MATERIAL SAFETY DATA SHEET
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1 MATERIAL SAFETY DATA SHEET BAYER POLYMERS LLC PRODUCT SAFETY & REGULATORY AFFAIRS 100 Bayer Road Pittsburgh, PA TRANSPORTATION EMERGENCY NON-TRANSPORTATION CALL CHEMTREC: BAYER EMERGENCY PHONE...: (412) INTERNATIONAL: BAYER INFORMATION PHONE.: (800) CHEMICAL PRODUCT IDENTIFICATION: PRODUCT NAME...: Bayer Butyl 301 PRODUCT CODE...: R17301 CHEMICAL FAMILY...: Butyl (IIR) Rubber CHEMICAL NAME...: 1,3-Butadiene, 2-methyl-, polymer with 2-methyl-1-propene CAS NUMBER...: PRODUCT USE...: Rubber articles 2. COMPOSITION/INFORMATION ON INGREDIENTS: INGREDIENT NAME /CAS NUMBER EXPOSURE LIMITS CONCENTRATION (%) ***** HAZARDOUS INGREDIENTS ***** This product contains no hazardous ingredients as defined under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR ***** OTHER INGREDIENTS ***** The following potentially hazardous constituent(s) are contained at levels below OSHA disclosure requirements and are provided for informational purposes only. Residual Isoprene Monomer OSHA : Not Established Less than 10ppm ACGIH: Not Established Product Code: R17301 MSDS Page 1
2 2. COMPOSITION/INFORMATION ON INGREDIENTS (Continued) INGREDIENT NAME /CAS NUMBER EXPOSURE LIMITS CONCENTRATION (%) Residual Isobutene Monomer OSHA : Not Established Less than 10ppm ACGIH: Not Established 3. HAZARDS IDENTIFICATION: ***************************************************************** * EMERGENCY OVERVIEW * * * * CAUTION! Color: White; Form: Solid; Bales; Odor: * * Odorless; Contact with hot material will cause thermal * * burns; Irritating gases/fumes may be given off during * * burning or thermal decomposition. * ***************************************************************** POTENTIAL HEALTH EFFECTS: ROUTE(S) OF ENTRY...: Inhalation; Skin Contact; Eye Contact HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE: ACUTE EFFECTS OF EXPOSURE...: Material is a non-reactive solid and has not been associated with any adverse acute health effects. Mechanical irritation (i.e. abrasion) may occur if material is introduced into the eye. Eyes may become red, feel scratchy and may tear. NOTE: Gases and fumes evolved during the thermal processing or decomposition of this material may irritate the eyes, skin and respiratory tract. CHRONIC EFFECTS OF EXPOSURE...: No applicable information was found concerning any adverse chronic health effects from using this product. However, repeated or prolonged skin contact is to be avoided. CARCINOGENICITY...: The components of this product are not listed by NTP, IARC or regulated as a carcinogen by OSHA. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE...: None known EXPOSURE LIMITS...: Based on the physical form this product is unlikely to dust. However, if dusting should occur, the ACGIH-TLV TWA for Particulates Not Otherwise Classified (PNOC) of 10 mg/m3 for inhalable particulates and 3 mg/m3 for respirable particulates is recommended. Observe a more stringent limit for product gases and fumes if applicable. Product Code: R17301 MSDS Page 2
3 4. FIRST AID MEASURES: FIRST AID FOR EYES...: Flush eyes with plenty of lukewarm water. FIRST AID FOR SKIN...: Wash affected areas with soap and water. Get medical attention if thermal burn occurs. FIRST AID FOR INHALATION: Remove to fresh air. FIRST AID FOR INGESTION.: Get medical attention. 5. FIRE FIGHTING MEASURES: FLASH POINT...: Greater than 572 F (300 C) - Cleveland Open Cup FLAMMABLE LIMITS: UPPER EXPLOSIVE LIMIT (UEL)(%): Not Established LOWER EXPLOSIVE LIMIT (LEL)(%): Not Established AUTO-IGNITION TEMPERATURE...: May occur above 572 F (300 C) EXTINGUISHING MEDIA...: Carbon Dioxide; Foam; Water spray for large fires. SPECIAL FIRE FIGHTING PROCEDURES: Full emergency equipment with self-contained breathing apparatus should be worn by firefighters. During a fire irritating and toxic gases may be generated by thermal decomposition and combustion. 6. ACCIDENTAL RELEASE MEASURES: SPILL OR LEAK PROCEDURES...: Remove mechanically by method which minimizes generation of airborne dust. Place in appropriately marked sealable containers. 7. HANDLING AND STORAGE: STORAGE TEMPERATURE(MIN/MAX): Ambient/104 F (40 C) SHELF LIFE...: See the Handling/Storage Precautions section below. SPECIAL SENSITIVITY...: Heat, Light, Moisture HANDLING/STORAGE PRECAUTIONS: Material should be stored in a clean, dry environment in original packaging. Product should be used within 5 years of its date of manufacture. Product Code: R17301 MSDS Page 3
4 8. PERSONAL PROTECTION: EYE PROTECTION REQUIREMENTS...: Safety glasses recommended. SKIN PROTECTION REQUIREMENTS...: Gloves recommended. HAND PROTECTION REQUIREMENTS...: Cloth gloves recommended. VENTILATION REQUIREMENTS...: Thermal processing equipment should be ventilated to control gases and fumes given off during processing. Residual monomers may be released at elevated processing temperatures. Engineering controls should be sufficient to ensure airborne levels do not approach or exceed the exposure limit values for these residuals. RESPIRATOR REQUIREMENTS...: A NIOSH/MSHA approved dust respirator is recommended if the airborne dust concentration is near or exceeds the exposure limits for Particulates Not Otherwise Classified (PNOC) or an organic vapor cartridge should be used if ventilation is not sufficient to control fumes released during thermal processing. ADDITIONAL PROTECTIVE MEASURES...: Emergency showers and eye wash stations should be available. Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train employees on the safe use and handling of this product. 9. PHYSICAL AND CHEMICAL PROPERTIES: PHYSICAL FORM...: Solid APPEARANCE...: Bales COLOR...: White ODOR...: Odorless ph...: Not Applicable BOILING POINT...: Not Applicable MELTING/FREEZING POINT...: Not Applicable SOLUBILITY IN WATER...: Insoluble SOLUBILITY (NON AQUEOUS)..: Hydrocarbons SPECIFIC GRAVITY...: 0.92 BULK DENSITY...: Not Established % VOLATILE BY VOLUME...: Negligible % VOLATILE BY WEIGHT...: 0.3% Max. EVAPORATION RATE...: Not Applicable (Butyl acetate = 1) VAPOR PRESSURE...: Not Applicable 10. STABILITY AND REACTIVITY: STABILITY...: This is a stable material. HAZARDOUS POLYMERIZATION...: Will not occur. INCOMPATIBILITIES...: Oxidizing agents Product Code: R17301 MSDS Page 4
5 10. STABILITY AND REACTIVITY (Continued) - INSTABILITY CONDITIONS...: Product may decompose exothermically with possibility of ignition at temperatures above 392 F (200 C). DECOMPOSITION TEMPERATURE..: Above 392 F (200 C) DECOMPOSITION PRODUCTS...: By fire or thermal decomposition: Carbon monoxide (CO), carbon dioxide (CO2), hydrocarbons, others undetermined. 11. TOXICOLOGICAL INFORMATION: ACUTE TOXICITY SKIN EFFECTS...: Non-irritating to rabbit skin. * * Tested according to the modified Draize Method (16 CFR ) 12. ECOLOGICAL INFORMATION: NO ECOLOGICAL INFORMATION AVAILABLE 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD...: Material may be incinerated or landfilled in compliance with federal, state/provincial and local environmental control regulations. 14. TRANSPORTATION INFORMATION: TECHNICAL SHIPPING NAME...: Butyl Rubber FREIGHT CLASS BULK...: Rubber, Crude FREIGHT CLASS PACKAGE...: Rubber, Crude (NMFC ) PRODUCT LABEL...: Bayer Butyl 301 DOT (DOMESTIC SURFACE) HAZARD CLASS OR DIVISION...: Non-Regulated IMO / IMDG CODE (OCEAN) HAZARD CLASS DIVISION NUMBER...: Non-Regulated Product Code: R17301 MSDS Page 5
6 14. TRANSPORTATION INFORMATION (Continued) --- IMO / IMDG CODE (continued) ICAO / IATA (AIR) HAZARD CLASS DIVISION NUMBER...: Non-Regulated 15. REGULATORY INFORMATION: OSHA STATUS...: This product is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR However, thermal processing and decomposition fumes from this product may be hazardous as noted in Section 3. TSCA STATUS...: On TSCA Inventory CERCLA REPORTABLE QUANTITY..: None SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES..: None SECTION 311/312 HAZARD CATEGORIES...: Non-hazardous under Section 311/312 SECTION 313 TOXIC CHEMICALS...: None RCRA STATUS...: If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR ) FOREIGN CHEMICAL INVENTORY LIST(S) CANADA DSL...: Listed The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. COMPONENT NAME /CAS NUMBER CONCENTRATION STATE CODE Butyl Rubber Essentially 100 % PA3, NJ4 Residual Isoprene Monomer Less than 10ppm CA1, MA Product Code: R17301 MSDS Page 6
7 15. REGULATORY INFORMATION (Continued) COMPONENT NAME /CAS NUMBER CONCENTRATION STATE CODE Residual Isobutene Monomer Less than 10ppm MA CA1 = Warning! This chemical is known to the State of California to cause cancer. MA = Massachusetts Hazardous Substance List NJ4 = New Jersey Other - included in 5 predominant ingredients > 1% PA3 = Pennsylvania Non-hazardous present at 3% or greater. 16. OTHER INFORMATION: HMIS RATINGS: Health Flammability Reactivity =Minimal 1=Slight 2=Moderate 3=Serious 4=Severe Bayer s method of hazard communication is comprised of Product Labels and Material Safety Data Sheets. HMIS ratings are provided by Bayer as a customer service. REASON FOR ISSUE...: Revised physical properties PREPARED BY...: W. W. Henderson, Ph.D. APPROVED BY...: J. H. Chapman APPROVAL DATE...: 09/01/2001 SUPERSEDES DATE...: 11/01/2000 MSDS NUMBER...: This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Bayer Corporation. The data on this sheet relates only to the specific material designated herein. Bayer Corporation assumes no legal responsibility for use or reliance upon these data. Product Code: R17301 MSDS Page 7 Last page
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