20/22 3. HAZARDS IDENTIFICATION The product is a liquid that can catch fire at temperatures in excess of 21 C if exposed to an ignition source. 4. FIRST AID MEASURES Contact with skin: Wash with plenty of water and soap. Contact with eyes: Wash immediately with water for at least 10 minutes. Swallowing: Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safetydata sheet. A suspension of activated charcoal in water, or liquid petrolatum may be administered. Inhalation: Ventilate the premises. The patient is to be removed immediately from the premises contaminated and made to rest in a well ventilated area. Should the patient feel unwell, consult a physician. 5. FIRE-FIGHTING MEASURES Recommended extinguishers: In case of fire, use CO2 or other dry fire-fighting equipment - chemical powders. Risks arising from combustion: Avoid inhaling the fumes. Protective equipment: Use protection for the respiratory tract. Cool the containers exposed to the fire with water. 6. ACCIDENTAL RELEASE MEASURES A0/1 Page n. 1 of 3

2 CARBOXANE 2000 PART A Measures for personal safety: Use gloves and protective clothing. Environmental measures: Limit leakages with earth or sand. Eliminate all unguarded flames and possible sources of ignition. Do not smoke. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Cleaning methods: If the product is in a liquid form, stop it from entering the drainage system. Recover the product for re-use if possible, or for elimination. The product might, where appropriate, be absorbed by inert material. After the product has been recovered, rinse the area and materials involved with water. 7. HANDLING AND STORAGE Handling precautions: Avoid contact and inhalation of the vapours. See, too, paragraph 8 below. Do not eat or drink while working. Do not smoke while working. Storage conditions: Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight. Instructions as regards storage premises: Cool and adequately ventilated. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Precautionary measures: Give adequate ventilation to the premises where the product is stored and/or handled. Respiratory protection: Use adequate protective respiratory equipment. Protection for hands: Not needed for normal use. Eye protection: Safety goggles. Protection for skin: No special precaution must be adopted for normal use. Exposure limit(s) (ACGIH): heptan-2-one; methyl amyl ketone TLV-TWA: 233 mg/m3, 50 ppm 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and colour: LIQUID Odour: SOLVENT Flash point: 35 C Solid/gas flammability: LEL 1,1-7,9% Relative density: 1,51 Solubility in water: NOT SOLUBLE Vapour density: HEAVIER THAN AIR 10. STABILITY AND REACTIVITY Conditions to avoid: Stable under normal conditions. Substances to avoid: Avoid contact with combustible materials. The product could catch fire. Hazardous decomposition products: A0/1 Page n. 2 of 3

3 CARBOXANE 2000 PART A 11. TOXICOLOGICAL INFORMATION The concentration of each substance should be borne in mind in assessing the toxicological effects deriving from the preparation. Set out below is the toxicological information relating to the main substances in the preparation. the product does not contain toxicologically relevant substances. 12. ECOLOGICAL INFORMATION Adopt sound working practices, so that the product is not released into the environment. 13. DISPOSAL CONSIDERATIONS Recover if possible. In so doing, comply with the local and national regulations currently in force. 14. TRANSPORT INFORMATION ONU number: Classification: UN 1263 PAINT or paint related material 3,III 15. REGULATORY INFORMATION Classification CEE R Phrases: S Phrases: S23 Do not breathe gas/fumes/vapour/spray. S51 Use only in well-ventilated areas. S43 In case of fire, use CO2 or other dry fire-fighting equipment - chemical powders. Where applicable, refer to the following regulatory provisions : Ministerial circulars 46 e 61 (Aromatic amines). Law 136/83 (Biodegradability of detergents). Presidential Decree D.P.R. 175/88 (Seveso Directive), Appendices II, III e IV. Presidential Decree D.P.R. 250/89 (Labelling of detergents). 16. OTHER INFORMATION Text of R phrases referred to under heading 2: R20/22 Harmful by inhalation and if swallowed. Main bibliographic sources: NIOSH - Registry of toxic effects of chemical substances (1983) I.N.R.S. - Fiche Toxicologique CESIO - Classification and labelling of anionic, nonionic surfactants (1990) The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release A0/1 Page n. 3 of 3

4 Safety Data Sheet dated , version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Trade name: Trade code: B0 Supplier: APSA S.p.A-Via Milano Cologno Monzese MI Emergency telephone number of the company and/or of an authorised advisory centre: APSA S.p.A. - Tel.: North Europe Carboline Tel South Europe Corroline France Tel COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components within the meaning of EEC directive 67/548 and corresponding classification: % xylene N.67/548/EEC: CAS: EINECS: Xn R10 R20/21 R38 2,5-10 % 1-methoxy-2-propanol N.67/548/EEC: CAS: EINECS: R % amino propyl tri ethoxy silane N.67/548/EEC: CAS: EINECS: C R22 R34 3. HAZARDS IDENTIFICATION The product is a liquid that can catch fire at temperatures in excess of 21 C if exposed to an ignition source. The product is harmful following acute exposure to it and poses a serious health threat if inhaled or brought into contact with the skin. The product is corrosive and, if brought, into contact with the skin, causes burning, with the destruction of the entire thickness of skin tissue. 4. FIRST AID MEASURES Contact with skin: Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the toxin must be rinsed immediately with plenty of running water and possibly with soap. Contact with eyes: Do not use eyewash or ointment of any kind before obtaining an examination or advice from an ophthalmologist. Wash immediately with water for at least 10 minutes. Swallowing: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. Administer petrolatum; administer neither milk nor animal or vegetable fats of any kind. Page n. 1 of 4

5 Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises to rest in a well ventilated area. CALL A PHYSICIAN. 5. FIRE-FIGHTING MEASURES Recommended extinguishers: In case of fire, use CO2 or other dry fire-fighting equipment - chemical powders. Risks arising from combustion: Avoid inhaling the fumes. Protective equipment: Use protection for the respiratory tract. Cool the containers exposed to the fire with water. 6. ACCIDENTAL RELEASE MEASURES Measures for personal safety: Use a mask, gloves and protective clothing. Environmental measures: Limit leakages with earth or sand. Eliminate all unguarded flames and possible sources of ignition. Do not smoke. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Cleaning methods: Rapidly recover the product. To do so, wear a mask and protective clothing. If the product is in a liquid form, stop it from entering the drainage system. Recover the product for re-use if possible, or for elimination. The product might, where appropriate, be absorbed by inert material. After the product has been recovered, rinse the area and materials involved with water. 7. HANDLING AND STORAGE Handling precautions: Avoid contact and inhalation of the vapours. See, too, paragraph 8 below. Do not eat or drink while working. Do not smoke while working. Storage conditions: Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight. Instructions as regards storage premises: Cool and adequately ventilated. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Precautionary measures: Give adequate ventilation to the premises where the product is stored and/or handled. Respiratory protection: Use adequate protective respiratory equipment. Protection for hands: Use protective gloves. Eye protection: Safety goggles. Protection for skin: Use clothing that provides comprehensive protection to the skin. Exposure limit(s) (ACGIH): xylene TLV-TWA: 434 mg/m3, 100 ppm TLV-STEL: 651 mg/m3, 150 ppm 1-methoxy-2-propanol TLV-TWA: 369 mg/m3, 100 ppm TLV-STEL: 553 mg/m3, 150 ppm Page n. 2 of 4

6 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: LIQUID Odour: Solvent Boiling point: C Flash point: 23 C Autoignition temp: 500 Solubility in water: not soluble Vapour density: >1 Density: 1, STABILITY AND REACTIVITY Conditions to avoid: Stable under normal conditions. Substances to avoid: Avoid contact with combustible materials. The product could catch fire. Hazardous decomposition products: 11. TOXICOLOGICAL INFORMATION The concentration of each substance should be borne in mind in assessing the toxicological effects deriving from the preparation. Set out below is the toxicological information relating to the main substances in the preparation. xylene OBSERVATIONS ON HUMAN SUBJECTS NON-PROFESSIONAL EXPOSURE - Effects following acute exposure: Symptoms of intense exposure are: dermatitis, eczema, irritation to the eyes and to the respiratory tract. Inhaling the vapours can cause dizziness, headache, nausea, incoordination, excitability, narcosis, anaemia, and paraesthesia of the hands and feet. PROFESSIONAL EXPOSURE - Effects following acute exposure: Narcotic at high concentrations. Irritation through inhalation at 200 ppm (TCLo). Inhalation of 200 ppm has irritating effects in human subjects. Human subject (oral)(ldlo): 50 mg/kg. Inhalatory human subject (LCLo) ppm/6h. 12. ECOLOGICAL INFORMATION Adopt sound working practices, so that the product is not released into the environment. 13. DISPOSAL CONSIDERATIONS Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force. 14. TRANSPORT INFORMATION ONU number: UN 2924, flammable corrosive liquid nos AMINOPROPYLTRIETHOXYSILANE Classification: 3,III Page n. 3 of 4

7 15. REGULATORY INFORMATION Classification CEE Symbols: C corrosive R Phrases: R34 Causes burns R20/21 Harmful by inhalation and in contact with skin. S Phrases: S23 Don't breathe gas/fumes/vapour/spray S43 In case of fire, use CO2 or other dry fire-fighting equipment - chemical powders. S25 Avoid contact with eyes. S36/37/39 Wear suitable protective clothing and gloves, and eye/face protection. Contents: xylene Where applicable, refer to the following regulatory provisions : Ministerial circulars 46 e 61 (Aromatic amines). Law 136/83 (Biodegradability of detergents). Presidential Decree D.P.R. 175/88 (Seveso Directive), Appendices II, III e IV. Presidential Decree D.P.R. 250/89 (Labelling of detergents). 16. OTHER INFORMATION Text of R phrases referred to under heading 2: R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. Main bibliographic sources: NIOSH - Registry of toxic effects of chemical substances (1983) I.N.R.S. - Fiche Toxicologique CESIO - Classification and labelling of anionic, nonionic surfactants (1990) The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release. Page n. 4 of 4