PC RTV 450 Silicone Adhesive Safety Data Sheet

Transcription

1 SECTION 1 IDENTIFICATION Product Name: PC RTV 450 Silicone adhesive Manufacturer/Supplier: Pittsburgh Corning Corporation 800 Presque Isle Drive Information Number: Pittsburgh, PA CHEMTREC: 800/ Generic Name: Use: Chemical Family: Silicone elastomer PC RTV 450 Silicone Adhesive is a one part neutral cure, silicone adhesive/sealant formulated for use at high temperatures with FOAMGLAS insulation Organopolysiloxane mixture General Comments: General information and emergency information available 8:00 AM 5:00 PM Monday through Friday. CHEMTREC telephone number is to be used only in the event of chemical transportation emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. All non-emergency questions should be directed to technical service. SECTION 2 HAZARD(S) IDENTIFICATION HAZARD CLASSIFICATION: SIGL WORD: HAZARD STATEMENT: Potential Irritant WARNING On direct contact uncured product or its vapor may cause slight irritation to skin. On direct contact uncured product or its vapor may cause slight irritation to eyes. HAZARDOUS POLYMERIZATION: Will Not Occur ROUTES OF EXPOSURE: Inhalation, Skin, Eyes, and Ingestion. IMMEDIATE EFFECTS: INHALATION:. SKIN CONTACT:.EYE CONTACT: INGESTION: Vapor overexposure may cause drowsiness, injure blood and liver, and may irritate eyes, nose and throat. Direct contact uncured product or its vapor may cause slight irritation to skin. Direct contact uncured product or its vapor may cause slight irritation to eyes. Not a likely route of entry. No information is available. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: ACUTE: CHRONIC: Carcinogenicity None known. None known. There are no components in this product that are listed as a carcinogen by NTP, IARC, ACGIH or OSHA: PC RTV 450 SDS docx May 19, 2014

2 SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient App. % by wt. CAS # Methylethylketoxime SECTION 4 FIRST AID MEASURES GENERAL ADVICE: Get immediate medical attention for any significant overexposure. INHALATION: SKIN CONTACT: EYE CONTACT: Remove to fresh air. Immediately remove product from skin with dry cloth or towel, and wash exposed area with detergent. Flush immediately with running water for 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention immediately. INGESTION: An unlikely route of entry. Wash out mouth with water provided person is conscious. Never give anything by mouth to an unconscious person. Call a physician immediately.. SECTION 5 FIRE FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: EXPLOSION DATA: Foam, dry chemical, carbon dioxide or fine water spray. If entering a confined area, use self-contained breathing apparatus. SENSITIVITY TO MECHANICAL IMPACT: SENSITIVITY TO STATIC DISCHARGE: UNUSUAL FIRE AND EXPLOSION HAZARDS: None. Not considered flammable or combustible, but will burn if involved in a fire. HAZARDOUS COMBUSTION PRODUCTS: SPECIAL FIRE FIGHTING MEASURES: Thermal decomposition may produce toxic fumes of Carbon Monoxide, and Carbon dioxide. None. Full emergency equipment with self contained breathing apparatus and full protective clothing should be worn by firefighters. SECTION 6 ACCIDENTAL RELEASE MEASURES PRECAUTIONS FOR PERSONNEL: Ensure adequate ventilation. Wear personal protective equipment. Refer to recommendations in section 8. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling and before eating or drinking. ENVIRONMENTAL PRECAUTIONS: Shut off all ignition sources. PROCESS FOR CLEANING: Contain the spill or leak. Scrape up with rag or other material and place in container. REGULATORY REQUIREMENTS: Follow applicable OSHA regulations (29 CFR ). FOAMGLAS Industry 2 of 6 May 19, 2014

3 SECTION 7 HANDLING AND STORAGE HANDLING: STORAGE: Keep container closed when not in use. Store in a cool place. Keep away from heat, sparks and flame. Do not lay the container on its side. Use only with adequate ventilation. Avoid breathing vapor. Avoid contact with eyes and skin. Contact lens wearers take appropriate precaution. Keep out of reach of children. Store in sealed containers in a cool dry ventilated area. (Keep away from heat, sparks and flame.) SECTION 8 EXPOSURE RESTRICTIONS AND PERSOL PROTECTION EXPOSURE LIMITS Ingredient App. % by wt. TLV OSHA REL TWA OTHER CAS # Methylethylketoxime 1 None None 3 ppm TWA (Vendor) 10 ppm STEL (AIHA WEEL) 10 PPM TWA (BEI) EXPOSURE GUIDELINES: See above ENGINEERING CONTROLS: Use air-supplied breathing apparatus if local exhaust or general ventilation is not sufficient to keep the airborne contaminant concentration below the exposure limit shown above. PERSOL PROTECTIVE EQUIPMENT: EYE PROTECTION: Wear safety glasses or goggles to avoid eye contact. SKIN PROTECTION: Wear impervious gloves such as vinyl to minimize contact with skin. Wear normal protective work clothing with long sleeved shirt. RESPIRATORY PROTECTION: Not required under normal conditions of use. Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or supplied air respirator when airborne contaminant level(s) are expected to exceed exposure limits indicated on the MSDS. Follow manufacturer's directions for respirator use. ENVIRONMENTAL EXPOSURE CONTROL: No specific controls are needed. WORK/HYGIENIC PRACTICES: Avoid contact with eyes and skin. Wash thoroughly after handling and before eating or drinking. SECTION 9 PHYSICAL PROPERTIES Appearance: Aluminum paste Flash Point : C (ºF) TCC Odor: Mild ethereal odor Ignition Temperature: C (ºF) Odor Threshold: NE Evaporation Rate (BuAC=1) <1 ph Flammability: Non- Combustible Melting Point/Freezing Point: C ( F) Flammable Limits: LEL UEL Boiling Point: C (ºF) Vapor Pressure: (MM Hg): ph: Nil Solubility in Water: Insoluble Vapor Density: (Air = 1) > 1 Partition Coefficient: n-octanol/water: NE Specific Gravity: (H 2 0 = 1): 1.04 Decomposition Temperature NE Density: lbs./gal (Calculated) 8.7 Viscosity UN Percent Volatile By Volume: (%) UN FOAMGLAS Industry 3 of 6 May 19, 2014

4 VOC: g/l (lbs./gal) 40 (0.33) SECTION 10 STABILITY AND REACTIVITY REACTIVITY: STABILITY: Will react with moisture Stable POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reaction will not occur CONDITIONS TO AVOID: MATERIALS TO AVOID: DECOMPOSITION PRODUCTS: None known Water or moisture Water, moisture, or humid air can cause methylethylketoxime. Thermal breakdown of this product during fire or very high heat condition may evolve the following hazardous decomposition product: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Nitrogen oxides. Formaldehyde. SECTION 11 TOXICOLOGICAL INFORMATION CAS # INGREDIENT DERMAL LD50 INHALATION LD50 ORAL LD Methylethylketoxime ml/kg rabbit 4.8 mg/l rat 4hr 4.0 ml/kg rat CAS # INGREDIENT CARCINOGENICITY TERATOGENICITY MUTAGENICITY ACGIH IARC Methylethylketoxime None None None None SECTION 12 ECOLOGICAL INFORMATION BIODEGRADATION: BIOACCUMULATION: No information is available. AQUATIC TOXICITY: No information is available. OTHER INFORMATION: None SECTION 13 DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Can be land-filled for cured product or burned in a chemical incinerator equipped with an afterburner and scrubber. Do not dispose the emptied container unlawfully. Observe all federal, state & local laws. SECTION 14 TRANSPORT INFORMATION SPECIAL SHIPPING INFORMATION: DOT SHIPPING CLASS: TDG IMDG PIN None Not regulated. Not regulated Not regulated Not available FOAMGLAS Industry 4 of 6 May 19, 2014

5 SECTION 15 REGULATORY INFORMATION Rotterdam Convention (PIC) Annex III: listed (Tributyl tin compounds (impurities) <2ppm) US Regulatory Information OSHA 29 CFR Irritant TSCA All components of this product are listed on TSCA Inventory SARA Title III: SARA SECTION 302: None SARA SECTION 304: None SARA (311,312) HAZARD CLASS: None SARA (313) CHEMICALS: CERCLA: RCRA: Refer to section 13 CPSC CLASSIFICATION: HMIS: FLAMMABILITY: 1 REACTIVITY: 0 HEALTH: 2 NFPA: FLAMMABILITY: 1 REACTIVITY: 0 HEALTH: 2 WHMIS CLASSIFICATION: D2B EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS) STATUS: Listed on the EINECS. LABELING ACCORDING TO EC-REGULATIONS REQUIRED: SYMBOL: Xn R-PHRASE : (R-40) Limited evidence of a carcinogenic effect. S-PHRASE: (S-36/37) Wear suitable protective clothing and gloves. (S-51) Use only in well-ventilated areas. CONTAINS: Methylethylketoxime ca. 1% CALIFORNIA PROPOSITION 65: A. This product contains a chemical known to the State of CA to cause birth defects or other reproductive harm. B. This product contains a chemical known to the State of CA to cause cancer. C. This product contains a chemical known to the State of CA to cause cancer and birth defects or other reproductive harm. FOAMGLAS Industry 5 of 6 May 19, 2014

6 SECTION 16 OTHER INFORMATION Prepared in accordance with 29 CFR This Product has been classified in accordance with the hazard criteria of the Controlled Products = not applicable NE = not established UN = unavailable CL = Ceiling Limit NEGL = Negligible PROP. = Proprietary AIHA WEEL = American Industrial Hygiene Association Workplace Environmental Exposure Level) BEI = Biological Exposure Index (ACGIH) THE DATA INCLUDED HEREIN ARE PRESENTED IN ACCORDANCE WITH THE VARIOUS ENVIRONMENT, HEALTH AND SAFETY REGULATIONS. IT IS THE RESPONSIBILITY OF A RECIPIENT OF THIS DATA TO REMAIN CURRENTLY INFORMED ON CHEMICAL HAZARD INFORMATION, TO DESIGN AND UPDATE ITS INFORMED ON CHEMICAL HAZARD INFORMATION, TO DESIGN AND UPDATE ITS OWN PROGRAM AND TO COMPLY WITH ALL TIOL, FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS APPLICABLE TO SAFETY, OCCUPATIOL HEALTH, RIGHT-TO-KNOW AND ENVIRONMENTAL PROTECTION. WHILE THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO BE ACCURATE, PITTSBURGH CORNING MAKES NO WARRANTY WITH RESPECT THERETO, AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. PC and FOAMGLAS are registered trademarks of Pittsburgh Corning. FOAMGLAS Industry 6 of 6 May 19, 2014