MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET PC Page 1 of 5 EMERGENCY NUMBERS: Sealed Air Corporation: (203) For emergency and general information 8:30am-5:00pm, (Eastern Time), Monday-Friday CHEMTREC: (800) SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION For Chemical Emergency - spill, leak, fire, exposure or accident 24 hours Product Name: INSTAPAK PORT CLEANER Chemical Name: Diisobutyl DBE Trade Name: DBE-IB Chemical Family: Dibasic esters Chemical Formula: (CH 3 ) 2 CHCH 2 OOC (CH 2 ) nococh 2 CH (CH 3 ) 2 n= 2, 3 and 4 SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Components: CAS No. Wt.% OSHA-PEL ACGIH-TLV Diisobutyl glutarate Not Listed Not Listed Diisobutyl adipate Not Listed Not Listed Diisobutyl succinate Not Listed Not Listed Carbon Dioxide (propellant) TWA 5,000 ppm TWA 5,000 ppm STEL/C 30,000 ppm This product is classified as hazardous under OSHA Hazard Communication Standard (29 CFR ). SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Health Hazards: Skin contact may cause irritation with discomfort or rash. Eye contact may cause eye irritation with discomfort or tearing. Physical Hazards: Slightly combustible liquid. Appearance: Clear liquid. Odor: Sweet. Note: Read the entire MSDS for a more thorough evaluation of the hazard information on this product. SECTION 4 - FIRST AID MEASURES Inhalation: Remove from further exposure and obtain medical attention. Administer oxygen if necessary. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with mild soap and water. Eye Contact: Immediately flush with copious amounts of water for at least 15 minutes, holding eyelids open with fingers. Obtain medical attention.

2 Page 2 of 5 SECTION 4 - FIRST AID MEASURES (continued) Ingestion: If large quantities are swallowed, give two glasses of lukewarm water if person is completely conscious and alert. DO NOT INDUCE VOMITING. Obtain emergency medical attention. Note to Physicians: Activated charcoal mixture may be beneficial. Suspend 50 grams of activated charcoal in 400 milliters of water and mix well. Administer 5 milliters per kilogram or 350 milliters for an average adult. SECTION 5 - FIRE FIGHTING MEASURES Flash Point: >212 F (>100 C) [TCC] Flammable limits (lower): Not established Flammable limits (upper): Not established Extinguishing Media: Carbon dioxide (CO 2 ), water, alcohol foam, dry chemical. Fire and Explosion Hazards: Contents under pressure. Keep temperature of containers below 120 F to prevent bursting. Fire Fighting Protective Equipment: Firefighters should be equipped with self-contained breathing apparatus and protective clothing. Water may be used to cool closed containers to prevent pressure build-up and possible bursting when exposed to high temperatures. NFPA Hazard Code: Health: 1 Flammability: 1 Reactivity: 0 Special Hazard: None SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills are unlikely due to the type of container used for this material. If a spill does occur, eye and skin protection should be worn during cleanup and ventilation maintained. Absorb on loose, absorbent material and dispose of with solid waste in accordance with federal, state, and local regulations. Flush spill area with water. Prevent contact with waterways and sewers. SECTION 7 - HANDLING AND STORAGE Storage Temperature: Min. 20 F (-7 C) Max. 120 F (49 C) Average Shelf Life: 2 years. Special Sensitivity: Do not expose pressurized cans to temperatures above 120 F. Precautions to be Taken in Handling and Storage: Keep away from open flames.

3 Page 3 of 5 SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits: OSHA-PEL: Diisobutyl DBE, Carbon Dioxide; Not Listed Ceiling = 5,000 ppm STEL = 30,000 ppm ACGIH-TLV: Diisobutyl DBE; Carbon Dioxide; Not Listed Ceiling = 5,000 ppm STEL = 30,000 ppm HMIS Hazard Code: Health 1 Flammability 1 Reactivity 0 PPE B (Personal Protective Equipment) (B= safety glasses and gloves) Respiratory Protection: None required during normal use. Eye Protection: Goggles or safety glasses with side shields. Contact lenses must not be worn. Protective Clothing: Chemical resistant butyl rubber, nitrile rubber or other suitable protective gloves. Ventilation: Good general ventilation. For guidance on engineering controls refer to the ACGIH publication Industrial Ventilation. Other: Eye wash station. Refer to the "Recommendations for the Safe Use & Handling of Instapak Foam-in- Place Chemicals" bulletin before handling Instapak chemicals. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Boiling Point: F ( C) Color: Clear Vapor Pressure: <0.01 mm Hg at 20 C Odor: Sweet Specific Gravity: at 25 C Vapor Density (Air = 1): 3.0 Bulk Density: 8.0 lbs/gal Molecular Weight: 242 (average) % Volatile by Weight: 100% at 20 C Melting Point: <-67 F (<-55 C) Solubility in Water: Miscible VOC Content: 955 g/l per EPA Method 22 SECTION 10 - STABILITY AND REACTIVITY Stability: Stable. Hazardous Polymerization: Will not occur. Conditions to Avoid: Avoid any excessive heat, ignition sources, open flames, or other high temperature conditions. Incompatible Materials: Oxidizing agents, acids and alkalies. Hazardous Decomposition Products: Oxides of carbon.

4 Page 4 of 5 SECTION 11 - TOXICOLOGICAL INFORMATION Toxicity Data: LD50 Oral: LC 50 Inhalation: 16,426 mg/kg (Rats) >31.9 mg/l (Rats) Primary Route(s) of Exposure: Inhalation/Skin absorption. Inhalation: A single exposure by inhalation caused body weight loss, and clear ocular discharge during exposure. Post-exposure corneal cloudiness and slight to severe body weight loss occurred. Skin Contact: Mild skin irritant, but is not a skin sensitizer in animals. Eye Contact: Mild eye irritant. A single application of 10 ul to the eye caused slight transient clouding of the cornea. Ingestion: Single doses by ingestion caused weakness, moderate weight loss and nonspecific effects. Chronic Effects: As noted above. Carcinogenicity: The ingredients of this product (>0.1%) are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA, and not listed as carcinogens by NTP. Mutagenicity: No applicable data. Reproductive Effects: No applicable data. Teratogenicity and Fetotoxicity: No applicable data. SECTION 12 - ECOLOGICAL INFORMATION Environmental Fate and Degradation: No applicable data. Persistence and Degradation: No applicable data. Aquatic Toxicity: 48 Hour LC 50 : mg/l (Daphnia magna) 96 Hour LC 50 : mg/l (Fathead minnows) SECTION 13 - DISPOSAL CONSIDERATIONS Recover non-usable free liquid and dispose of through permitted waste-to-energy facility or biological treatment system or absorb liquid on loose, absorbent material and dispose of with solid waste in accordance with federal, state, and local regulations. Flush area of contact with water. Container should be fully discharged prior to disposal. This material is not a hazardous waste under RCRA 40 CFR 261 when disposed of in its purchased form.

5 Page 5 of 5 SECTION 14 - TRANSPORT INFORMATION DOT: Consumer Commodity, ORM-D IMO: Aerosols, non-flammable, UN 1950, Class 2, limited quantity IATA/ICAO Class: Aerosols, UN 1950, Class 2.2, limited quantity Reportable Quantity (RQ): Not applicable. SECTION 15 - REGULATORY INFORMATION TSCA Status: All ingredients listed or are not required to be listed. CERCLA Status: Discarded material is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form. SARA 302 Extremely Hazardous Substances: None. SARA 311/312 Hazard Type: Immediate (acute) Health Hazard. SARA 313 Listed Ingredients: None. SECTION 16 - OTHER INFORMATION Other Regulations/Legislation which apply to this product: Substances used to manufacture this product do not require listing under California, Massachusetts, New Jersey or Pennsylvania state regulations. Section(s) Revised: Company logo revised. Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks. M-57 Rev. 1/2004