SYSTERM SAFETY DATA SHEET
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1 SAFETY DATA SHEET 1. Identification of the substance/preparation and of the company/undertaking Product name: Name and address of supplier: Classic Chemicals Sdn Bhd 19,Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam,Selangor Emergency telephone no.: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories Flammable liquid, category 3 Acute toxicity, category 4, dermal Acute toxicity, category 4, inhalation Skin irritation, category 2 Hazard statements H226 H312 H332 H315 Signal word Danger Hazard Statements H226 Flammable liquid and vapour. H312+H332 Harmful in contact with skin or if inhaled. H315 Causes skin irritation. Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P309+P311 IF exposed or if you feel unwell: Call a POISON CENTER doctor/physician. Hazard symbols: Xn
2 SAFETY DATA SHEET Product name: R-phrases R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. S-phrases S25 Avoid contact with eyes. 3. Composition/information on ingredients Product name: Dimethylbenzene CAS-No.: Molar mass: Molecular formula: C 8 H 10 EC No.: Index no.: Other means of identification: Dimethylbenzene 4. First aid measures After inhalation: Remove from exposure, rest and keep warm. In severe cases obtain medical attention. After skin contact: Wash off thoroughly with soap and water. Remove contaminated clothing and wash before re-use. In severe cases, obtain medical attention. After eye contact: Irrigate thoroughly with water for at lest 10 minutes. If discomfort persists, obtain medical attention. After ingestion: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain medical attention. 5. Fire-fighting measures Suitable extinguishing media: Foam, drypowder, carbon dioxide or vaporising liquids.. Special risks: Flammable. Vapour/air mixture explosive. 6. Accidental release measures Shut off all sources of ignition. Inform others to keep at a safe distance. Wear appropriate protective clothing. Absorb on an inert absorbent, transfer to a suitable container and arrange removal by disposal company. Wash site of spillage thoroughly with water and detergent. For large spillages liquids should be contained with sand or earth and both liquids and solids transferred to salvage containers. Any residues should be treated as for small spillages.
3 SAFETY DATA SHEET Product name: 7. Handling and storage Handling: All electrical equipment must be flameproofed. Take precautions against static discharge. Do not breathe vapour. Immediately change contaminated clothing. Do not empty into drains. Storage: Store at room temperature (+15 o C to +25 o C recommended). Keep well closed and protected from direct sunlight and moisture. 8. Exposure controls/personal protection As appropriate to the situation and the quantity handled. Engineering methods to control or prevent exposure are preferred. Methods could include process enclosure or mechanical ventilation. Respiratory protection: Ventilation: Eye protection: Glove protection: Other Precautions: Self-contained breathing apparatus Fume cupboard, flameproof Goggles or face-shield Viton, Polyvinyl alcohol or PE/EVAL (Silver Shield) Plastic apron, sleeves, boots if handling large quantities 9. Physical and chemical properties Form: liquid Colour: colourless Odour: characteristic ph value not available Melting temperature -95 o C Boiling temperature 140 o C Ignition temperature 465 o C Flash point 25 o C Explosion limits lower 1.1 % upper 7.0 % Vapour pressure (21 o C) 6.7 mmhg Vapour density 3.66 Density (20 o C) 0.86 g/ml Solubility in water (20 o C) Immiscible or insoluble log P(o/w): Stability and reactivity Stable. Unsuitable working materials: light metals, rubber, various plastics. Substances to be avoided strong oxidizing agents, conc. sulfuric acid, nitric acid, uranium hexafluoride, sulfur. The possibility of reaction with other substances cannot be excluded.
4 SAFETY DATA SHEET Product name: 11. Toxicological information Acute toxicity: Inhalation may lead to the formation of oedemas in the respiratory tract. After absorption of toxic quantities: Drowziness, dizziness, euphoria, excitation, spasms, in certain circumstances narcosis. Effect potentiated by: ethanol. Possible effect on: liver, urinary tract. After skin contact: Irritations. Danger of skin absorption. Degreasing effect on the skin, possibly followed by secondary inflammation. After long-term exposure to the chemical: dermatitis. After eye contact: Severe irritation. Risk of blindness! Subacute to chronic toxicity: After long term exposure to the chemical: Results from animal experiments indicate possible teratogenic effects. Further data LD 50 : ( (mixed isomers) (oral, rat): 4300 mg/kg LC 50 : () (mixed isomers) (inhalation, rat): 22 mg/l Skin irritation test (rabbit): ( (mixed isomers) (500 mg/24h): moderate irritant effect Eye irritation test (rabbit): ( (mixed isomers) (5 mg/24h): severe irritant effect No evidence of carcinogenic properties. Evidence of teratogenic effects. 12. Ecological information Do not allow to enter drinking water supplies, waste water, or soil! Risk of formation of explosive vapours above water surface. 13. Disposal considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty containers thoroughly before returning for recycling. 14. Transport information Transport over land ADF-/RID ADR/RID class: 3 Name of material: XYLENES Sea transport IMDG IMDG class: 3 UN-No.: 1307 Packaging group: III Correct technical name: XYLENES Air transport ICAO-TI and IATA-DGR ICAO/IATA class: 3 UN/ID-No.: 1307 Packaging group: III Correct technical name: XYLENES
5 SAFETY DATA SHEET Product name: 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Water hazard class (WGK) 2 Chemical Safety Assessment No data available 16. Other information Relevant R-, H- and EUH-phrases (Number and full text) R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. H226 Flammable liquid and vapour. H312+H332 Harmful in contact with skin or if inhaled. H315 Causes skin irritation. Revision Date: 01 Jan 2016 The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product.
6 LEMBARAN DATA KESELAMATAN 1. Pengenalpastian bahan / sediaan dan syarikat / aku janji Nama produk: Nama dan alamat pembekal: Classic Chemcials Sdn Bhd 19,Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam,Selagor telefon kecemasan no.: Pengenalan Bahaya Pengelasan bahan atau campuran Pengelasan menurut Peraturan (EC) No 1272/2008 [CLP] kelas bahaya dan kategori bahaya cecair mudah terbakar, kategori 3 Ketoksikan akut, kategori 4, kulit Ketoksikan akut, kategori 4, penyedutan Kerengsaan kulit, kategori 2 penyataan bahaya H226 H312 H332 H315 Perkataan isyarat Penyata bahaya H226 H312 + H332 H315 pernyataan langkah P210 P243 P280 P302 + P352 P304 + P340 P309 + P311 Bahaya cecair dan wap mudah terbakar. Memudaratkan jika bersentuhan dengan kulit atau jika tersedut. Boleh menyebabkan kerengsaan kulit. Jauhkan daripada haba / percikan api / nyalaan terbuka / permukaan panas. Dilarang merokok. Ambil langkah-langkah keselamatan terhadap pelepasan statik. Pakai sarung tangan pelindung / pakaian pelindung / perlindungan mata / muka. JIKA TERKENA KULIT: Basuh dengan sabun dan air. JIKA TERSEDUT: Pindahkan mangsa ke tempat udara segar dan biarkan berehat dalam kedudukan yang bernafas dengan selesa. JIKA terdedah atau jika anda merasa kurang sihat: Hubungi PUSAT RACUN doktor / pakar perubatan. Simbol Bahaya: Xn
7 LEMBARAN DATA KESELAMATAN Nama produk: Frasa-R R10 R20 / 21 R38 S Frasa S25 Mudah terbakar. Memudaratkan melalui penyedutan dan jika bersentuhan dengan kulit. Merengsa kepada kulit. Elakkan sentuhan dengan mata. 3. Komposisi / maklumat mengenai bahan-bahan Nama produk: Dimethylbenzene CAS-No.: jisim molar: Formula molekul: C 8 H 10 EC No.: Indeks no.: cara pengenalan lain: Dimethylbenzene 4. Langkah-langkah pertolongan cemas Jika tersedut: Buang dari pendedahan, rehat dan menyimpan panas. Dalam kes-kes yang teruk dapatkan rawatan perubatan. Jika terkena kulit: Basuh sehingga bersih dengan sabun dan air. Tanggalkan pakaian yang tercemar dan basuh sebelum digunakan semula. Dalam kes-kes yang teruk, dapatkan rawatan perubatan. Jika terkena mata: Mengairi bersih dengan air sekurang supaya 10 minit. Jika ketidakselesaan berterusan, dapatkan rawatan perubatan. Selepas pengambilan: Basuh mulut sehingga bersih dengan air dan beri banyak air untuk minum. Dapatkan rawatan perubatan. 5. Langkah memadam kebakaran pemadam media yang sesuai: Busa, drypowder, karbon dioksida atau vaporising cecair.. risiko khas: Mudah terbakar. Wap / campuran udara letupan. 6. Langkah-langkah pengawalan pelepasan tidak sengaja Tutup semua punca pencucuhan. Maklumkan kepada orang lain untuk berada di jarak yang selamat. Pakai pakaian perlindungan yang sesuai. Menyerap pada penyerap lengai, memindahkan ke dalam bekas yang sesuai dan menguruskan pembuangan oleh syarikat pelupusan. Basuh tapak tumpahan sehingga bersih dengan air dan detergen. Untuk tumpahan besar cecair harus lengkap dengan pasir atau tanah dan kedua-dua cecair dan pepejal dipindahkan untuk menyelamatkan bekas. Apa-apa sisa harus dianggap sebagai untuk tumpahan kecil.
8 LEMBARAN DATA KESELAMATAN Nama produk: 7. Pengendalian dan penyimpanan pengendalian: Semua peralatan elektrik mesti flameproofed. Ambil langkah berjaga-jaga terhadap nyahcas statik. Jangan menyedut wap. Segera menukar pakaian yang tercemar. Jangan buang ke dalam longkang. penyimpanan: Simpan pada suhu bilik (+ 15 o C ke + 25 o C disyorkan). Pastikan juga ditutup dan dilindungi daripada cahaya matahari langsung dan kelembapan. 8. Kawalan pendedahan / perlindungan diri Sebagaimana yang sesuai dengan keadaan dan kuantiti yang dikendalikan. Kejuruteraan kaedah untuk mengawal atau mengelakkan pendedahan diutamakan. Kaedah boleh termasuk proses tertutup atau pengudaraan mekanikal. Perlindungan Pernafasan: alat pernafasan serba lengkap Alih udara: Fume almari, flameproof Perlindungan mata: Goggles atau perisai muka Sarung tangan perlindungan: Viton, Polyvinyl alkohol atau PE / EVAL (Silver Shield) Langkah berjaga-jaga lain: apron plastik, lengan, but - jika pengendalian kuantiti yang besar 9. Sifat-sifat fizikal dan kimia Bentuk: cecair Warna: tidak berwarna Bau: ciri nilai ph tidak tersedia suhu lebur -95 o C Takat suhu 140 o C Suhu pencucuhan 465 o C Takat kilat 25 o C Had letupan yang lebih rendah 1.1 % atas 7.0 % Tekanan wap (21 o C) 6.7 mmhg Ketumpatan wap 3.66 Ketumpatan (20 o C) 0.86 g / ml Keterlarutan dalam Air (20 o C) Tidak boleh larut atau tidak larut log P (o / w): Kestabilan dan Kereaktifan Stabil. bahan-bahan yang tidak sesuai kerja: logam, getah, pelbagai plastik. Bahan yang perlu dielakkan agen pengoksidaan yang kuat, conc. asid sulfurik, asid nitrik, uranium hexafluoride, sulfur. Kemungkinan tindak balas dengan bahan-bahan lain tidak boleh dikecualikan.
9 LEMBARAN DATA KESELAMATAN Nama produk: 11. Maklumat toksikologi Ketoksikan akut: Penyedutan boleh membawa kepada pembentukan oedemas dalam saluran pernafasan. Selepas penyerapan kuantiti toksik: Drowziness, pening, keghairahan, pengujaan, kejang, dalam keadaan tertentu narkosis. Kesan potentiated oleh: etanol. kesan mungkin pada: hati, saluran kencing. Jika terkena kulit: kegatalan. Bahaya penyerapan kulit. Nyahgris kesan pada kulit, mungkin diikuti oleh keradangan menengah. Selepas pendedahan jangka panjang kepada kimia: dermatitis. Jika terkena mata: Kerengsaan teruk. Risiko buta! Subakut ketoksikan kronik: Selepas pendedahan jangka panjang kepada kimia: Keputusan daripada eksperimen haiwan menunjukkan mungkin ada kesan teratogenik. maklumat lanjut LD 50 : ( (isomer bercampur) (lisan, tikus): 4300 mg / kg LC 50 : () (isomer bercampur) (penyedutan, tikus): 22 mg / l ujian kerengsaan kulit (arnab): ( (isomer bercampur) (500 mg / 24h): Kesan kerengsaan sederhana ujian kerengsaan mata (arnab): ( (isomer bercampur) (5 mg / 24h): Kesan kerengsaan teruk Tiada bukti sifat karsinogen. Bukti kesan teratogenik. 12. Maklumat ekologi Jangan biarkan ia memasuki bekalan air minuman, air sisa, atau tanah! Risiko pembentukan wap bahan letupan di atas permukaan air. 13. Maklumat pelupusan Sisa kimia biasanya diklasifikasikan sebagai sisa khas, dan oleh itu adalah dilindungi oleh peraturanperaturan yang berbeza mengikut lokasi. Hubungi pihak berkuasa pelupusan sisa tempatan anda untuk mendapatkan nasihat, atau berpindah kepada syarikat pelupusan kimia. Berkumur bekas kosong teliti sebelum kembali untuk dikitar semula. 14. Maklumat pengangkutan Pengangkutan ke atas jalan ADR / RID ADR / RID: 3 Namakan bahan: XYLENES Pengangkutan laut IMDG kelas IMDG: 3 UN.:1307 Kumpulan Pembungkusan: III Betul nama teknikal: XYLENES Pengangkutan udara ICAO-TI dan IATA-DGR kelas ICAO / IATA: 3 UN / ID-No.: 1307 Kumpulan pembungkusan: III Betul nama teknikal: XYLENES
10 LEMBARAN DATA KESELAMATAN Nama produk: 15. Maklumat pengawalan Keselamatan, kesihatan dan peraturan alam sekitar / undang-undang khusus untuk bahan atau campuran Bahaya air kelas (WGK) 2 Penilaian Keselamatan Kimia Data tidak terdapat 16. Maklumat lain R- berkaitan, H- dan EUH-frasa (Bilangan dan teks penuh) R10 Mudah terbakar. R20 / 21 Memudaratkan melalui penyedutan dan jika bersentuhan dengan kulit. R38 Merengsa kepada kulit. H226 H312 + H332 H315 cecair dan wap mudah terbakar. Memudaratkan jika bersentuhan dengan kulit atau jika tersedut. Boleh menyebabkan kerengsaan kulit. Tarikh Semakan: 1 Januari 2016 Maklumat yang terkandung dalam dokumen ini adalah berdasarkan pada keadaan pengetahuan semasa kami. Ia menyifatkan produk dengan mengambil kira langkah-langkah keselamatan yang sesuai. Ia tidak mewakili jaminan sifat-sifat produk.
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