Safety Data Sheet according to Federal Register / Vol. 77, No. 58/ Monday, March 26, 2012/ Rules and Regulations Revision date: 03/29/2013

Transcription

1 03:27:29 p.m /5 SUNSTAR Crayola1M Squeeze-A-Color Children's Toothpaste according to Federal Register / Vol. 77, No. 58/ Monday, March 26, 2012/ Rules and Regulations Revision date: 03/29/2013 SECTION 1; Identification of the substance/mixture and of the company/undertaking 1.1. Produtt Identifier Product form: Mixture Product name: Crayola Squeeze-A-ColorT'M Children's Toothpaste Product code: 4050, 4052 (42 grams per tube; 3 tubes per package) Synonyms: Children's toothpaste, Crayola Mini Tubes 1.2. Intended Use Of The Product Use of the substance/mixture: Children's toothpaste. ThiS mixture is a product regulated by the FDA. Within the meaning of the OSHA Hazard Communication Standard [29 CFR ): this mixture is not considered a hazard when used in a manner which is consistent with the labeled directions Name, Address, And Telephone Of The Responsible Party Sunstar Americas, Inc West Foster Avenue Chicago, IL Emergency telephone number Emergency number : 1 8OQ SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHs.-US classification Not classified 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards No additional information available 2A. Unknown acute toxicity (GHS US) SECTION 3; Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixture Name Product Identifier GH5-US classification D-Glucitol (CAS No.) " Not dassifie d Xylitol (CAS No.) Comb. Dust Sodiu m fluoride (CAS No.) Acute Tox. 3 (Orall, H301 Acute Tox. 2 (Dermal), H310 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Version: Description of first aid measures First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation: When symptoms occur: go into open air and ventilate suspected area. First-aid measures after skin contact: Rinse with plenty of water. 03,!29/20U EN (English) 1/5

2 03:27:46 p.m /5 according to F~",I Register IVaI. n, No. 581 Monday, March 26, Rules and Regulations First-aid measures after eyii contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid measures after Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after Inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of normal use. symptoms/injuries after skin contact: May cause mild sldn irritation. Symptoms/Injuries after eye contact: May cause mild eye irritation. Symptoms/injuries after ingestion: Diarrhea. Gastrointestinal irritation Indication of any Immediate medical attention and special treatment needed If you feel unwell, seek medical advice (show the label where possible). SECTION 5: Firefighting measures 5.1. ExtInguishing media Suitable extinguishing media: Foam. Dry powder. carbon dioxide. Water sprav. Sand. Use extinguishing media appropriate for surrounding fire. Unsuitable extinguishing media: Do not use a heavy water stream. S.2. Special hazards arising from the substance or mixture Fire hazard: Not considered flam mabie but may burn at high temperatures. Explosion hazard: None known Advice for firefighters Firefightinslnstruttions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. 00 not allow run-off from fire fighting to enter drains or water courses. Protection 00 not enter fire area without 6.1. Personal precautions, protective equipment and emersency procedures General measures: Spilled material may present a slipping hazard For non-emergency personnel Protective equipment: Use appropriate personal protection equipment (PPE) For emergency responders Protective equipment: Equip cleanup crew with proper protection. Emergency procedures: Ventilate area Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment: Soak up diluted material with inert solids or flush with large amount of water. Methods for cleaning up: Clear up spills immediately and dispose of waste safely Reference to other sections See Heading 8, exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Hygiene measures: Handle in accordance with good industrial hygiene and safety procedures ConditIons for safe storage, induding any incompatibilities Storage conditions: Keep only in the original container in a cool, well ventilated place away from; incompatible materials. Keep container closed when not in use. Incompatible products: Strong bases. Strong acids. Strong oxidizers Specific end use(s) Children's toothpaste. SECTION 8: Exposure controls/personal protection S.l. Control parameters No Occupational Exposure Limits have been established for this product or its chemical components. 03/29/2013 EN (English) 2/5

3 03:28:07 p.m /5 according to Federal Register I Vol. 77. NO. 58' Mondav. March / RuleSilnd Regulations 8.2. Exposure controls Appropriate engineering controls Consumer exposure controls Other information SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Gel Appearance Odour Odour threshold ph 6-8 Relative evaporation rate (butylacetate=l) Melting point Freezing point Boiling point Flash Point Auto-ignition temperature Decomposition Temperature Flammability (solid. gasl Vapour pressure Relative vapour density at 20 DC Relative density Solubility Log Pow LogKow Viscosity. kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. : Not generally required. The use of personal protective equipment may be necessary as conditions warrant. : When using, do not eat, drink or smoke. Clear, colored gel Melon (red). apple (green). or blueberry (blue) Water: Complete Not applicable 9.2. other Information No additional information available SECTION 10: Stability and reactivity Reactivity No additional information available Chemical stability Stable under normal conditions Possibility of hazardous reactions Hazardous pofymerization will not occur Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. Strong oxidizers. to.6. Ha%ardous decomposition products carbon oxides (CO, C02). Silicon oxides. HydrofluoriC Acid. Phosphates. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Not classified 03/29/2013 EN (English) 315

4 03:28:23 p.m /5 according to Federal Register / Vol. n. No. 58/ Mondav. March / Rules and Regulations LDSO oral rat ld50 dermal rat LD500ralm ID-Glucltol ( ) ldso oral rat 152 mg/kg! 17Smg/kg I mg/kg I mg/kg Skin corrosion/irritation: Not classified ph: 6 8 Serious eye damage/irritation: Not classified ph: 6-8 Respiratory or skin sensitisation: Not classified Germ cell mutagenicity: Not classified Carcinogenicity: Not classified IARCgroup 13 NationalToxiclty Program (NTP) Status 11 Reproductive toxicity: Not classified Specific till'let organ toxicity (single exposure): Not classified Specific target organ toxicity (repeated exposure): Not classified Aspiration hazard: Not classified Symptoms/injuries after Inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Symptoms/injuries after skin contact: May cause mild skin irritation. Symptoms/injuries after eye contact: May cause mild eye irritation. after ~.I:!Stlflln: Toxicity LCSO fishes 1 > 530 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus) EC50 Daphnia mg/i (Exposure time: 48 h - Species: Daphnia magna) EC50 other aquatic organisms mg/i (Exposure time: 96 h - Species: Pseudokirchneriella subcapitata) LCSOflsh2 830 mgjl {Exposure time: 96 h - Species: lepomis macrochirus [semi-staticll. EC50 Daphnia 2 98 mgll (Exposure time; 48 h - Species: Daphnia magna [Static]) ECSO other aquatic organisms mg/i (Exposure time: 12 h Species: Desmodesmus subspicatus (static]). Persistence and de radability Crayola Squeeze-A-Color Children'S Toothpaste Persistence and degradability Not established Bloaccumulative potential trayola S ueeze-a-color Children's Toothpaste BioacQlmulatlve potential Not established Mobility in soli No additional information available Other adverse effects Other Information : AVOid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations. Ecology - waste materials: Avoid release to the environment. 03/29/2013 EN lfngllsh) 4/5

5 03:28:41 p.m /5 according to Federal Register / Vol. 77. No. 58/ Monday, March 26, 2012/ Rules and Regulation$ SECTION 14: Transport information In accordance with ICAO/IATA/DOT/TOG UN number Not regulated for transport UN proper shipping name Not regulated for transport Additional information Not regulated for transport OVerland transport Not regulated for transport Transport by sea Not regulated for transport Air transport Not regulated for transport SECTION 15: Regulatory information US Federal regulations Sodium fluorfde ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Xylitol ( ) listed on the United States TSCA (Toxic Substances Control Act) inventory D-Glucltol (so..70-4) Listed on the United States TSCA (Toxic Substances Control AC!) inventory US State regulations u.s. -Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance Ust U.S. Pennsylvania RTK (Right to Know)- Environmental Hazard List U.S. - Pennsylvania RTK (Right to Know) list SECTION 16: Other information Data sourc:es This document has been prepared in accordance with the SOS requirements of the OSHA Hazard Communication Standard 29 CFR GHS Full Text Phrases; Acute Tax. 2 (Dermal) Acute toxicity (dermal) category 2 Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral) category 3 Acute Tox. 2 (Dermal) Acute toxicity (dermal) Category 2 Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 Comb. Oust Combustible Oust Eye Irrlt. 2A Serious eye damage/eye irritation Category 2A Skin I rrit. 2 skin corrosion/irritation category 2 H301 Toxic if swallowed, H310 Fatal in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation NFPA health haurd : 1 Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure 0 conditions, and are not reactive with water. HMIS III Rating Health : 0 Minimal Hazard - No significant risk to health Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard This information is based on our current knowledge and is intended to describe the productfor the purposes ofhealth, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. SOS us (GHS HazCom} 03/29/2013 EN (EIIBII,h) 5/5