Paint & Varnish Remover Safety Data Sheet

Transcription

1 SECTION 1: Product and company identification Product name : Paint & Varnish Remover Use of the substance/mixture : Solvent Product code : 0330 Company : Total Solutions P.O. Box Milwaukee, WI USA T (414) Emergency number : Chemtec: (800) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Carc. 2 H351 STOT SE 1 H370 STOT SE 3 H335 STOT SE 3 H336 Full text of H-phrases: see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS07 GHS08 : Harmful if swallowed Causes skin irritation Causes serious eye irritation May cause respiratory irritation May cause drowsiness or dizziness Suspected of causing cancer Causes damage to organs : Obtain special instructions before use Do not handle until all safety precautions have been read and understood Do not breathe fume, mist, spray, vapors Avoid breathing fume, gas, mist, spray, vapors Wash thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Wear eye protection, protective gloves, protective clothing If swallowed: Call a doctor, a POISON CENTER if you feel unwell If on skin: Wash with plenty of water If inhaled: Remove person to fresh air and keep comfortable for breathing If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If exposed: Call a poison center/doctor If exposed or concerned: Get medical advice/attention Call a doctor, a POISON CENTER if you feel unwell Specific treatment (see First aid measures on this label) Rinse mouth If skin irritation occurs: Get medical advice/attention If eye irritation persists: Get medical advice/attention Take off contaminated clothing and wash before reuse Store in a well-ventilated place. Keep container tightly closed Store locked up Dispose of contents/container to comply with local/regional/national regulations Date of issue: 6/29/2015 Revision date: 05/11/2015 Version: 1.0 P GHS SDS Page 1 of 6

2 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section Mixture Name Product identifier % Classification (GHS-US) dichloromethane (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 STOT SE 3, H336 STOT SE 3, H335 methanol (CAS No) Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 STOT SE 1, H370 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a physician immediately. First-aid measures after skin contact : Take off immediately all contaminated clothing and wash it before reuse. Wash immediately with lots of water. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Call a physician immediately. First-aid measures after ingestion : Do not induce vomiting. Rinse mouth with water. Drink plenty of water. Get immediate medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : May cause drowsiness or dizziness. Symptoms/injuries after inhalation : Central nervous system depression. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Toxic if swallowed Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : All extinguishing media allowed Special hazards arising from the substance or mixture Reactivity : On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. Take account of environmentally hazardous firefighting water. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Isolate from fire, if possible, without unnecessary risk For non-emergency personnel Protective equipment : Protective goggles. Gloves. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. Avoid contact with skin, eyes and clothing. Ventilate spillage area For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Stop leak if safe to do so. Stop release. Ventilate area. Date of issue: 6/29/2015 Revision date: 05/11/2015 Version: 1.0 P GHS SDS Page 2 of 6

3 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Methods for cleaning up : This material and its container must be disposed of in a safe way, and as per local legislation Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Do not get in eyes, on skin, or on clothing. Hygiene measures : Wash thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep container closed when not in use. Storage area : Meet the legal requirements. Store in a cool area. Store in a well-ventilated place. Special rules on packaging : meet the legal requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (ppm) 50 ppm (Dichloromethane (Methylene chloride); USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) 8.2. Exposure controls Personal protective equipment : Use appropriate personal protective equipment when risk assessment indicates this is necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance Odor Odor threshold ph Melting point Freezing point Boiling point : Opaque. pink to red liquid. : solvent odor Flash point : > 200 F Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Specific gravity / density Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity : 1.3 g/ml : Insoluble in water. Date of issue: 6/29/2015 Revision date: 05/11/2015 Version: 1.0 P GHS SDS Page 3 of 6

4 Viscosity, kinematic Viscosity, dynamic VOC content : < 6 % SECTION 10: Stability and reactivity Reactivity On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Chemical stability Possibility of hazardous reactions Refer to section 10.1 on Reactivity Conditions to avoid Incompatible materials Hazardous decomposition products On burning: release of toxic and corrosive gases/vapors phosgene hydrogen chloride chlorine carbon monoxide - carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. LD50 oral rat LD50 dermal rabbit > 2000 mg/kg (Rat; Literature study) > 2000 mg/kg (Rabbit; Literature study) methanol ( ) LD50 dermal rabbit mg/kg ATE CLP (oral) mg/kg body weight ATE CLP (dermal) mg/kg body weight ATE CLP (gases) ppmv/4h ATE CLP (dust, mist) mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Suspected of causing cancer. IARC group 2B - Possibly Carcinogenic to Humans Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Causes damage to organs. May cause respiratory irritation. May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Not classified : Not classified : Central nervous system depression. May cause drowsiness or dizziness. : Causes skin irritation. : Causes serious eye irritation. : Toxic if swallowed. SECTION 12: Ecological information Toxicity LC50 fish mg/l (LC50; 96 h; Pimephales promelas) EC50 Daphnia mg/l (EC50; 48 h) Persistence and degradability Date of issue: 6/29/2015 Revision date: 05/11/2015 Version: 1.0 P GHS SDS Page 4 of 6

5 Persistence and degradability Not readily biodegradable in water. Biodegradable in the soil Bioaccumulative potential BCF fish (BCF) Log Pow 1.25 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container to comply with local/regional/national/international regulations. Waste disposal recommendations : Dispose of contents/container to local/regional/national regulations. SECTION 14: Transport information Department of Transportation (DOT) Transport document description : UN1593 Dichloromethane solution, 6.1, III UN-No.(DOT) : UN1593 Proper Shipping Name (DOT) : Dichloromethane solution Transport hazard class(es) (DOT) : Class Poisonous materials 49 CFR Hazard labels (DOT) : Poison inhalation hazard Packing group (DOT) DOT Packaging Non Bulk (49 CFR 173.xxx) : 203 DOT Packaging Bulk (49 CFR 173.xxx) : 241 DOT Special Provisions (49 CFR ) DOT Packaging Exceptions (49 CFR 173.xxx) DOT Quantity Limitations Passenger aircraft/rail (49 CFR ) DOT Quantity Limitations Cargo aircraft only (49 CFR ) DOT Vessel Stowage Location : III - Minor Danger : IB3,IP8,N36,T7,TP2 : 153 : 60 L : 220 L : A Additional information Other information : This product may be elegible to be shipped as a Consumer Commodity ORM-D utilizing the exception found at 49 CFR ADR Transport by sea Air transport SECTION 15: Regulatory information All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. methanol CAS No methanol ( ) Date of issue: 6/29/2015 Revision date: 05/11/2015 Version: 1.0 P GHS SDS Page 5 of 6

6 methanol ( ) Listed on SARA Section 313 (Specific toxic chemical listings) RQ (Reportable quantity, section 304 of EPA's List of Lists) 5000 lb California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer and/or reproductive toxicity SECTION 16: Other information Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging. Full text of H-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category Acute Tox. 3 (Inhalation) Acute toxicity (inhalation) Category Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category Carc. 2 Carcinogenicity Category Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Flam. Liq. 2 Flammable liquids Category Skin Irrit. 2 Skin corrosion/irritation Category STOT SE 1 Specific target organ toxicity (single exposure) Category STOT SE 3 Specific target organ toxicity (single exposure) Category STOT SE 3 Specific target organ toxicity (single exposure) Category H225 Highly flammable liquid and vapor H301 Toxic if swallowed H302 Harmful if swallowed H311 Toxic in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H331 Toxic if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H351 Suspected of causing cancer H370 Causes damage to organs NFPA health hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. Prepared by: Technical Department This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Our company assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Date of issue: 6/29/2015 Revision date: 05/11/2015 Version: 1.0 P GHS SDS Page 6 of 6