MSDS NIC Industries, Inc
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1 1 of 5 1 PRODUCT AND COMPANY IDENTIFICATION Manufacturer NIC Industries, Inc th Street White City, OR Contact: Telephone Number: FAX Number: info@nicindustries.com Web 2 HAZARDS IDENTIFICATION Route of Entry: Target Organs: Inhalation: Skin Contact: Eye Contact: Ingestion: Eyes, Ingestion, Inhalation, Skin Central Nervous System, Kidneys, Liver May produce symptoms of central nervous system depression including headache, dizziness, nausea, loss of balance, and drowsiness. Vapor and/or mist can be irritating to the respiratory tract. May cause moderate irritation. May cause severe irritation Low ingestion hazard in normal use. Swallowing large amounts may cause drowsiness. Repeated ingestion may cause internal injuries. HMIS II-ratings (scale 0-4): Health = 2, Fire = 3, Reactivity = 0 HMIS Rating H2/F3/PH 3 COMPOSITION/INFORMATION ON INGREDIENTS Ingredients: Cas # Perc. Chemical Name % Trisiloxane, octamethyl % Silicic acid (H4SiO4), tetrapropyl ester % Silicic acid (H4SiO4), tetrakis(2-butoxyethyl) ester % 1-Butanol, titanium(4+) salt
2 4 FIRST AID MEASURES 2 of 5 Inhalation: Skin Contact: Eye Contact: Ingestion: Remove to fresh air. Seek medical attention immediately. Wash thoroughly with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash all clothing before re-use. If irritation persists, seek medical attention. Immediately flush with water for at least 15 minutes. Seek medical attention. Do not induce vomiting. Seek medical attention immediately. 5 FIRE FIGHTING MEASURES Flash Point: Flash Point Method: Burning Rate: Autoignition Temperature: LEL: UEL: Flammability Classification: 80.6 deg F Closed Cup Not Determined Not Determined Not available Not available Flammable Extinguishing Media: On large fires use medium expansion (> 30:1) AFFF alcohol compatible foam or water spray. On small fires use medium expansion (>30:1) AFFF alcohol compatible foam, CO2 or water spray. Water can be used to cool fire exposed containers. Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Evacuate all unnecessary personnel and eliminate all sources of ignition. Environmental Precautions: Contain liquids and prevent discharge into streams and sewers, control or stop the loss of volatile material to the atmosphere. Do not apply water to the spill. Spills should be reported, if required, to the appropriate local, state, or federal agencies. Small Spills: Cover with an inorganic absorbent, such as vermiculite, perlite, ground clay, or sand; sweep up, and dispose of appropriately. Clean contaminated area with soap and water. Large Spills: Dike to contain and pump into drums for disposal. Add vermiculite absorbent to remaining material (as above).
3 7 HANDLING AND STORAGE 3 of 5 Handling Precautions: Storage Requirements: Use with adequate ventilation. Product evolves n-propyl alcohol when exposed to water or humid air. Provide ventilation during use to control n-propyl alcohol within exposure guielines or use respiratory protection. Product evolves 2-butoxyethanol when exposed to water or humid air. Provide ventilation during use to control 2-butoxyethanol within exposure guielines or use respiratory protection. Product evolves n-butyl alcohol when exposed to water or humid air. Provide ventilation during use to control n-butyl alcohol within exposure guielines or use respiratory protection. Keep container properly closed and properly labeled. Store in a cool dry place designated for combustible liquid storage. Keep away from heat, sparks, and open flame. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Protective Equipment: Exposure Guidelines/Other: General room ventilation plus local exhaust at points of emission to maintain levels of airborne contaminates below exposure limits. HMIS PP, C Goggles, Gloves, Apron Eyes: Use chemical worker's goggles Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Suitable Gloves: Silver Shield Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. IH personnel can assist in judging the adequacy of existing engineering controls. Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR ) and use NIOSH/MSHA approved respirators. CAS NUMBER COMPONENT NAME EXPOSURE LIMITS Octamethyltrisiloxane TWA 200 ppm Tetrapropyl orthosilicate OSHA PEL: TWA: 200 ppm STEL: 250 ppm ACGIH TLV: TWA: 200 ppm STEL: 400 ppm Butoxy ethyl orthosilicate OSHA PEL: TWA: 50 ppm 240 mg/m3 ACGIH TLV: TWA: 200 ppm Tetrabutyl titanate OSHA PEL: TWA 100 ppm ACGIH TLV: 20 ppm
4 9 PHYSICAL AND CHEMICAL PROPERTIES 4 of 5 Appearance: Physical State: Odor: ph: Vapor Pressure: Vapor Density: Clear liquid Liquid Slight Odor Boiling Point: Freezing/Melting Pt.: Solubility: Spec Grav./Density: >100 deg C STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid (incompatability): Hazardous Decomposition products: Hazardous Polymerization: Stable None Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 7 Will not occur 11 TOXICOLOGICAL INFORMATION No known applicable information 12 ECOLOGICAL INFORMATION Complete information is not yet available 13 DISPOSAL CONSIDERATIONS Do not mix this product with aqueous or other protic waste streams. Dispose of in accordance with the local, state, and federal regulations is the recommended disposal method.
5 14 TRANSPORT INFORMATION DOT Class: Flammable Liquid (3) #3 US DOT: Proper Shipping Name: Octamethyltrisiloxane Hazard Class: 3 UN Number: 1993 Packing Group: III IATA: Proper Shipping Name: Octamethyltrisiloxane Hazard Class: 3 UN Number: 1993 Packing Group: III 5 of 5 15 REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR OTHER INFORMATION U.S. Federal Regulations: OSHA Standard 29 CFR requires that information be provided to employees regarding the hazards of chemicals by means of hazard communication program including labeling, material safety data sheets, training and access to written records. We request that you, and it is your legal duty to, make all information in this available to all your employees. NON-WARRANTY: The information presented in this publication is based upon the research and experience of NIC Industries, Inc. No representation or warranty is made, however, concerning the accuracy or completeness of express or implied, including without limitation any warranty of merchantability or fitness for any particular purposes, and no warranty or representation shall be implied by law or otherwise. Any products sold by NIC Industries, Inc. are not warranted as suitable for any particular purpose to the buyer. The suitability of any products for any purpose particular to the buyer is for the buyer to determine. NIC Industries, Inc. assumes no responsibility for the section of products suitable to the particular purposes of any particular buyer. NIC Industries, Inc shall in no way be liable for any special, incidental, or consequential damages. END OF MSDS DOCUMENT
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