SAFETY DATA SHEET Bilt Hamber Laboratories - Dynax UB Firm Film 750ml Aerosol

Transcription

1 REVISION DATE 17/06/2016 SDS No SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PRODUCT NO. 362 SUPPLIER Bilt Hamber Laboratories Radford Way Billericay Essex CM12 OEG Tel. +44 (0) (Hours 09:00-17:00 Mon to Fri) Fax. +44 (0) technical@bilthamber.com Permanent Painted Coatings Unit 1 / 4 Prosperity Parade WARRIEWOOD NSW 2102 Tel (02) Hours Mon to Fri 2 HAZARDS IDENTIFICATION Extremely flammable Vapours may cause drowsiness and dizziness. Irritating to skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1999/45) Xi;R38. F+;R12. N;R50/53. R67. PHYSICAL AND CHEMICAL HAZARDS Pressurised container: Must not be exposed to temperatures above 50 C. The product is extremely flammable, and explosive vapour/air mixtures may be formed even at normal room temperatures. HUMAN HEALTH In high concentrations, vapours and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content % Classification (67/548/EEC) BUTANE % F+;R12 HEPTANE % F;R11 Xn;R65 Xi;R38 R67 N;R50/53 ISOBUTANE % F+;R12 NAPHTHA (PETROLEUM) HYDROTREATED % Xn;R65. R10,R66. HEAVY PROPANE % F+;R12 The Full Text for all R-Phrases is Displayed in Section 16 4 FIRST-AID MEASURES GENERAL INFORMATION Move the exposed person to fresh air at once. INHALATION Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Keep the affected person warm and at rest. Get prompt medical attention. INGESTION Immediately rinse mouth and provide fresh air. Do not induce vomiting. Get medical attention. SKIN CONTACT Wash skin with soap and water. Get medical attention if any discomfort continues. EYE CONTACT 1 / 4

2 REVISION DATE 17/06/2016 SDS No Immediately rinse with water. Continue to rinse for at least 15 minutes. Make sure to remove any contact lenses from the eyes before rinsing. Get medical attention promptly if symptoms occur after washing. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Water spray, foam, dry powder or carbon dioxide. SPECIAL FIRE FIGHTING PROCEDURES Use water spray to reduce vapours. Aerosol cans may explode in a fire. Cool aerosol containers exposed to heat with water spray and remove container, if no risk is involved. 2 / 4

3 REVISION DATE 17/06/2016 SDS No UNUSUAL FIRE & EXPLOSION HAZARDS Extremely flammable. Forms explosive mixtures with air. May explode in a fire. Vapours are heavier than air and may spread near ground to sources of ignition. SPECIFIC HAZARDS Pressurised container: Must not be exposed to temperatures above 50 C. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area. ENVIRONMENTAL PRECAUTIONS Avoid discharge into drains. SPILL CLEAN UP METHODS Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry sand or earth and place into containers. Provide ventilation and confine spill. Do not allow runoff to sewer. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Keep away from heat, sparks and open flame. Read and follow manufacturer's recommendations. Avoid inhalation of vapours and spray mists. Do not spray on a naked flame or any incandescent material. When sprayed on a naked flame or any incandescent material the aerosol vapours can be ignited. STORAGE PRECAUTIONS Extremely flammable. Store at moderate temperatures in dry, well ventilated area. Keep away from heat, sparks and open flame. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name STD TWA - 8 Hrs STEL - 15 Min Notes BUTANE WEL 600 ppm 1450 mg/m3 750 ppm 1810 mg/m3 HEPTANE WEL 500 ppm ISOBUTANE Asphyxiating Asphyxiating NAPHTHA (PETROLEUM) HYDROTREATED HEAVY PROPANE OES 150 ppm 1000 mg/m3 Asphyxiating Asphyxiating WEL = Workplace Exposure Limit. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. In case of inadequate ventilation use suitable respirator. HAND PROTECTION Protective gloves should be used if there is a risk of direct contact or splash. EYE PROTECTION Wear approved chemical safety goggles where eye exposure is reasonably probable. HYGIENE MEASURES When using do not eat, drink or smoke. Wash promptly if skin becomes wet or contaminated. 9 PHYSICAL AND CHEMICAL PROPERTIES 3 / 4

4 REVISION DATE 17/06/2016 SDS No APPEARANCE COLOUR ODOUR SOLUBILITY Aerosol Black of solvents Insoluble in water FLASH POINT ( C) -40 AUTO IGNITION 215 TEMPERATURE ( C) FLAMMABILITY LIMIT - LOWER(%) 0.6 FLAMMABILITY LIMIT - UPPER(%) STABILITY AND REACTIVITY 4 / 4

5 REVISION DATE 17/06/16 SDS No STABILITY Highly volatile. CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight. 11 TOXICOLOGICAL INFORMATION SKIN CONTACT Irritating to skin. EYE CONTACT Spray and vapour in the eyes may cause irritation and smarting. HEALTH WARNINGS In high concentrations, vapours are narcotic and may cause headache, fatigue, dizziness and nausea. Arrhythmia, (deviation from normal heart beat). ROUTE OF ENTRY Inhalation. Skin absorption. TARGET ORGANS Central nervous system Respiratory system, lungs MEDICAL SYMPTOMS Narcotic effect. Vapours may cause drowsiness and dizziness. 12 ECOLOGICAL INFORMATION ECOTOXICITY The product contains a substance which is very toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment. Do not allow to enter drains, sewers or watercourses. 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Make sure containers are empty before discarding (explosion risk). Do not puncture or incinerate even when empty. Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION PROPER SHIPPING NAME ENVIRONMENTALLY HAZARDOUS SUBSTANCE/MARINE POLLUTANT UN NO. ROAD AEROSOLS UN NO. SEA IMDG CLASS EMS UN NO. AIR AIR CLASS AIR SUB CLASS AIR PACK GR. ADR CLASS NO. ADR CLASS ADR PACK GROUP ADR LABEL NO. 5 / 4

6 REVISION DATE 17/06/16 SDS No N o. lass 2: Gases N/A F-D, S-U N/A 2 C 15 REGULATORY INFORMATION 6 / 4

7 REVISION DATE 17/05/2012 SDS No LABELLING Irritant Extremely Flammable Dangerous for the environment RISK PHRASES R12 R38 Extremely flammable. Irritating to skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. SAFETY PHRASES S2 S16 S23 Keep out of the reach of children. Keep away from sources of ignition - No smoking. Do not breathe vapour/spray. S24/25 Avoid contact with skin and eyes. S29 S51 U2 U3 Do not empty into drains. Use only in well-ventilated areas. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. UK REGULATORY REFERENCES Health and Safety at Work Act Chemicals (Hazard Information & Packaging) Regulations. The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. EU DIRECTIVES Dangerous Preparations Directive 1999/45/EC. STATUTORY INSTRUMENTS Control of Substances Hazardous to Health. APPROVED CODE OF PRACTICE Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. 16 OTHER INFORMATION REVISION DATE 17/05/2012 REV. NO./REPL. SDS GENERATED 5 RISK PHRASES IN FULL R10 R11 R12 R38 R50/53 R65 R66 R67 Flammable. Highly flammable. Extremely flammable. Irritating to skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 7 / 4

8 REVISION DATE 17/05/2012 SDS No DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8 / 4