SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 Safety data sheet Page: 1/15 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Efka PX Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: dispersing agent 1.3. Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Regional Business Unit Dispersions and Resins Europe Telephone: address: 1.4. Emergency telephone number International emergency number: Telephone: SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Flam. Liq. 3 STOT SE 3 (Vapours may cause drowsiness and dizziness.)

2 Page: 2/15 H226, H336 For the classifications not written out in full in this section the full text can be found in section Label elements Globally Harmonized System, EU (GHS) Pictogram: Signal Word: Warning Hazard Statement: H226 H336 Flammable liquid and vapour. May cause drowsiness or dizziness. Precautionary Statements (Prevention): P271 Use only outdoors or in a well-ventilated area. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves and eye/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P243 Take action to prevent static discharges. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P240 Ground and bond container and receiving equipment. P242 Use only non-sparking tools. Precautionary Statements (Response): P312 Call a POISON CENTER or doctor/physician if you feel unwell. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378 In case of fire: Use foam or dry powder for extinction. Precautionary Statements (Storage): P233 Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point.

3 Page: 3/15 According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: 2-methoxy-1-methylethyl acetate 2.3. Other hazards According to Regulation (EC) No 1272/2008 [CLP] No specific dangers known, if the regulations/notes for storage and handling are considered. SECTION 3: Composition/Information on Ingredients 3.1. Substances Not applicable 3.2. Mixtures Chemical nature Preparation based on: polymer additive organic solvents Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 butan-1-ol Content (W/W): >= 0.2 % - < 0.3 % CAS Number: EC-Number: REACH registration number: Flam. Liq. 3 Acute Tox. 4 (oral) Skin Corr./Irrit. 2 Eye Dam./Irrit. 1 STOT SE 3 (drowsiness and dizziness) STOT SE 3 (irr. to respiratory syst.) H226, H318, H315, H302, H336, H335 2-methoxy-1-methylethyl acetate Content (W/W): >= 25 % - < 50 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Flam. Liq. 3 STOT SE 3 (drowsiness and dizziness) H226, H336 For the classifications not written out in full in this section, including the hazard classes and the hazard statements, the full text is listed in section 16.

4 Page: 4/15 SECTION 4: First-Aid Measures 4.1. Description of first aid measures Remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink ml of water. Do not induce vomiting unless told to by a poison control center or doctor Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., (Further) symptoms and / or effects are not known so far 4.3. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. SECTION 5: Fire-Fighting Measures 5.1. Extinguishing media Suitable extinguishing media: dry powder, foam 5.2. Special hazards arising from the substance or mixture harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

5 Page: 5/15 SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Breathing protection required Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. SECTION 7: Handling and Storage 7.1. Precautions for safe handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Sources of ignition should be kept well clear. Take precautionary measures against static discharges. If delivered in plastic packing, highest permissable emptying temperature is 5 Kelvin below the flash point Conditions for safe storage, including any incompatibilities Further information on storage conditions: Keep container tightly closed and in a cool place Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Components with occupational exposure limits : butan-1-ol : 2-methoxy-1-methylethyl acetate STEL value 550 mg/m3 ; 100 ppm (OEL (EU)) indicative

6 Page: 6/15 Skin Designation (OEL (EU)) The substance can be absorbed through the skin. TWA value 275 mg/m3 ; 50 ppm (OEL (EU)) indicative Components with PNEC : butan-1-ol freshwater: mg/l marine water: mg/l intermittent release: 2.25 mg/l STP: 2476 mg/l sediment (freshwater): mg/kg sediment (marine water): mg/kg soil: mg/kg : 2-methoxy-1-methylethyl acetate freshwater: mg/l marine water: mg/l intermittent release: 6.35 mg/l sediment (freshwater): 3.29 mg/kg sediment (marine water): mg/kg soil: 0.29 mg/kg STP: 100 mg/l Components with DNEL : butan-1-ol worker: Long-term exposure - systemic and local effects, Inhalation: 310 mg/m3 consumer: Long-term exposure- systemic effects, Inhalation: mg/m3 consumer: Long-term exposure- systemic effects, oral: mg/kg consumer: Long-term exposure - local effects, Inhalation: 155 mg/m3 consumer: Long-term exposure- systemic effects, dermal: mg/kg : 2-methoxy-1-methylethyl acetate worker: Long-term exposure- systemic effects, Inhalation: 275 mg/m3 worker: Long-term exposure- systemic effects, dermal: mg/kg consumer: Long-term exposure- systemic effects, oral: 1.67 mg/kg consumer: Long-term exposure- systemic effects, Inhalation: 33 mg/m3 consumer: Long-term exposure- systemic effects, dermal: 54.8 mg/kg 8.2. Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN Type A) Hand protection: Chemical resistant protective gloves (EN 374)

7 Page: 7/15 Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) butyl rubber (butyl) mm coating thickness nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Form: Colour: Odour: Odour threshold: liquid yellow to brownish characteristic Not determined due to potential health hazard by inhalation. ph value: not applicable Melting point: -66 C (1,013 hpa) Information applies to the solvent. Boiling point: 140 C Information applies to the solvent. Flash point: 44 C Information applies to the solvent. Evaporation rate: not determined Flammability: Flammable. Lower explosion limit: 1.5 %(V) (200 C, 1013 hpa) Information applies to the solvent. Upper explosion limit: 7 %(V) (200 C, 1013 hpa) Information applies to the solvent. Ignition temperature: 315 C Vapour pressure: 3.4 hpa (20 C) (closed cup) (Directive 92/69/EEC, A.11) (Directive 92/69/EEC, A.11)

8 Page: 8/15 Density: g/cm3 (20 C) g/cm3 (55 C) Relative density: approx. 1.0 (20 C) Relative vapour density (air): not determined Solubility in water: partly soluble Partitioning coefficient n-octanol/water (log Kow): not applicable for mixtures Self ignition: Based on its structural properties the product is not classified as selfigniting. Thermal decomposition: No decomposition if used as directed. Explosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: not fire-propagating 9.2. Other information Test type: Spontaneous selfignition at room-temperature. Self heating ability: Hygroscopy: Surface tension: Grain size distribution: Study scientifically not justified. Non-hygroscopic No data available. The substance / product is marketed or used in a non solid or granular form. SECTION 10: Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated Chemical stability The product is stable if stored and handled as prescribed/indicated Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions Conditions to avoid See MSDS section 7 - Handling and storage Incompatible materials Substances to avoid:

9 Page: 9/15 strong oxidizing agents, strong bases, strong acids Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. SECTION 11: Toxicological Information Information on toxicological effects Acute toxicity Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg LC50 rat (by inhalation): > 20 mg/l 4 h LD50 rat (dermal): > 5,000 mg/kg Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant Serious eye damage/irritation rabbit: non-irritant Respiratory/Skin sensitization Experimental/calculated data: other other: Non-sensitizing. Germ cell mutagenicity Assessment of mutagenicity:

10 Page: 10/15 No mutagenic effect was found in various tests with bacteria and mammalian cell culture. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Carcinogenicity Assessment of carcinogenicity: The whole of the information assessable provides no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a toxic effect on reproduction. Developmental toxicity Assessment of teratogenicity: Based on the ingredients, there is no suspicion of a teratogenic effect. Specific target organ toxicity (single exposure) Assessment of STOT single: Possible narcotic effects (drowsiness or dizziness). Remarks: The product has not been tested. The statement has been derived from the structure of the product. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The information available on the product provides no indication of toxicity on target organs after repeated exposure. Aspiration hazard No aspiration hazard expected. SECTION 12: Ecological Information Toxicity Toxicity to fish: LC50 (96 h) > 100 mg/l, Fish Aquatic invertebrates: LC50 (48 h) > 100 mg/l, daphnia

11 Page: 11/15 Aquatic plants: EC50 (72 h) > 100 mg/l, algae Microorganisms/Effect on activated sludge: EC50 (0.5 h) > 100 mg/l, bacteria Chronic toxicity to fish: No data available. Chronic toxicity to aquatic invertebrates: No data available. Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity Persistence and degradability Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria) Bioaccumulative potential Assessment bioaccumulation potential: Significant accumulation in organisms is not to be expected Mobility in soil Assessment transport between environmental compartments: Volatility: No data available Results of PBT and vpvb assessment According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria Other adverse effects

12 Page: 12/15 The product does not contain substances that are listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. SECTION 13: Disposal Considerations Waste treatment methods Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. SECTION 14: Transport Information Land transport ADR UN number UN1866 UN proper shipping name: RESIN SOLUTION Transport hazard class(es): 3 Packing group: III Environmental hazards: no Special precautions for Tunnel code: D/E user: RID UN number UN1866 UN proper shipping name: RESIN SOLUTION Transport hazard class(es): 3 Packing group: III Environmental hazards: no Special precautions for None known user: Inland waterway transport ADN

13 Page: 13/15 UN number UN1866 UN proper shipping name: RESIN SOLUTION Transport hazard class(es): 3 Packing group: III Environmental hazards: Special precautions for user: no None known Transport in inland waterway vessel Not evaluated Sea transport IMDG UN number: UN 1866 UN proper shipping name: RESIN SOLUTION Transport hazard class(es): 3 Packing group: III Environmental hazards: no Marine pollutant: NO Special precautions for None known user: Air transport IATA/ICAO UN number: UN 1866 UN proper shipping name: RESIN SOLUTION Transport hazard class(es): 3 Packing group: III Environmental hazards: No Mark as dangerous for the environment is needed Special precautions for None known user: UN number See corresponding entries for UN number for the respective regulations in the tables above UN proper shipping name See corresponding entries for UN proper shipping name for the respective regulations in the tables above Transport hazard class(es)

14 Page: 14/15 See corresponding entries for Transport hazard class(es) for the respective regulations in the tables above Packing group See corresponding entries for Packing group for the respective regulations in the tables above Environmental hazards See corresponding entries for Environmental hazards for the respective regulations in the tables above Special precautions for user See corresponding entries for Special precautions for user for the respective regulations in the tables above Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Shipment approved: Pollution name: Pollution category: Ship Type: Not evaluated Not evaluated Not evaluated Not evaluated Not evaluated SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture Prohibitions, Restrictions and Authorizations Annex XVII of Regulation (EC) No 1907/2006: Number on List: 3, 40 If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection Chemical Safety Assessment Advice on product handling can be found in sections 7 and 8 of this safety data sheet. SECTION 16: Other Information Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. Full text of the classifications, including the hazard classes and the hazard statements, if mentioned in section 2 or 3: Flam. Liq. Flammable liquids

15 Page: 15/15 STOT SE Specific target organ toxicity single exposure Acute Tox. Acute toxicity Skin Corr./Irrit. Skin corrosion/irritation Eye Dam./Irrit. Serious eye damage/eye irritation H226 Flammable liquid and vapour. H336 May cause drowsiness or dizziness. H318 Causes serious eye damage. H315 Causes skin irritation. H302 Harmful if swallowed. H335 May cause respiratory irritation. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.