Revision Date: 12/21/2016. Telephone : (514) / 1 (800) :

Transcription

1 SECTION 1. IDENTIFICATION Product name : Manufacturer or supplier's details Company name : Sika Canada Inc. 601, avenue Delmar Pointe-Claire, QC H9R 4A9 Canada Telephone : (514) / 1 (800) Telefax : (514) Health and Safety Services s address : ehs@ca.sika.com Emergency telephone : CANUTEC (collect) (613) (24 hours) Recommended use of the chemical and restrictions on use For further information, refer to product data sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Respiratory sensitization : Category 1 Skin sensitization : Category 1 Carcinogenicity (Inhalation) Specific target organ systemic toxicity - repeated exposure (Inhalation) : Category 1A : Category 2 (hearing organs) GHS label elements Hazard pictograms : Signal Word Hazard Statements : Danger : H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. 1 / 11

2 H350i May cause cancer by inhalation. H373 May cause damage to organs (hearing organs) through prolonged or repeated exposure if inhaled. Precautionary Statements Warning : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 In case of inadequate ventilation wear respiratory protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. : Reports have associated repeated and prolonged exposure to some of the chemicals in this product with permanent brain,liver, kidney and nervous system damage. Intentional misuse by deliberate concentration and inhalation of vapors may be harmful or fatal. Other hazards None known. Supplemental information If product is in liquid or paste form, physical or health hazards listed related to dust are not considered significant. However, product may contain substances that could be potential hazards if caused to become airborne due to grinding, sanding or other abrasive processes. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients Chemical name CAS-No. Concentration (% w/w) xylene >= 1 - < 2 4,4'-methylenediphenyl diisocyanate >= 0 - < 1 ethylbenzene >= 0 - < 1 2 / 11

3 Quartz (SiO2) >= 0 - < 1 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : Move out of dangerous area. Consult a physician. Show this material safety data sheet to the doctor in attendance. : Move to fresh air. Consult a physician after significant exposure. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. : Remove contact lenses. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting without medical advice. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention. : sensitizing effects carcinogenic effects Asthmatic appearance Allergic reactions See Section 11 for more detailed information on health effects and symptoms. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause cancer by inhalation. May cause damage to organs through prolonged or repeated exposure if inhaled. : Treat symptomatically. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Further information Special protective equipment : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. : In the event of fire, wear self-contained breathing apparatus. 3 / 11

4 for fire-fighters SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. Deny access to unprotected persons. : Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Local authorities should be advised if significant spillages cannot be contained. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion Advice on safe handling Conditions for safe storage : Normal measures for preventive fire protection. : Avoid exceeding the given occupational exposure limits (see section 8). Do not get in eyes, on skin, or on clothing. For personal protection see section 8. Persons with a history of skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Smoking, eating and drinking should be prohibited in the application area. Follow standard hygiene measures when handling chemical products. : Prevent unauthorized access. Store in original container. Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Store in accordance with local regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) 4 / 11 Control parameters / Permissible concentration Basis xylene TWA 100 ppm CA AB OEL

5 Biological occupational exposure limits Ingredients CAS-No. Control parameters xylene Methylhippuric acids Biological specimen Urine 434 mg/m3 STEL 150 ppm CA AB OEL 651 mg/m3 TWAEV 100 ppm CA QC OEL 434 mg/m3 STEV 150 ppm CA QC OEL 651 mg/m3 TWA 100 ppm CA BC OEL STEL 150 ppm CA BC OEL TWA 100 ppm ACGIH STEL 150 ppm ACGIH 4,4'-methylenediphenyl diisocyanate TWA ppm CA AB OEL 0.05 mg/m3 TWA ppm CA BC OEL C 0.01 ppm CA BC OEL TWAEV ppm CA QC OEL mg/m3 TWA ppm CA ON OEL C 0.02 ppm CA ON OEL TWA ppm ACGIH ethylbenzene TWA 100 ppm CA AB OEL 434 mg/m3 STEL 125 ppm CA AB OEL 543 mg/m3 TWA 20 ppm CA BC OEL TWAEV 100 ppm CA QC OEL 434 mg/m3 STEV 125 ppm CA QC OEL 543 mg/m3 TWA 20 ppm ACGIH STEL 125 ppm ACGIH Quartz (SiO2) TWA (Respirable 0.1 mg/m3 CA ON OEL frac- tion) TWA (Respirable mg/m3 CA AB OEL par- ticulates) TWAEV 0.1 mg/m3 CA QC OEL (respirable dust) TWA (Respirable) mg/m3 CA BC OEL (Silica) TWA (Respirable fraction) mg/m3 (Silica) ACGIH Sampling time End of shift (As soon as Permissible concentration g/g creatinine Basis ACGIH BEI 5 / 11

6 ethylbenzene Sum of mandelic acid and phenyl glyoxylic acid Engineering measures Urine possible after exposure ceases) End of shift (As soon as possible after exposure ceases) 0.15 g/g creatinine ACGIH BEI : Use of adequate ventilation should be sufficient to control worker exposure to airborne contaminants. If the use of this product generates dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Personal protective equipment Respiratory protection Hand protection : Use a properly fitted NIOSH approved air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapor/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used. Remarks Eye protection Skin and body protection Hygiene measures : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary. : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. : Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Remove contaminated clothing and protective equipment before entering eating areas. Wash thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 6 / 11

7 Appearance Color Odor Odor Threshold ph : paste : various : aromatic : Not applicable Melting point/range / Freezing point Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density : Not applicable : 0.01 hpa (0.01 mmhg) Density : ca g/cm3 (23 C (73 F) ()) Solubility(ies) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Viscosity, dynamic Viscosity, kinematic Explosive properties Molecular weight : insoluble : > 20.5 mm2/s (40 C) SECTION 10. STABILITY AND REACTIVITY Reactivity : No dangerous reaction known under conditions of normal use. 7 / 11

8 Chemical stability : The product is chemically stable. Possibility of hazardous reactions Conditions to avoid Incompatible materials : Stable under recommended storage conditions. No decomposition if stored and applied as directed. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute inhalation toxicity : Acute toxicity estimate: > 40 mg/l Exposure time: 4 h Test atmosphere: vapor Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: 4,4'-methylenediphenyl diisocyanate: Acute inhalation toxicity : Acute toxicity estimate: mg/l Test atmosphere: dust/mist Method: Expert judgment Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Skin sensitization: May cause an allergic skin reaction. Respiratory sensitization: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Germ cell mutagenicity Carcinogenicity May cause cancer by inhalation. IARC Group 1: Carcinogenic to humans Quartz (SiO2) Group 2B: Possibly carcinogenic to humans 8 / 11

9 titanium dioxide ethylbenzene Carbon black NTP Known to be human carcinogen Quartz (SiO2) Reproductive toxicity STOT-single exposure STOT-repeated exposure May cause damage to organs (hearing organs) through prolonged or repeated exposure if inhaled. Aspiration toxicity SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity No data available Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects Product: Additional ecological information : Do not empty into drains; dispose of this material and its container in a safe way. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional 9 / 11

10 local authority requirements. Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION Domestic regulation TDG (road/train) Not dangerous goods International Regulations IATA-DGR Not dangerous goods IMDG-Code Not dangerous goods Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. SECTION 15. REGULATORY INFORMATION Canadian lists No substances are subject to a Significant New Activity Notification. SECTION 16. OTHER INFORMATION Revision Date : Prepared by : R & D of Sika Canada Inc. Notice to Reader: The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material, product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone number listed. SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS. All sales of Sika products are subject to its current terms and conditions of sale available at or / 11

11 CA / Z8 Full text of other abbreviations ADR Accord européen relatif au transport international des marchandises Dangereuses par Route CAS Chemical Abstracts Service DNEL Derived no-effect level EC50 Half maximal effective concentration GHS Globally Harmonized System IATA International Air Transport Association IMDG International Maritime Code for Dangerous Goods LD50 Median lethal dosis (the amount of a material, given all at once, which causes the death of 50% (one half) of a group of test animals) LC50 Median lethal concentration (concentrations of the chemical in air that kills 50% of the test animals during the observation period) MARPOL International Convention for the Prevention of Pollution from Ships, 1973 as modified by the Protocol of 1978 OEL Occupational Exposure Limit PBT Persistent, bioaccumulative and toxic PNEC Predicted no effect concentration REACH Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency SVHC Substances of Very High Concern vpvb Very persistent and very bioaccumulative 11 / 11