MATERIAL SAFETY DATA SHEET

Transcription

1 SECTION 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product name: TEROSON SB 3140 WH AE Product-Code: Intended use: Road stone anti chip agent Supplier: Henkel Australia Pty Ltd Canterbury Road 3137 Kilsyth, Victoria Australia Phone: +61 (3) Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER: SECTION 2. HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE: Hazardous according to the criteria of ASCC. Classification of material F+ - Extremely flammable Xn - Harmful Risk phrases: R12 Extremely flammable. R18 In use, may form flammable/explosive vapour-air mixture. R20/21 Harmful by inhalation and in contact with skin. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S2 Keep out of the reach of children. S16 Keep away from sources of ignition - No smoking. S23 Do not breathe gas/fumes/vapour/spray. S36 Wear suitable protective clothing. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Class or division: 2.1 Page 1 of 6 TEROSON SB 3140 WH AE

2 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS General chemical description: Styrene-butadiene (SBR) latex Solvent mixture Identity of ingredients: Chemical ingredients CAS-No. Proportion Dimethyl ether % Xylene - mixture of isomeres % Naphtha (Petroleum), hydrodesulfurized heavy, < 10 % <0,1% Benzene Ethylbenzene < 10 % < 1 % Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl, salts with bentonite Solvent naphtha (petroleum), heavy arom < 1 % non hazardous ingredients~ < 10 % SECTION 4. FIRST AID MEASURES Skin: Eyes: Inhalation: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. If necessary, see a dermatologist. Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Fresh air, oxygen supply, warmth; seek specialist medical attention. First Aid facilities: Eye wash and safety shower SECTION 5. FIRE FIGHTING MEASURES Suitable extinguishing media: Improper extinguishing agent: Decomposition products in case of fire: Particular danger in case of fire: Special protective equipment for fire-fighters: Hazchem code: All common extinguishing agents are suitable. Water jet (solvent-containing product). Toxic and irritating vapors forming ignitable mixtures with air. carbon oxides. Cool aerosol containers with jet of water. Containers may explode. Wear protective equipment. Wear self-contained breathing apparatus. 2YE Page 2 of 6 TEROSON SB 3140 WH AE

3 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions and emergency procedures: Environmental precautions: Clean-up methods: Sort out leaking cans, spray until empty and destroy. Wear protective equipment. Keep away from sources of ignition and naked flames. Avoid contact with skin and eyes. Don't breathe vapours or aerosole. Danger of slipping on spilled product. Keep unprotected persons away. See advice in section 8 Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems. Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to Section 13. SECTION 7. HANDLING AND STORAGE Precautions for safe handling: Conditions for safe storage: Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Take measures to prevent the build-up of electrostatic charges. Use explosion-proof equipment. Do not spray against flames or glowing bodies. Keep away from sources of ignition - no smoking. The storage regulations for aerosols apply. Store in a cool place. Keep away from heat and direct sunlight. Storage at 15 to 25 C is recommended. SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National exposure standards: Ingredient DIMETHYL ETHER form of exposure TWA (ppm) TWA (mg/m3) Peak Limit. STEL (ppm) STEL (mg/m3) (mg/m3) Page 3 of 6 TEROSON SB 3140 WH AE

4 Engineering controls: Ensure good ventilation/extraction. Eye protection: Skin protection: Goggles which can be tightly sealed. Wear protective equipment. Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Protective clothing that covers arms and legs. Respiratory protection: If inhalation risk exists, wear a respirator or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Odor: Flash point: Density: Solubility: max. VOC content: light grey liquid, Aerosol of solvent Not available g/cm3 Solvent: Water, Insoluble 574 g/l SECTION 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of temperature and pressure. Conditions to avoid: Temperatures over appr. 50 C Container may burst when heated to over 50ºC. The contents may form explosive, combustible mixture. Avoid ignition sources and naked flames. Comply with warming on container label. Incompatible materials: Strong oxidizing agents. Hazardous decomposition products: Hazardous polymerization: Irritating and toxic gases or fumes may be released during a fire. Will not occur. Page 4 of 6 TEROSON SB 3140 WH AE

5 SECTION 11. TOXICOLOGICAL INFORMATION HEALTH EFFECTS: Ingestion: Skin: Eyes: Inhalation: Chronic effects: Aspirated material can enter the lungs and result in pneumonitis. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Solvent action can dry and defat the skin, causing the skin to crack, leading to dermatitis. Causes skin irritation. May be harmful if absorbed through skin. Vapors may irritate eyes. Contact with eyes will cause irritation. Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Harmful by inhalation. Repeated excessive dermal exposure may cause marked skin irritation and may increase the possibility of allergic reactions. Toxicity data: Acute oral toxicity: Xylenes (individual or mixed isomers) Ethyl benzene LD 50 (Mouse) = 1,590 mg/kg LD 50 (Rat) = 6,670 mg/kg LD 50 (Rat) = 3,523-8,600 mg/kg LD 50 (Mouse) = 5,627 mg/kg LD 50 (Rat) = 4,300 mg/kg LD 50 (Rat) = 5.46 g/kg LD 50 (Rat) = 3,500 mg/kg SECTION 12. ECOLOGICAL INFORMATION General ecological information: Do not empty into drains, soil or bodies of water. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. SECTION 13. DISPOSAL CONSIDERATIONS Waste disposal of product: Disposal for uncleaned package: In consultation with the responsible local authority, must be subjected to special treatment. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. SECTION 14. TRANSPORT INFORMATION Road and Rail Transport: Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). UN no.: 1950 Proper shipping name: AEROSOLS Class or division: 2.1 Packaging group: Page 5 of 6 TEROSON SB 3140 WH AE

6 Hazchem code: Emergency information: EPG: 2YE Refer to the Dangerous Goods - Initial Emergency Response Guide HB 76. 2D1 Marine transport IMDG: UN no.: 1950 Proper shipping name: AEROSOLS Class or division: 2.1 Packaging group: EmS: F-D,S-U Seawater pollutant: - Air transport IATA: UN no.: 1950 Proper shipping name: Aerosols, flammable Class or division: 2.1 Packaging group: Packaging instructions (passenger) 203 Packaging instructions (cargo) 203 SECTION 15. REGULATORY INFORMATION SUSDP Poisons Schedule: None SECTION 16. OTHER INFORMATION Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code ASCC - Australian Safety and Compensation Council SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons STEL - Short term exposure limit TWA - Time weighted average Date of previous issue: Disclaimer: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in this Material Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Material Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material's characteristics and, where appropriate, to conduct their own tests in the specific context of the material's intended use. Page 6 of 6 TEROSON SB 3140 WH AE