SAFETY DATA SHEET IKO WATER BASED ADHESIVE 3.5 L (Retail Version) IKO WATER BASED ADHESIVE (Commercial Version)

Transcription

1 SECTION 1 SUBSTANCE IDENTITY AND COMPANY CONTACT INFORMATION PRODUCT TRADE IKO Water Based Adhesive Water-based Primer Adhesive PRODUCT NUMBER , CHEMICAL FAMILY PRODUCT USE MANUFACTURER/SUPPLIER WEBSITE EMERGENCY NUMBER Mixture Primer Adhesive BramCal Production Ltd. 305 Rutherford Road Brampton, Ontario L6W 3R5 CANUTEC: (24 hours information only) SECTION 2 HAZARD IDENTIFICATION CLASSIFICATION OF THE SUBSTANCE OR MIXTURE SIGNAL WORD WARNING SYMBOL(S) CLASSIFICATION Acute toxicity (Inhalation) - Category 4 Carcinogenicity -Category 2 Eye irritation - Category 2 Skin irritation - Category 2 Specific target organ toxicity (repeated exposure) - Category 2 HAZARD STATEMENTS PRECAUTIONARY STATEMENTS H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled. H315+H319 Causes skin and eye irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands and skin thoroughly after handling. P280 Wear eye protection/face protection. Wear protective gloves. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep Page 1 of 8

2 comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/attention if you feel unwell. P501 Dispose of contents and container in accordance with local, regional, national and international regulations. NFPA HMIS SECTION 3 CHEMICAL COMPOSITION AND DATA ON COMPONENTS HAZARDOUS CHEMICAL % (w/w) CAS NUMBER Water < Asphalt (bitumen) < Potassium hydroxide < Sodium hydroxide < SECTION 4 FIRST AID INHALATION INGESTION SKIN CONTACT EYE CONTACT ACUTE AND CHRONIC SYMPTOMS MEDICAL ATTENTION Remove source of exposure or move to fresh air. Keep at rest in a position comfortable for breathing. Get medical advice or attention if you feel unwell. Rinse mouth with water. Get medical advice or attention if you feel unwell or are concerned. Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. Get medical advice or attention if you feel unwell. Quickly and gently blot or brush chemical off the face. Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for minutes, while holding the eyelid(s) open. Remove contact lenses, if present and easy to do. If eye irritation persists, get medical advice or attention. Refer to section 11, Toxicological Information, for additional information. Page 2 of 8

3 SECTION 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA FIRE FIGHTING FLAMMABILITY Not combustible. Use extinguishing agent suitable for surrounding fire. Heating increases the release of toxic vapour. Evacuate area. Approach fire from upwind to avoid hazardous vapours or gases. Before entry, especially into confined areas, use an appropriate monitor to check for: toxic gases or vapours. Not applicable. PROPERTIES: FLASH POINT FLAMMABLE LIMITS IN AIR AUTO IGNITION TEMPERATURE SPECIAL PPE FOR FIRE-FIGHTERS Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE MEASURES AND EMERGENCY PROCEDURES ENVIRONMENTAL PRECAUTIONS SPILL MANAGEMENT Emergency responders: use the personal protective equipment recommended in Section 8, Exposure Control and Personal Protection. Increase ventilation to area or move leaking container to a well-ventilated and secure area. Remove or isolate incompatible materials as well as other hazardous materials. It is good practice to prevent releases into the environment. Do not allow into any sewer, on the ground or into any waterway. If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas. Contain and soak up spill with absorbent that does not react with spilled product. Place used absorbent into suitable, covered, labeled containers for disposal. Contaminated absorbent poses the same hazard as the spilled product. SECTION 7 - HANDLING AND STORAGE HANDLING PROCEDURE Avoid breathing in this product. Do not get in eyes, on skin or on clothing. Do not swallow. Only use where there is adequate ventilation. Avoid generating vapours or mists. Avoid heating that will Page 3 of 8

4 increase the amount of vapours. Wash hands thoroughly after handling this material. STORAGE PRECAUTIONS Store in an area that is: cool, ventilated. Protect from freezing. SECTION 8 EXPOSURE CONTROL AND PERSONAL PROTECTION CHEMICAL Asphalt (Bitumen) Fumes Potassium hydroxide Sodium hydroxide OCCUPATIONAL EXPOSURE LIMITS ALBERTA ONTARIO BRITISH COLUMBIA OSHA TWA : 5 TWA : 0.5 TWA : 0.5 No information mg/m 3 mg/m 3 mg/m 3 available. Ceiling : 2 Ceiling : 2 Ceiling : 2 No information mg/m 3 mg/m 3 mg/m 3 available. TWA : 2 Ceiling : 2 Ceiling : 2 Ceiling : 2 mg/m 3 mg/m 3 mg/m 3 mg/m 3 Ceiling : 2 mg/m 3 ACGIH TWA : 0.5 mg/m 3 TWA : 2 mg/m3 STEL : 2 mg/m 3 ENGINEERING MEASURES Use local exhaust ventilation, if general ventilation is not adequate to control amount in the air. Provide eyewash in work area, if contact or splash hazard exists. PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY PROTECTION SKIN AND BODY PROTECTION EYE PROTECTION HYGIENE MEASURES OTHER CONTROLS Wear a NIOSH approved air-purifying respirator with an organic vapour cartridge. Wear chemical safety goggles. Wash exposed skin prior to eating, drinking or smoking and at the end of each shift. Wash contaminated clothing prior to reuse. SECTION 9 PHYSCAL AND CHEMICAL PROPERTIES APPEARANCE (PHYSICAL STATE, COLOR etc.) ODOR ODOR THRESHOLD PH Brown-black viscous liquid Page 4 of 8

5 MELTING POINT/FREEZING POINT INITIAL BOILING POINT AND BOILING RANGE FLASH POINT EVAPORATION RATE FLAMMABILITY UPPER/LOWER FLAMMABILITY/EXPLOSIVE LIMITS VAPOR PRESSURE VAPOR DENSITY MOLECULAR WEIGHT SOLUBILITY(IES) PARTITION COEFFICIENT: N- OCTANOL/WATER AUTO-IGNITION TEMPERATURE Not available (melting); 0ºC (32ºF) (estimated) (freezing) 100ºC (212ºF) (estimated) Soluble in water. SPECIFIC GRAVITY 1.01 VISCOSITY SECTION 10 STABILITY AND REACTIVITY REACTIVITY: CHEMICAL STABILITY POSSIBILITY OF HAZARDOUS REACTIONS CONDITIONS TO AVOID INCOMPATIBLE MATERIALS HAZARDOUS DECOMPOSITION PRODUCTS Normally stable. Freezing. Prolonged exposure to high temperatures. Strong acids (e.g. hydrochloric acid), oxidizing agents (e.g. peroxides). Page 5 of 8

6 SECTION 11 TOXICOLOGICAL INFORMATION ACUTE/CHRONIC TOXICITY CHEMICAL Asphalt (Bitumen) Fume Potassium hydroxide LC50 LD50 (ORAL) LD50 (DERMAL) No information available. No information available mg/kg (rat) 2001 mg/kg (rat) 333 mg/kg (rat) No information available. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE PRIMARY ROUTE OF EXPOSURE Inhalation HEALTH EFFECTS: EYES SKIN INHALATION INGESTION STOT (SPECIFIC TARGET ORGAN TOXICITY)- SINGLE EXPOSURE STOT (SPECIFIC TARGET ORGAN TOXICITY) REPEATED EXPOSURE Human experience and animal tests show mild irritation. Human experience and animal tests show mild irritation. May cause dermatitis. Symptoms may include dry, red, cracked skin (dermatitis). CARCINOGENICITY REPRODUCTIVE TOXICITY: CHEMICAL Asphalt (Bitumen) fume Sodium hydroxide IARC ACGIH NTP OSHA Group 2B Not listed Not listed Not listed Not designated Not listed Not listed DEVELOPMENT OF OFFSPRING Page 6 of 8

7 SEXUAL FUNCTION AND FERTILITY GERM CELL MUTAGENICITY SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY Acute Aquatic Toxicity: CHEMICAL Sodium hydroxide LC50 FISH 45.5 mg/l (96-hour) EC50 CRUSTACEA No information available. ErC50 AQUATIC PLANTS No information available ErC50 ALGAE No information available PERSISTENCE & DEGRADABILITY BIODEGRADATION MOBILITY BIOACCUMULATION POTENTIAL Does not degrade rapidly based on quantitative tests. SECTION 13 DISPOSAL CONSIDERATIONS DISPOSAL RECOMMENDATIONS Dispose of contents and container in accordance with local, regional, national and international regulations. SECTION 14 TRANSPORT INFORMATION Not regulated under Canadian TDG regulations. SPECIAL PRECAUTIONS: Not applicable TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 and the IBC CODE: Not applicable SECTION 15 - REGULATIONS SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS CANADA Domestic Substances List (DSL)/Non-Domestic Substances List (NDSL): Page 7 of 8

8 All ingredients are listed on the DSL/NDSL. USA Toxic Substances Control Act (TSCA) Section 8(b): All ingredients are listed on the TSCA inventory. SECTION 16 OTHER INFORMATION REVISION DATE OF SDS January 23, 2018 REPLACES THE MSDS/SDS FROM PREPARED BY June 30, 2017 HSE department GENERAL INFORMATION WEBSITE OTHER INFO/DISCLAMERS Read this Safety Data Sheet before handling or disposing of this product. This product safety information is provided to help our customers with health, safety and/or environmental matters. We have taken reasonable effort to ensure that the test methods and sources for this data are correct and reliable, however, we give no warranty, expressed or implied, regarding its correctness. Since conditions or methods of handling and using this product are beyond our control, we do not assume responsibility and expressly disclaim liability for damages resulting from or connected with the handling, storage, use or disposal of the product. Page 8 of 8