SAFETY DATA SHEET (SDS)

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1 SAFETY DATA SHEET (SDS) Document No: SDS/WS-1.0 Issue No: 1.0 Issue Date: 13-Jan-15 BRAND NAME PRODUCT NAME PRODUCT CODE BARCODE NUMBER PROTANE NATURALS Moroccan Argan Oil Hair Spray SDS Version Number: 1 SDS Version Date: IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name: Other Names: Recommended Use: Supplier Name: ABN: Street Address: Telephone Number: Facsimile Number: Emergency Telephone No: Moroccan Argan Oil Hair Spray N/A Styling of hair McBride Australia Pty Ltd /400 Canterbury Road, Surry Hills, Melbourne VICTORIA AUSTRALIA 61 (0) (0) Poisons Information Centre (phone Australia ) 2. HAZARDS IDENTIFICATION Statement of Hazardous or Dangerous Nature: Classification: NON HAZARDOUS ACCORDING TO CRITERIA OF THE AUSTRALIAN SAFETY AND COMPENSATION COUNCIL (NOHSC) CLASSIFIED AS DANGEROUS GOODS ACCORDING TO AUSTRALIAN DANGEROUS GOODS (ADG) CODE Risk Phrase(s): see Approved Criteria for Classifying Hazardous Substances (NOHSC: ) R12 - Extremely flammable Safety Phrase(s): see Approved Criteria for Classifying Hazardous Substances (NOHSC: ) S2 - Keep out of the reach of children S16 - Keep away from sources of ignition - No smoking S23 - Do not breathe spray S24 - Avoid contact with skin S25/26 - Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advise. S47 - Keep at temperature not exceeding 50 C S45 - In case of fire, use carbon dioxide, powder extinguishing agents or water directed spray. In case of accident or if you feel unwell seek medical advise immediately (show the label where possible) Hazard pictogram: see Labelling of Workplace Hazardous Chemicals Code of Practice (Safe Work Australia December 2011) This document becomes uncontrolled once printed. Page 1 of 5

2 3. COMPOSITION / INFORMATION ON INGREDIENTS Components CAS No. Proportion Butane/Propane/Isobutane % Ethanol % 4. FIRST AID MEASURES For advice, contact Poisons Information Centre (phone Australia ) or a doctor (For each route of exposure provide indication of medical attention and special treatment needed including description of most important symptoms, acute and delayed) Inhalation: Remove from site of exposure into fresh air and keep at rest in a position comfortable for breathing. Skin Contact: Eye Contact: Ingestion: Note to Physician: If skin irritation occurs, wash the skin with soap and running water. Contact a doctor in the event of skin irritation persists Immediately wash the eye with plenty of water for at least 10 minutes, holding the eye open. Remove contact lenses if present and easy to do so and continue rinsing eyes for 15 minutes. If redness or irritation persists, obtain medical advice. Not expected to produce significant adverse health effects when the recommended instructions for use are followed. If swallowed, do not induce vomiting. Wash out the mouth with water. Obtain medical advice immediately. In case of accidental ingestion, dilute with fluids (water or milk). Contact a Doctor or the Poisons Information Centre (Phone Australia ). Treat symptomatically. 5. FIRE FIGHTING MEASURES Hazards from combustion products: Precautions for firefighters and special protective equipment: Suitable extinguishing material: Flammability - Extremely flammable aerosol. Explosion Hazard- Class 2.1 Flammable Gas Pressurised container. May burst if heated. In the event of fire/heat, heating may cause expansion Wear Safe Work Australia approved Self Contained Breathing Apparatus (SCBA) and full body protective clothing. Prevent, by any means available, spillage from entering drains or water course. Use water delivered All common extinguishing agents: carbon dioxide, powder or water directed spray is suitable. This document becomes uncontrolled once printed. Page 2 of 5

3 6. ACCIDENTAL RELEASE MEASURES Emergency procedures: Methods and materials for containment and clean up: 7. HANDLING AND STORAGE Immediately contact police or fire brigade. Spill or leak area should be isolated immediately. Eliminate all sources of ignition. Keep unauthorized personnel away. Keep upwind and to higher ground. When a large quantity is involved in fire, consider initial evacuation. Send message to police and fire brigade. Tell them the Minor location, Spills material, UN Number, quantity and emergency contact as well as damage observed. Eliminate all ignition sources (No smoking, flares, sparks or flame). Clean up all spills immediately. If water is available, spray leaking containers to reduce ignition hazard and disperse gas. Ventilate area. Avoid breathing vapours and contact with skin and eyes. Use only as directed. Extremely flammable- Do not spray on a open flame or other ignition source; Do not Precautions for safe handling: pierce or burn, even after use. Keep away from sources of ignition - No smoking. Keep out of reach of children. Avoid contact with eyes. ⁰ Keep out of reach of children. Store in a cool dry, well ventilated area. Pressurised container. Protect from Conditions for safe storage: sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn this can, even when empty. Store away from corrosive products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the ADG Code for Dangerous Goods Class EXPOSURE CONTROLS / PERSONAL PROTECTION National Exposure Standards: Ethanol ( ): 1000ppm Butane (1097-8): 800ppm Biological Limit Values: Engineering Controls: Personal Protective Equipment Not required if used in accordance with label instructions. Local exhaust ventilation may be necessary to minimise excessive vapour concentration, if levels are likely to be high or in a confined space. Wear safety glasses and protective gloves. Wear respirator complying with AS1715 and AS1716 if concentration levels are high. Not required if used in accordance with label instructions. Wear safety glasses and protective gloves. Wear respirator complying with AS1715 and AS1716 if concentration levels are high. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Colour: Odour: ph: Specific Gravity or Density: Vapour Pressure: Vapour Density: Percent Volatiles: Boiling Point Range: Freezing/ Melting Point: Solubility: Flash Point (include method detection): Flammability Limits: Ignition Temperature: Aerosol, Colourless spray Colourless Pleasant fruity smell /-0.01 (@25 C) Above 300kPa (3 bar) at 50 C N/A Partial solubility in water, solubility in solvents (-)80 C Do not expose to temperatures exceeding 50 C Other: This document becomes uncontrolled once printed. Page 3 of 5

4 10. STABILITY AND REACTIVITY Chemical Stability: Conditions to avoid: Incompatible Materials: Hazardous Decomposition Products: Hazardous Reactions: Stable under normal ambient conditions of storage and use. Avoid heat sources. Heat, flames and sparks. Avoid static charge and discharge with high concentrations and in confined space. Avoid damp conditions. Strong oxidising agents, flammable liquids. 11. TOXICOLOGICAL INFORMATION HEALTH EFFECTS Ingestion: Eye Contact: Skin Contact: Inhalation: Long term effects: Acute Toxicity/ Chronic Toxicity: (ie LD 50 ) Unlikely due to high volatility of product, but, is harmful if ingested Liquid will cause severe damage, vapour may irritate eyes. May cause cold burn. Repeated or prolonged contact may irritate skin. Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. May cause light-headedness, dizziness and drowsiness. Excessive exposure may cause asphyxiation. Not classified Not classified 12. ECOLOGICAL INFORMATION Ecotoxicity: Persistence and Degradability: Mobility: Other Adverse Effects: No known significant effects or critical hazards. Propellant will vaporise rapidly when released to atmosphere. Propellant consists of hydrocarbons that photo chemically decompose under atmospheric conditions. 13. DISPOSAL CONSIDERATIONS Disposal methods: (including container disposal) Special precautions for landfill or incineration: Completely emptied packages can be recycled. Filled, unused packages must be disposed of separately in accordance with the waste management directives of the municipality. Do not pierce Keep out of reach of children. Spray in well ventilated area. Keep away from sources of ignition No smoking. Extremely flammable- Do not spray on a naked flame or any incandescent material. 14. TRANSPORT INFORMATION Regulation ADG IMDG IATA UN Number Proper Shipping Name DG Class Packing Group Label 1950 AEROSOLS, Flammable 2.1 2YE/3WE 1950 AEROSOLS, Flammable 2.1 2YE/3WE 1950 AEROSOLS, Flammable 2.1 2YE/3WE Additional Information This document becomes uncontrolled once printed. Page 4 of 5

5 15. REGULATORY INFORMATION Poisons Schedule (Australia only): APVMA Status: TGA Status: AICS Status: No constituents of this product are regulated by Poisons Standard All constituents of this product are listed on the AICS. 16. OTHER INFORMATION SDS Version Number: 1 SDS Version Date: Reason for issue: New Product Key/Legend to Abbreviations and Acronyms used in the SDS: Abbreviation/Acronym ADG AICS APVMA AQIS AS ASCC DG ERG Code IATA IMDG LD 50 NOHSC SDS STEL TGA TLV TWA UN Number Meaning Australian Code for the Transport of Dangerous Goods by Road and Rail Australian Inventory of Chemical Substances Australian Pesticides and Veterinary Medicines Authority Australian Quarantine and Inspection Service Australian Standard (as issued by Standards Australia) Australian Safety and Compensation Council Dangerous Goods Emergency Response Guidebook Code. The Emergency Response Guidebook is used by first responders (eg firefighters, police officers and ambulance personnel) when responding to a transportation emergency involving hazardous materials. International Air Transport Association International Maritime Dangerous Goods The median lethal toxicological dose, LD 50 is an abbreviation for Lethal Dose, 50%. of a toxic substance. This is the dose required to kill half the members of a tested population. National Occupational Health and Safety Commission Safety Data Sheet Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There should be at least 60 minutes between successive exposures at the STEL. Therapeutic Goods Administration Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical agents to which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect. Time Weighted Average - The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day working week. UN numbers are four-digit numbers that identify hazardous substances, and articles (such as explosives, flammable liquids, toxic substances, etc.) in the framework of international transport. This SDS has been prepared by the ALDI Stores product supplier from current technical data and summarises at the date of issue their best knowledge of the health and safety information of the product, and in particular how to safely handle and use the product in the workplace. This SDS may only be reproduced in full. Summaries or excerpts from this SDS may not contain all the relevant information and thus are not permitted. ALDI Stores gives no warranty and makes no representation as to the accuracy, reliability or completeness of the information contained in this SDS. Please be aware that the information in this SDS may be subject to change and may no longer be current. The user should make their own determination in light of their own circumstances as to the suitability of this information and the safe conditions for the use of this product. To the extent permitted by law, ALDI Stores will not be liable for any loss, damage or expense arising from the use of this SDS, whether caused by the negligent act or omission of ALDI Stores or otherwise. End of SDS This document becomes uncontrolled once printed. Page 5 of 5

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