Version 1.3 Revision Date Classification (67/548/EEC, 1999/45/EC)
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2 Classification (67/548/EEC, 1999/45/EC) Highly flammable Harmful Irritant Dangerous for the environment Label elements Labeling (REGULATION (EC) No 1272/2008) Hazard pictograms : R11: Highly flammable. R65: Harmful: may cause lung damage if swallowed. R38: Irritating to skin. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67: Vapors may cause drowsiness and dizziness. Signal Word : Danger Hazard Statements : H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. Precautionary Statements : Prevention: P210 P233 P240 P243 P273 P280 Response: P301 + P310 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Take precautionary measures against static discharge. Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P331 Storage: P403 + P235 Do NOT induce vomiting. Store in a well-ventilated place. Keep cool. Hazardous ingredients which must be listed on the label:
3 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms : Cyclohexylmethane Hexahydrotoluene MCH (Pure Grade) Molecular formula : C7H14 Mixtures Hazardous ingredients Chemical Name CAS-No. EINECS-No Classification (67/548/EEC) F; R11 Xn; R65 Xi; R38 R67 N; R51-R53 Classification (REGULATION (EC) No 1272/2008) Asp. Tox. 1; H304 Skin Irrit. 2; H315 Flam. Liq. 2; H225 STOT SE 3; H336 Aquatic Chronic 2; H411 Concentration [wt%] F; R11 Repr.Cat.3; R63 Xn; R48/20-R65 Xi; R38 R67 Xn; R65 Flam. Liq. 2; H225 Repr. 2; H361 Asp. Tox. 1; H304 STOT RE 2; H373 Skin Irrit. 2; H315 STOT SE 3; H336 Repr. 2; H361 0,1-1 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section FIRST AID MEASURES General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Symptoms of poisoning may only appear several hours later. Do not leave the victim unattended. If inhaled : Move to fresh air. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Take victim immediately to hospital.
4 5. FIRE-FIGHTING MEASURES Flash point : -5,5 C (22,1 F) Method: Tagliabue Open Cup Autoignition temperature : 285 C (545 F) Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Special protective equipment for fire-fighters : Dry chemical. Carbon dioxide (CO2). Alcohol-resistant foam. : High volume water jet. : Do not allow run-off from fire fighting to enter drains or water courses. : Wear self contained breathing apparatus for fire fighting if necessary. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Fire and explosion protection Hazardous decomposition products : Do not spray on an open flame or any other incandescent material. Use only explosion-proof equipment. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away from open flames, hot surfaces and sources of ignition. : Hydrocarbons. Carbon oxides. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Handling
5 Advice on safe handling : Avoid formation of aerosol. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Advice on protection against fire and explosion : Do not spray on an open flame or any other incandescent material. Use only explosion-proof equipment. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away from open flames, hot surfaces and sources of ignition. Storage Requirements for storage areas and containers : No smoking. Keep container tightly closed in a dry and wellventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters LT Komponentai Pagrindas, bazė Vertė Kontrolės parametrai Pastaba LT OEL IPRD 50 mg/m3 PL Składniki Podstawa Wartość Parametry dotyczące kontroli PL NDS NDS mg/m3 PL NDS NDSch mg/m3 PT Componentes Bases Valor Parâmetros de controlo PT OEL VLE-MP 400 ppm, Uwaga Nota SI Komponente Osnova Vrednost Parametri nadzora Pripomba SI OEL MV 500 ppm, mg/m3 SK Súčasti Podstata Hodnota Kontrolné parametre Poznámka SK OEL NPEL 200 ppm, 810 mg/m3 Kategórie II, SK OEL CEIL mg/m3 Kategórie II, Kategórie II Faktory so systémovými účinkami. Trvanie píku: 15 minút priemerná hodnota. Frekvencia za zmenu: 4. Interval medzi píkmi: 1hodina. Kategória II znamená, že NPEL môže byť krátkodobo prekročený maximálne 2-8 krát za zmenu. Maximálne trvanie priemernej píkovej expozície nesmie presiahnuť 15 minút 4-krát za zmenu v intervale jednej hodiny medzi píkmi, pričom priemerný NPEL za 8-hodinovú zmenu musí byť dodržaný. AT Inhaltsstoffe Basis Wert Zu überwachende Parameter AT OEL TMW 400 ppm, mg/m3 AT OEL KZW ppm, mg/m3 Bemerkung BE Bestanddelen Basis Waarde Controleparameters Opmerking BE OEL TGG 8 hr 400 ppm, mg/m3
6 CZ Složky Základ Hodnota Kontrolní parametry Poznámka CZ OEL PEL mg/m3 CZ OEL NPK-P mg/m3 DE Inhaltsstoffe Basis Wert Zu überwachende Bemerkung Parameter DE TRGS 900 AGW 200 ppm, 810 mg/m3 DFG, DFG Senatskommission zur Prüfung gesundheitsschädlicher Arbeitsstoffe der DFG (MAK-Kommission) DK Komponenter Basis Værdi Kontrolparametre Note DK OEL GV 200 ppm, 805 mg/m3 EE Komponendid, osad Alused Väärtus Kontrolliparameetrid Märkused EE OEL Piirnorm 400 ppm, mg/m3 ES Componentes Base Valor Parámetros de control Nota ES VLA VLA-ED 400 ppm, mg/m3 FI Aineosat Peruste Arvo Valvontaa koskevat muuttujat FI OEL HTP-arvot 8h 400 ppm, mg/m3 FI OEL HTP-arvot 15 min 500 ppm, mg/m3 Nota FR Composants Base Valeur Paramètres de Note contrôle FR VLE VME 400 ppm, mg/m3 normal, normal Valeurs limites indicatives GR Συστατικά Βάση Τιμή Παράμετροι ελέγχου Σημείωση GR OEL TWA 500 ppm, mg/m3 GR OEL STEL 500 ppm, mg/m3 IE Ingredients Basis Value Control parameters Note IE OEL OELV - 8 hrs (TWA) 400 ppm, mg/m3 IE OEL OELV - 15 min (STEL) 500 ppm, mg/m3 Personal protective equipment Respiratory protection : In the case of vapor formation use a respirator with an approved filter. Hand protection : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water. Tightly fitting safety goggles. Skin and body protection : Impervious clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
7 Appearance Form : Liquid Physical state Color Odor : Liquid : Colorless : Mild Safety data Flash point : -5,5 C (22,1 F) Method: Tagliabue Open Cup Lower explosion limit Upper explosion limit Oxidizing properties : 1,2 %(V) : 6,7 %(V) : no Autoignition temperature : 285 C (545 F) Molecular formula Molecular Weight ph Freezing point Boiling point/boiling range Vapor pressure Density Water solubility Viscosity, dynamic : C7H14 : 98,21 g/mol : No data available : -127 C (-197 F) : 100,4 C (212,7 F) : 1,60 PSI at 37,8 C (100,0 F) : 771,7 G/L : Negligible : 0,732 cps Relative vapor density : 3 (Air = 1.0) Evaporation rate : 1 Percent volatile : > 99 % 10. STABILITY AND REACTIVITY Possibility of hazardous reactions Conditions to avoid : Heat, flames and sparks. Materials to avoid : May react with oxygen and strong oxidizing agents, such as chlorates, nitrates, peroxides, etc.
8 Other data 11. TOXICOLOGICAL INFORMATION : This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. No decomposition if stored and applied as directed. Acute oral toxicity : LD50: > mg/kg Species: rat LD50: mg/kg Species: rat Sex: Not Specified Acute inhalation toxicity : LC50: > 4044 ppm Exposure time: 4 HR Species: rat LC50: mg/lexposure time: 4 HR Species: rat Acute dermal toxicity : LD50: > mg/kg Species: rabbit LD50: mg/kg Species: rabbit Sex: Not Specified Skin irritation Eye irritation Sensitization : May cause skin irritation in susceptible persons. : May cause eye irritation. Vapors may cause irritation to the eyes, respiratory system and the skin. Vapors may cause irritation to the eyes, respiratory system and the skin. : Did not cause sensitization on laboratory animals. Repeated dose toxicity : Species: rabbit Application Route: Inhalation Dose: 0, 1160, 3330 ppm Exposure time: 10 wk NOEL: 1160 ppm Lowest observable effect level: 3330 ppm
9 Species: rat Application Route: Inhalation Dose: 0, 100, 625, 1250, 3000 ppm Exposure time: 15 wk Number of exposures: 6.5 h/d, 5 d/wk NOEL: 625 ppm Species: mouse Application Route: Inhalation Dose: 0, 100, 625, 1250, 3000 ppm Exposure time: 14 wk Number of exposures: 6.5 h/d, 5 d/wk NOEL: 100 ppm Carcinogenicity : Species: rat Dose: 0, 600, 1200 ppm Exposure time: 2 yrs Number of exposures: 6.5 h/d, 5 d/wk Remarks: No evidence of carcinogenicity Species: mouse Dose: 0, 600, 1200 ppm Exposure time: 2 yrs Number of exposures: 6.5 h/d, 5 d/wk Remarks: No evidence of carcinogenicity Reproductive toxicity : Species: rat Application Route: Inhalation Dose: 0, 100, 500, 2000 ppm Test period: 95 d NOAEL Parent: 2000 ppm Teratogenicity : Species: rat Application Route: Inhalation Dose: 0, 100, 500, 2000 ppm Test period: 95 d NOAEL Teratogenicity: ppm Aspiration toxicity Further information : May be fatal if swallowed and enters airways. Substances known to cause human aspiration toxicity hazards or to be regarded as if they cause human aspiration toxicity hazard. : Concentrations substantially above the TLV value may cause narcotic effects. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Solvents may degrease the skin.
10 12. ECOLOGICAL INFORMATION Toxicity to fish : LC50: 72 mg/l Exposure time: 96 HR Species: see user defined free text LC50: mg/l Exposure time: 96 HR Species: Pimephales promelas (fathead minnow) Toxicity to daphnia and other aquatic invertebrates. : EC50: 3,78 mg/l Exposure time: 48 HR Species: Daphnia magna (Water flea) Toxicity to algae : EC50: 134 mg/l Exposure time: 72 HR Species: Chlamydomonas angulosa (Green algae) Elimination information (persistence and degradability) Biodegradability : Expected to be biodegradable Further information on ecology Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with long lasting effects. 13. DISPOSAL CONSIDERATIONS The information in this MSDS pertains only to the product as shipped. Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility. Product Contaminated packaging : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.
11 14. TRANSPORT INFORMATION The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition). Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the MSDS and the bill of lading. USDOT UN2296, METHYLCYCLOHEXANE, 3, II IMO / IMDG UN2296, METHYLCYCLOHEXANE, 3, II, MP (METHYLCYCLOHEXANE), (-5,5 C) IATA UN2296, METHYLCYCLOHEXANE, 3, II ADR UN2296, METHYLCYCLOHEXANE, 3, II RID UN2296, METHYLCYCLOHEXANE, 3, II 15. REGULATORY INFORMATION National legislation Major Accident Hazard Legislation : 96/82/EC Update: 2003 Dangerous for the environment 9b Quantity 1: 200 t Quantity 2: 500 t : 96/82/EC Update: 2003 Highly flammable 7b Quantity 1: t Quantity 2: t Notification status Europe REACH United States of America TSCA Canada DSL Australia AICS New Zealand NZIoC Japan ENCS Korea KECI Philippines PICCS China IECSC
12 16. OTHER INFORMATION NFPA Classification : Health Hazard: 1 Fire Hazard: 3 Reactivity Hazard: Further information Legacy MSDS Number : Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this MSDS pertains only to the product as shipped. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of Government LOAEL Lowest Observed Adverse Effect Level Industrial Hygienists AICS Australia, Inventory of Chemical NFPA National Fire Protection Agency Substances DSL Canada, Domestic Substances List NIOSH National Institute for Occupational Safety & Health NDSL Canada, Non-Domestic Substances List NTP National Toxicology Program CNS Central Nervous System NZloC New Zealand Inventory of Chemicals CAS Chemical Abstract Service NOAEL No Observable Adverse Effect Level EC50 Effective Concentration NOEC No Observed Effect Concentration EC50 Effective Concentration 50% OSHA Occupational Safety & Health Administration EINECS European Inventory of Existing Chemical PEL Permissible Exposure Limit Substances MAK Germany Maximum Concentration Values PICCS Philipines Inventory of Commercial Chemical Substances GHS Globally Harmonized System PRNT Presumed Not Toxic >= Greater Than or Equal To RCRA Resource Conservation Recovery Act IC50 Inhibition Concentration 50% STEL Short-term Exposure Limit IARC International Agency for Research on Cancer SARA Superfund Amendments and Reauthorization Act. IECSC Inventory of Existing Chemical TLV Threshold Limit Value Substances in China ENCS Japan, Inventory of Existing and New TWA Time Weighted Average Chemical Substances KECI Korea, Existing Chemical Inventory TSCA Toxic Substance Control Act <= Less Than or Equal To UVCB Unknown or Variable Compositon, Complex Reaction Products, and Biological Materials LC50 Lethal Concentration 50% WHMIS Workplace Hazardous Materials
13 LD50 Lethal Dose 50% Information System Full text of R-phrases referred to under sections 2 and 3 R11 Highly flammable. R38 Irritating to skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R51 Toxic to aquatic organisms. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Full text of H-Statements referred to under sections 2 and 3. H225 H304 H315 H336 H361 H373 H411 Highly flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects.
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