ARISTA RAPID E-6 COLOR FIRST DEVELOPER

Transcription

1 ARISTA RAPID E-6 COLOR FIRST DEVELOPER 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 COLOR FIRST DEVELOPER Product Number: , , Date Prepared: 04/23/2007 Customer Information Phone Number: CHEMTREC : 24 Hour Emergency Transport Phone Number: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % POTASSIUM METABISULFITE N.E. N.E , 5-DIHYDROXYBENZENESULFONIC ACID MONOSODIUM SALT mg/m³ 10 mg/m³ 5-10 POTASSIUM CARBONATE mg/m³ 10mg/m³ 1-5 POTASSIUM HYDROXIDE N.E. 2mg/m³ CEILING 1-5 SODIUM BICARBONATE N.E. N.E. 1-5 PENTASODIUM DTPA MIXTURE N.E. N.E. < 2 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: Causes severe irritation and burns. Inhalation: Expected to be a low hazard for recommended handling. In contact with strong acids or if heated, sulfites may liberate sulfur dioxide gas which is irritating to respiratory tract. Ingestion: May be harmful if swallowed, especially to sulfite-sensitive individuals. Skin Contact: Causes irritation; may cause allergic reaction. Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty breathing, abdominal pain, skin irritation, mucus membrane irritation, coughing, nausea, diarrhea. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Some asthmatics or sulfitesensitive persons may experience wheezing, chest tightness, stomach upset, hives, faintness, weakness, and diarrhea. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. Date: 6/19/07 Rapid E-6 First Developer 1 / 4

2 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use agent appropriate for surrounding fire. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual Fire And Explosion Hazards: Fire or excessive heat may cause production of hazardous decomposition products. Combustion Products: Carbon dioxide, carbon monoxide, and oxides of sulfur. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority and may require pre-treatment. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well-ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Use of respiratory protection is generally not required. However, if use conditions generate vapors or fumes, use a NIOSH approved acid gas respirator. Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits. Protective Gloves: Rubber or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear, yellow solution, slight odor. Solubility In Water: Complete Boiling Point: >100 C Vapor Pressure:18 mm 20 C Ph: 9.76 Specific Gravity: 1.23 g /ml Melting Point: Not applicable Freezing Point: N.E. Date: 6/19/07 Rapid E-6 First Developer 2 / 4

3 Evaporation Rate: N.E. Vapor Density: 0.6 Percent Volatile: Molecular Weight: Not applicable Pounds Per Gallon: VO.C. = STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: None Incompatibility: Strong acids, strong oxidizing agents. Hazardous Decomposition Or By Products: May produce oxides of sulfur. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No.: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: None CALIF. PROP. 65: Product contains a mixture which includes trace amounts of Trisodium NTA. The State of California s Safe Drinking Water and Toxic Enforcement Act of 1986, or Proposition 65 requires the following information. This regulation does not address di minimus levels; therefore, even trace amounts of the chemicals included on Proposition 65 s list of chemicals known to the State of California to cause cancer or reproductive toxicity must be noted with the Safe Harbor wording. WARNING: This product contains Trisodium NTA known to the State of California to cause cancer, birth defects or other reproductive harm. CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS ABOVE THE MINIMUM AMOUNT LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/l Vapor Pressure: N.E. mmhg@ 20 C Date: 6/19/07 Rapid E-6 First Developer 3 / 4

4 16. OTHER INFORMATION (HMIS) Health: 2 Flammability: 0 Reactivity: 0 Protective: B OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein. Date: 6/19/07 Rapid E-6 First Developer 4 / 4

5 ARISTA RAPID E-6 COLOR DEVELOPER PART A 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 COLOR DEVELOPER PART A Product Number: , , Date Prepared: 04/23/2007 Customer Information Phone Number: CHEMTREC : 24 Hour Emergency Transport Phone Number: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % POTASSIUM HYDROXIDE N.E. 2mg/m³ CEILING 5-10 MONOSODIUM PHOSPHATE mg/m³* N.E PENTASODIUM SALT MIXTURE N.E. N.E. 1-3 * Particulates not otherwise regulated respirable fraction. 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: Causes severe irritation and burns. Inhalation: Mist may cause irritation to respiratory tract. In contact with strong acids or if heated may liberate sulfur dioxide gas which is irritating. Some asthmatics or hypersensitive individuals may experience difficult breathing. Ingestion: Harmful if swallowed. May cause burns to the gastrointestinal tract. Some asthmatics and sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset, hives, diarrhea. Skin Contact: Causes burns. Signs And Symptoms Of Exposure: Eye and skin burns, abdominal pain, vomiting and diarrhea upon ingestion., difficulty breathing. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. Date: 6/19/07 Rapid E-6 Developer Part A 1 / 4

6 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Noncombustible Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use agent appropriate for the surrounding area. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous decomposition products. Unusual Fire And Explosion Hazards: None Combustion Products: Carbon dioxide and carbon monoxide. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. May require neutralization for ph > Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority. Working solution is able to be flushed to sewer with large amounts of water upon approval. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well-ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: If use conditions do not maintain vapors or fumes below exposure limits, use a NIOSH approved respirator with acid gas cartridges. Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits, typically 10 air changes per hour. Protective Gloves: Rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles) and a face shield. Other Protective Clothing or Equipment: Rubber or plastic apron or other protective clothing suitable for the exposure risk. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear slight yellow, odorless liquid. Solubility In Water: Complete Boiling Point: >100 C Vapor Pressure: 18 mm 20 C Ph: (1+1) = Date: 6/19/07 Rapid E-6 Developer Part A 2 / 4

7 Specific Gravity: 1.13 g /ml Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: 0.6 (air=1) Percent Volatile: Molecular Weight: Not applicable Pounds Per Gallon: 9.43 V.O.C. = STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: High temperatures Incompatibility: Strong Acids. Hazardous Decomposition Or By Products: May produce oxides of sulfur and phosphorus Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION Ship Name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Contains Potassium Hydroxide) Hazard Class: 8 UN No.: 3266 Packing Group: II Guide No: 154 Limited Quantity Exception may apply to this product, for inner packagings not over 1.0L (0.3 gal) for liquids and 1.0 kg (2.2 lb) for solids (b) (1). Each package must conform to the packaging requirements of Subpart B of Part 173 and may not exceed 30 kg (66 lb) gross weight. For further information consult the 49 CFR. DOT Class: CONSUMER COMMODITY, ORM-D Hazard Class: NOT APPLICABLE UN No.: NOT APPLICABLE Packing Group: NOT APPLICABLE Guide No: NOT APPLICABLE Ship Name: NOT APPLICABLE 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Date: 6/19/07 Rapid E-6 Developer Part A 3 / 4

8 SCAQMD Rule Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/l Vapor Pressure: N.E. mmhg@ 20 C 16. OTHER INFORMATION (HMIS) Health: 3 Flammability: 0 Reactivity: 0 Protective: C OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein. Date: 6/19/07 Rapid E-6 Developer Part A 4 / 4

9 ARISTA RAPID E-6 COLOR DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 COLOR DEVELOPER PART B Product Number: , , Date Prepared: 04/23/2007 Customer Information Phone Number: CHEMTREC : 24 Hour Emergency Transport Phone Number: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % 4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIAMINE SESQUISULFATE MOMOHYDRATE N.E. 1.0 mg/m³* SODIUM METABISULFITE N.E 5 mg/m³ 1-3 *Manufacturer s industrial hygiene guideline. 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: May cause irritation. Inhalation: Harmful if inhaled. Mist may cause irritation to respiratory tract. In contact with strong acids or if heated may liberate sulfur dioxide gas which is irritating. Some asthmatics or hypersensitive individuals may experience difficult breathing. Ingestion: Harmful if swallowed. Toxic. May cause burns to the gastrointestinal tract. Some asthmatics and sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset, hives, diarrhea. Skin Contact: Prolonged contact will cause burns. Signs And Symptoms Of Exposure: Eye and skin burns, abdominal pain, vomiting and diarrhea upon ingestion and difficulty breathing. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. Date: 6/19/07 Rapid E-6 Developer Part B 1 / 4

10 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Water spray, carbon dioxide, dry chemical, alcohol foam. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous decomposition products. Unusual Fire And Explosion Hazards: None Combustion Products: Carbon dioxide, carbon monoxide, oxides of sulfur, oxides of nitrogen. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. May require neutralization if ph < 2.0. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority. Working solution is able to be flushed to sewer with large amounts of water upon approval. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Avoid breathing mist or vapor. Store in a cool, dry, well-ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: If use conditions do not maintain vapors or fumes below exposure limits, use a NIOSH approved respirator with acid gas cartridges. Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits, typically 10 air changes per hour. Protective Gloves: Rubber or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron or other protective clothing suitable for the exposure risk. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Light straw color, sulfur dioxide odor. Solubility In Water: Complete Boiling Point: >100 C Vapor Pressure: 18 mm 20 C Ph: 1.76 Date: 6/19/07 Rapid E-6 Developer Part B 2 / 4

11 Specific Gravity: 1.09/ml Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: 0.6 (air=1) Percent Volatile: Molecular Weight: Not applicable Pounds Per Gallon: 9.11 V.O.C. = STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: None Incompatibility: Strong bases and oxidizers. Hazardous Decomposition Or By Products: May produce oxides of sulfur, carbon, and nitrogen. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION Ship Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Contains CD-3) Hazard Class: 8 UN No.: 3265 Packing Group: II Guide No: 153 Limited Quantity Exception may apply to this product, for inner packagings not over 1.0L (0.3 gal) for liquids and 1.0 kg (2.2 lb) for solids (b) (1). Each package must conform to the packaging requirements of Subpart B of Part 173 and may not exceed 30 kg (66 lb) gross weight. For further information consult the 49 CFR. DOT Class: CONSUMER COMMODITY, ORM-D Hazard Class: NOT APPLICABLE UN No.: NOT APPLICABLE Packing Group: NOT APPLICABLE Guide No: NOT APPLICABLE Ship Name: NOT APPLICABLE 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Date: 6/19/07 Rapid E-6 Developer Part B 3 / 4

12 SCAQMD Rule Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/l Vapor Pressure: N.E. mmhg@ 20 C 16. OTHER INFORMATION (HMIS) Health: 2 Flammability: 1 Reactivity: 0 Protective: B OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein. Date: 6/19/07 Rapid E-6 Developer Part B 4 / 4

13 ARISTA RAPID E-6 BLIX PART A 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 BLIX PART A Product Number: , , Date Prepared: 04/23/2007 Customer Information Phone Number: CHEMTREC : 24 Hour Emergency Transport Phone Number: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % AMMONIUM THIOSULFATE N.E. N.E SODIUM SULFITE N.E. N.E HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: Causes irritation. Inhalation: May cause irritation mucous membranes and to upper respiratory tract. Ingestion: May cause irritation to gastrointestinal track. Some asthmatics or sulfite-sensitive persons may experience wheezing, chest tightness, stomach upset, hives, faintness, weakness, and diarrhea. Skin Contact: May cause irritation or reddening. Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty breathing, abdominal pain, skin irritation, mucus membrane irritation, coughing, nausea, diarrhea. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Immediately wash skin with plenty of soap. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Aggravated Medical Conditions: Asthmatics or hypersensitive individuals may experience difficult breathing. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto-ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Any applicable to the primary cause of the fire. Flood with water. Date: 6/19/07 Rapid E-6 Blix Part A 1 / 3

14 Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual Fire And Explosion Hazards: None known. Combustion Products: Carbon dioxide, carbon monoxide, oxides of sulfur and nitrogen. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment during cleanup. For small amount less than one gallon flush to sewer with large amounts of water. For larger spills, dike the spill. Prevent liquid from entering sewers, waterways or low areas. Soak up with sawdust, sand, oil dry, or other absorbent material. Absorb spillage in inert material. Remove non-usable solid material and/or contaminated soil for disposal. Discharge to sewer may require approval of local authorities. Contaminated surfaces may be cleaned using water. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not reuse containers. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: When this product is used in the intended way, no respiratory protection is anticipated to be necessary. Ventilation: Avoid breathing vapors or mist. Local exhaust ventilation is recommended. Ventilation must be adequate to keep hazardous ingredients below their exposure limits. Protective Gloves: Impervious gloves and aprons recommended. Eye Protection: Chemical safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear, colorless solution; ammonia odor. Solubility In Water: Complete Boiling Point: 100 C Specific Gravity: 1.24 Vapor Pressure: 18m 20 C Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: Ph: 7.38 Molecular Weight: Not applicable Pounds Per Gallon: V.O.C. = STABILITY AND REACTIVITY Stability: Stable Date: 6/19/07 Rapid E-6 Blix Part A 2 / 3

15 Conditions To Avoid: Strong acids and alkali. Incompatibility Strong acids will liberate sulfur dioxide; strong bases of sodium hydroxide will liberate ammonia fumes. Hazardous Decomposition Or By Products: Sulfur dioxide, ammonia. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/l Vapor Pressure: N.E. mmhg@ 20 C 16. OTHER INFORMATION (HMIS) Health: 1 Flammability: 0 Reactivity: 0 Protective: B OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein. Date: 6/19/07 Rapid E-6 Blix Part A 3 / 3

16 ARISTA RAPID E-6 BLIX PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 BLIX PART B Product Number: , , Date Prepared: 04/23/2007 Customer Information Phone Number: CHEMTREC : 24 Hour Emergency Transport Phone Number: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % FERRIC AMMONIUM EDTA ppm 25 ppm HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: May cause transient irritation. Inhalation: Low hazard for recommended handling. Ingestion: Expected to be low hazard if swallowed. May cause irritation of the mouth, throat, and stomach. Skin Contact: May cause redness and irritation. Signs And Symptoms Of Exposure: Redness of eyes and skin. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Dermatitis, asthma, and sulfite sensitiveness for working solution. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as a carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use agent appropriate for surrounding fire. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual Fire And Explosion Hazards: Not considered a fire hazard. When involved in a fire, does not contribute any unusual hazards. Combustion Products: Oxides of carbon and nitrogen are produced by the combustion of this product. Date: 6/19/07 Rapid E-6 Blix Part B 1 / 3

17 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority. Working solution should be able to be flushed to sewer with large amounts of water. Contaminated surfaces should be cleaned using water. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not reuse containers. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: When this product is used in the intended way, no respiratory protection is anticipated to be necessary. If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved respirator should be worn of organic vapor type. Ventilation: Good ventilation of 10 room volumes per hour. Ventilation rates should match conditions of use. Protective Gloves: Latex, rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure: See Section PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Reddish brown solution; ammonia odor Solubility In Water: Complete Boiling Point: > 100 ºC Vapor Pressure: 18m 20ºC Specific Gravity: 1.25 Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: Ph: 7.34 Molecular Weight: Not applicable Pounds Per Gallon: V.O.C. is STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Metals such as aluminum, copper, copper alloys, nickel, and zinc. Aqueous solution in contact with aluminum evolves hydrogen. Date: 6/19/07 Rapid E-6 Blix Part B 2 / 3

18 Incompatibility: Strong oxidizers, alkalis, acids. Hazardous Decomposition Or By Products: May produce oxides of nitrogen, carbon dioxide, carbon monoxide, and ammonia. Hazardous Polymerization: Will Not Occur Conditions To Avoid: None 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Discharge, treatment or disposal may be subject to Federal, State (provincial in Canada) or local laws. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No.: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/l Vapor Pressure: N.E. mmhg@ 20 C 16. OTHER INFORMATION (HMIS) Health: 1 Flammability: 0 Reactivity: 0 Protective: B OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for injuries from the use of the product described herein. Date: 6/19/07 Rapid E-6 Blix Part B 3 / 3

19 ARISTA RAPID E-6 BLIX PART C 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 BLIX PART C Product Number: , , Date Prepared: 04/23/2007 Customer Information Phone Number: CHEMTREC : 24 Hour Emergency Transport Phone Number: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % SODIUM METABISULFITE N.E. 5 mg/m³ ACETIC ACID mg/m³ TWA = 25 mg/m³ < 2 STEL = 37 mg/m³ POTENTIAL HEALTH EFFECTS Eye Contact: May cause temporary irritation. Inhalation: Expected to be a low hazard for usual industrial or commercial handling by trained personnel. In contact with strong acids or if heated, sulfites may liberate sulfur dioxide gas. Sulfur dioxide gas is irritating to the respiratory tract. Ingestion: May be harmful if swallowed. May cause irritation to gastrointestinal tract. Some asthmatics or sulfite-sensitive persons may experience wheezing, chest tightness, stomach upset, hives, faintness, weakness, and diarrhea. Skin Contact: This material has a low potential to cause allergic skin reactions; however, cases of human skin sensitization have been reported. Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty breathing, wheezing, chest tightness, stomach upset, hives, faintness, weakness, and diarrhea. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Immediately wash skin with plenty of soap. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Aggravated Medical Conditions: Asthmatics or hypersensitive individuals may experience difficult breathing. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as a carcinogen. 5. FIRE FIGHTING MEASURES Flash Point: Nonflammable Flash Point Method: Not applicable Auto-ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Any applicable to the primary cause of the fire. Flood with water. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous decomposition products. Date: 6/19/07 Rapid E-6 Blix Part C 1 / 3

20 Unusual Fire And Explosion Hazards: Sulfur dioxide can be emitted under high temperatures. Combustion Products: Carbon dioxide, carbon monoxide, oxides of sulfur. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment during cleanup. For small amount less than one gallon flush to sewer with large amounts of water if permitted. For larger spills, dike the spill. Prevent liquid from entering sewers, waterways or low areas. Soak up with sawdust, sand, oil dry, or other absorbent material. Absorb spillage in inert material. Remove non-usable solid material and/or contaminated soil for disposal. Discharge to sewer may require approval of local authorities. Contaminated surfaces may be cleaned using water. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep containers closed. Do not store with incompatible materials. Keep from contact with oxidizing materials, highly oxygenated or halogenated solvents, and organic compounds containing reducible functional groups. Keep away from combustible material. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Remove and wash contaminated clothing promptly. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not reuse containers. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: None should be needed. A respirator should be worn if hazardous decomposition products are likely to be or have been released. Respirator type: Acid gas. Ventilation: Avoid breathing vapors or mist. Local exhaust ventilation (typically 10 air changes per hour) is recommended. Ventilation must be adequate to keep hazardous ingredients below their exposure limits. Protective Gloves: Impervious gloves are recommended. Eye Protection: Chemical safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear, colorless liquid with a strong vinegar odor. Solubility In Water: Complete Boiling Point: 100 ºC Vapor Pressure: N.E. Specific Gravity: 1.14 Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: Ph: 3.46 Molecular Weight: Not applicable Pounds Per Gallon: 9.50 V.O.C g/l or 1.08%, or 0.17 lb. /gal. Date: 6/19/07 Rapid E-6 Blix Part C 2 / 3

21 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Strong bases. Incompatibility Strong bases will liberate sulfur dioxide. Hazardous Decomposition Or By Products: Sulfur dioxide Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule Photochemically Reactive: No Maximum Grams of VOC per Liter: gm/l Vapor Pressure: N.E. mmhg@ 20 C 16. OTHER INFORMATION (HMIS) Health: 2 Flammability: 0 Reactivity: 0 Protective: C OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein. Date: 6/19/07 Rapid E-6 Blix Part C 3 / 3