Zoecon Altosid XR Extended Residual Briquets. Relevant identified uses of the substance or mixture and uses advised against

Transcription

1 Zoecon Altosid XR Extended Residual Briquets Safety Data Sheet Section 1: Identification Product identifier Product Name Zoecon Altosid XR Extended Residual Briquets Synonyms ; ; ; ; ; EPA Reg. No.: ; ProLink XR Extended Release Briquets; Zoecon RF 292 Briquet Product Description White to gray briquet. Relevant identified uses of the substance or mixture and uses advised against Recommended use Insect growth regulator. Restrictions on use Avoid contact with eyes, skin or clothing. Keep out of reach of children. Details of the supplier of the safety data sheet Manufacturer Wellmark International 1501 E. Woodfield Road, Suite 200 West Schaumburg, IL United States Emergency telephone number Manufacturer CHEMTREC Manufacturer CHEMTREC Outside North America Collect Calls Accepted Manufacturer Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR HCS Classification of the substance or mixture Label elements Carcinogenicity 1A Eye Mild Irritation 2B DANGER Hazard statements May cause cancer. Causes eye irritation Page 1 of 8

2 Precautionary statements Prevention Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. Storage/Disposal Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store locked up. Supplemental information The finished product is not considered carcinogenic because of the product s physical form. The Hazard Statement May Cause Cancer is presented because a component of this product contains a naturally occurring trace amount of crystalline silica (quartz) which is classified as carcinogenic to humans if inhaled. Respiratory exposure to silica dust from the finished product is not expected to occur under normal conditions of use due to the manner in which the constituents are bound. The crystalline silica in the finished product is unlikely to pose personal exposure via inhalation. Other hazards Under United States Regulations (29 CFR Hazard Communication Standard), this product is considered hazardous. Section 3 Composition/Information on Ingredients Substances Mixtures Material does not meet the criteria of a substance. Composition Chemical Name Identifiers % (s) Methoprene CAS: % Plaster of paris CAS: > 80.88% Silica, crystalline quartz CAS: < 0.82% Other ingredients NDA < 17.02% Section 4: First Aid Measures Description of first aid measures Inhalation Skin Eye IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Page 2 of 8

3 Ingestion IF SWALLOWED: call a poison center or doctor if you feel unwell. Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center. Most important symptoms and effects, both acute and delayed Causes eye irritation, may cause cancer. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically and supportively. Section 5: Fire Fighting Measures Extinguishing media Suitable Extinguishing Media SMALL FIRES: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Unsuitable Extinguishing Media Firefighting Procedures Avoid heavy hose streams. Keep unauthorized personnel away. LARGE FIRES: Dike fire control water for later disposal; do not scatter the material. Stay upwind. Ventilate closed spaces before entering. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters Non combustible, substance itself does not burn but may decompose upon heating to produce toxic fumes which may include carbon oxides, smoke fumes, unburned hydrocarbons and terpenes. Wear positive pressure self contained breathing apparatus (SCBA). Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Emergency Procedures Environmental precautions Avoid contact with skin, eyes, and clothing. Use appropriate Personal Protective Equipment (PPE). Ventilate enclosed areas. Do not walk through spilled material. Avoid dust formation and breathing dust. Stay upwind. Ventilate closed spaces before entering. Avoid release into the environment. Do not allow runoff into water, storm drains or drainage ditches. Contain and prevent from release into any waterway, sewer or drain. Methods and material for containment and cleaning up Containment/Clean up Measures Section 7 Handling and Storage Precautions for safe handling Handling Use appropriate Personal Protective Equipment (PPE) Sweep up material and place in suitable container for disposal. Wash hands thoroughly with soap and water after handling. Read label before use. Avoid contact with skin or eyes. Avoid breathing dust. Conditions for safe storage, including any incompatibilities Storage Store in a well ventilated place. Keep container tightly closed. Store locked up. Store in cool, dry area, inaccessible to children. Store only in original container. Page 3 of 8

4 Section 8 Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines Silica, crystalline quartz ( ) Plaster of paris ( ) Exposure Limits/Guidelines Result ACGIH NIOSH OSHA TWAs TWAs mg/m3 TWA (respirable fraction) Not established 0.05 mg/m3 TWA (respirable dust) Not established 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Exposure Limits Supplemental OSHA Silica, crystalline quartz ( ): Mineral Dusts: ((30)/(%SiO2 + 2) mg/m3 TWA, total dust; (250)/(%SiO2 + 5) mppcf TWA, respirable fraction; (10)/(%SiO2 + 2) mg/m3 TWA, respirable fraction) Exposure controls Engineering Measures/Controls Personal Protective Equipment Pictograms Use adequate ventilation to remove vapors (fumes, dust etc) Respiratory Eye/Face Hands Skin/Body General Industrial Hygiene Considerations Environmental Exposure Controls If prolonged exposure is anticipated, it is recommended for handlers to wear an approved MSHA/NIOSH dust mask N 95. Wear safety glasses. Wear appropriate gloves. If prolonged exposure is anticipated, it is recommended for handlers to wear appropriate clothing to prevent skin contact. Avoid contact with skin, eyes or clothing. Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Section 9 Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Solid Appearance/Description White to gray briquet. Color White to gray. Odor Slight hydrocarbon. Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available Decomposition Temperature No data available ph Not relevant Specific Gravity/Relative Density 1.04 g/cc (64.9 lb/ft3) Viscosity Not relevant Water Solubility No data available Page 4 of 8

5 Volatility Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available Flammability Flash Point Not relevant UEL No data available LEL No data available Autoignition No data available Flammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity Chemical stability Stable Possibility of hazardous reactions Conditions to avoid Incompatible materials No dangerous reaction known under conditions of normal use. Hazardous polymerization will not occur. Hazardous decomposition products Non combustible, substance itself does not burn but may decompose upon heating to produce toxic fumes which may include carbon oxides, smoke, unburned hydrocarbons and terpenes. Section 11 Toxicological Information Information on toxicological effects CAS Zoecon Altosid XR Extended Residual Briquets NDA Acute Toxicity: Ingestion/Oral Rat LD50 >5100 mg/kg; Skin Rabbit LD50 >2100 mg/kg; Irritation: Eye Rabbit Mild irritation; Skin Rabbit Mild irritation GHS Properties Acute toxicity Aspiration Hazard Carcinogenicity Germ Cell Mutagenicity Skin corrosion/irritation Skin sensitization Classification Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral Classification criteria not met Classification criteria not met Carcinogenicity 1A Not classified data lacking Classification criteria not met Classification criteria not met Page 5 of 8

6 STOT RE STOT SE Toxicity for Reproduction Respiratory sensitization Serious eye damage/irritation Route(s) of entry/exposure Potential Health Effects Inhalation Acute (Immediate) Chronic (Delayed) Skin Acute (Immediate) Chronic (Delayed) Eye Acute (Immediate) Chronic (Delayed) Ingestion Acute (Immediate) Chronic (Delayed) Carcinogenic Effects Classification criteria not met Classification criteria not met Classification criteria not met Classification criteria not met Eye Mild Irritation 2B Inhalation, Ingestion, Eyes, and Skin Under normal conditions of use, no health effects are expected. Exposure to respirable crystalline silica is not expected during normal use of this product. However, prolonged overexposure to respirable crystalline silica may cause lung disease (silicosis). May cause mild irritation. Causes mild eye irritation. Under normal conditions of use, no health effects are expected. Exposure to respirable crystalline silica dust from the finished product is not expected to occur due to the manner in which the constituents are bound, thus the finished product is not considered carcinogenic under conditions of normal use. Section 12 Ecological Information Toxicity Component CAS Data (s) Methoprene (2.1%) Persistence and degradability Bioaccumulative potential Mobility in Soil Other adverse effects Crustacea: NOEC Crustacea Mysid shrimp mg/l [Chronic]; 96 Hour(s) LC50 Crustacea Mysid shrimp 0.11 mg/l [Acute]; 48 Hour(s) LC50 Crustacea Daphnia magna 0.36 mg/l [Acute]; Fish: 96 Hour(s) LC50 Fish Rainbow Trout 0.76 mg/l [Acute]; 96 Hour(s) LC50 Fish Blue Gill >0.37 mg/l [Acute]; NOEC Fish Fathead minnow mg/l [Chronic] Section 13 Disposal Considerations Page 6 of 8

7 Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT N/A Not regulated N/A N/A N/A IMO/IMDG N/A Not regulated N/A N/A N/A IATA/ICAO N/A Not regulated N/A N/A N/A Special precautions for user None specified. Transport in bulk according Not relevant. to Annex II of MARPOL 73/78 and the IBC Code Other information IMO/IMDG No data available Key to abbreviations = N/A = Not applicable. IATA/ICAO No data available Section 15 Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute, Chronic FIFRA Pesticide Labeling This material is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of nonpesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Precautionary Statements Keep out of reach of children. Hazards to Humans and Domestic Animals Causes moderate eye irritation. Harmful if absorbed through skin. Avoid contact with eyes, skin, or clothing. Wash thoroughly with soap and water after handling. First Aid Call a poison control center or doctor for treatment advice. If in eyes Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Environmental Hazards Do not contaminate water when disposing of unused product. Inventory Component CAS TSCA (s) Methoprene No Plaster of paris No Page 7 of 8

8 Silica, crystalline quartz Yes Section 16 Other Information Last Revision Date Preparation Date Disclaimer/Statement of Liability 17/July/ /July/2015 The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Page 8 of 8