Acute toxicity, dermal Acute toxicity, inhalation Skin corrosion/irritation Serious eye damage/eye irritation Sensitization, respiratory

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1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions PENNTROWEL LATEX UNDERLAYMENT FILLER (Fine and Regular) Manufacturer/Importer/Supplier/Distributor information Manufacturer Company Name Address After hours telephone number rmal work hours telephone number Website Emergency 24-hour telephone number Information on operation hours Workers (and your customers or users in the case of resale) should be informed of the potential presence of respirable dust and respirable crystalline silica as well as their potential hazards. Appropriate training in the proper use and handling of this material should be provided as required under applicable regulations. Ergon Armor 2829 Lakeland Drive Jackson, MS USA CHEMTREC: rth America International :00 a.m. to 5:00 p.m. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards t classified. Acute toxicity, oral Acute toxicity, dermal Acute toxicity, inhalation Skin corrosion/irritation Serious eye damage/eye irritation Sensitization, respiratory Sensitization, skin Carcinogenicity Specific target organ toxicity, repeated exposure t classified. t classified. Category 4 Category 4 Category 3 B A Label elements Signal word Hazard statement Prevention Danger Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes damage to organs through prolonged or repeated exposure by inhalation. May cause an allergic skin reaction. May cause cancer. Keep out of reach of children. Read label before use. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Do not breathe dust/fume. Use only outdoors or in a well-ventilated area. In case of inadequate ventilation wear respiratory protection. 1 / 7

2 Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. Wash hands after handling. IF exposed or concerned: Get medical advice/attention. Store away from incompatible materials. Dispose of contents/container in accordance with local/regional/national/international regulations. ne known. t applicable. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % QUARTZ PORTLAND CEMENT CALCIUM CARBONATE *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. Call a physician if symptoms develop or persist. Get medical attention if irritation develops and persists. Before washing use a dry brush to remove dust from skin. Wash off immediately with plenty of water. Take off contaminated clothing and wash before reuse. For minor skin contact, avoid spreading material on unaffected skin. Remove and isolate contaminated clothing and shoes. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Continue rinsing. Get medical attention if symptoms occur. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 2 / 7

3 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Keep formation of airborne dusts to a minimum. Provide appropriate exhaust ventilation at places where dust is formed. Do not breathe dust. Avoid prolonged exposure. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) CALCIUM CARBONATE (CAS ) US. OSHA Table Z-3 (29 CFR ) PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. US. ACGIH Threshold Limit s TWA 50 mppcf TWA 0.3 mg/m3 Total dust. 0.1 mg/m3 Respirable. 2.4 mppcf Respirable. US. NIOSH: Pocket Guide to Chemical Hazards CALCIUM CARBONATE (CAS ) Biological limit values Exposure guidelines Appropriate engineering controls TWA 1 mg/m3 Respirable fraction. TWA mg/m3 Respirable fraction. TWA 5 mg/m3 Respirable. 10 mg/m3 Total TWA 5 mg/m3 Respirable. 10 mg/m3 Total TWA 0.05 mg/m3 Respirable dust. biological exposure limits noted for the ingredient(s). Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica should be monitored and controlled. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Skin protection Other Respiratory protection Thermal hazards General hygiene considerations Wear protective gloves. 9. Physical and chemical properties Appearance Wear appropriate chemical resistant clothing. Use a particulate filter respirator for particulate concentrations exceeding the Occupational Exposure Limit. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Powder. 3 / 7

4 Odor Physical state Color Odor threshold Solid. Solid. Light grey ph 9-13 Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) 3110 F (1710 C) estimated 4046 F (2230 C) estimated Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Contact with incompatible materials. Powerful oxidizers. Chlorine. hazardous decomposition products are known. Expected to be a low ingestion hazard. Prolonged inhalation may be harmful. adverse effects due to skin contact are expected. 4 / 7

5 Species Acute Oral LD50 Mouse Rat Test Results 6450 mg/kg 6450 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Prolonged skin contact may cause temporary irritation. This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica inhaled from occupational sources can cause lung cancer in humans. However in making the overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) In June 2003, SCOEL (the EU Scientific Committee on Occupational Exposure Limits) concluded that the main effect in humans of the inhalation of respirable crystalline silica dust is silicosis. "There is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis (and, apparently, not in employees without silicosis exposed to silica dust in quarries and in the ceramic industry). Therefore, preventing the onset of silicosis will also reduce the cancer risk..." (SCOEL SUM Doc 94-final, June 2003) According to the current state of the art, worker protection against silicosis can be consistently assured by respecting the existing regulatory occupational exposure limits. Occupational exposure to respirable dust and respirable crystalline silica should be monitored and controlled. Risk of cancer cannot be excluded with prolonged exposure. IARC Monographs. Overall Evaluation of Carcinogenicity 1 Carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens Known To Be Human Carcinogen. US. OSHA Specifically Regulated Substances (29 CFR ) t listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity This product is not expected to cause reproductive or developmental effects. t classified. t classified. Aquatic Fish Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. LC50 Species * Estimates for product may be based on additional component data not shown. Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Western mosquitofish (Gambusia affinis) data is available on the degradability of this product. data available. data available. Test Results > mg/l, 96 hours other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 5 / 7

6 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. t applicable. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) t listed. US. OSHA Specifically Regulated Substances (29 CFR ) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances 6 / 7

7 US. Rhode Island RTK US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/carcinogenic substance Listed: October 1, 1988 International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. 7 / 7

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