2.2. Specific hazards: This product is not a hazardous substance in sense of the law on chemicals and regulations on hazardous substances.

Transcription

1 SAFETY DATA SHEET Page 1 of 6 Date issued: Date revised: Revised version No.: 3 1. Chemical product and supplier identification: 1.1. Product identification: P-105 GUMINOVA Identification No.: P Product use: Additive for regeneration of damages of printing rubber 1.3. Supplier identification ( manufacturer, importer, distributor): Supplier name: CINKARNA CELJE, Inc Supplier address: Kidričeva 26, 3001 CELJE SLOVENIJA, Contact person: lidija.senicar@cinkarna.si Emergency number: (Cinkarna Celje) 2. Hazard identification: 2.1. Hazards: Specific hazards: This product is not a hazardous substance in sense of the law on chemicals and regulations on hazardous substances Symptoms after exposure: - Inhalation: - - Skin contact: Slightly irritation - Contact with eyes: Slightly irritation. - Ingestion: Danger to environment: - 3. Composition with information on hazardous ingredients: 3.1. Common name: P-105 GUMINOVA Hazardous ingredients: Chemical name Registration number Index No. CAS No. EC No. wt./vol/%/max concentration Hazard symbol Risk Phrases

2 Cinkarna Celje, SAFETY DATA SHEET Page 2 of 6 Amidosulfonska kislina Ortofosforjeva kislina < C < 5 C > 5 Xi C 36/38, 52/ First aid measures: 4.1. General instructions: When using do not eat, drink or smoke Inhalation: Move to fresh air. Get medical attention if symptoms occur Contact with skin: In case of contact with skin, wash immediately skin with plenty of water. Take off immediately all contaminated clothing, shoes and any other item. Flush skin with water for at least 15 minutes. Get medical attention if symptoms occur Contact with eyes: Flush eyes with large amounts of water. If irritation persist, get medical attention Ingestion: If swallowed, do not induce vomiting. Get prompt medical attention First aid at work: - 5. Fire-fighting measures: 5.1. Suitable extinguishing medium: Water spray, foam, dry chemical, carbon dioxide Special exposure hazards: Special protective fire fighting equipment, indicated by standard if any: Use self-contained breathing apparatus if needed, eyes protection and protective clothing. 6. Accidental release measures: 6.1. Personal safety measures: Protective gloves, protective work clothing, ambient ventilation Environment protection: Prevent contamination of water Cleaning after accidental discharge: Contain spilled oil with sand or earth; remove from water surface by skimming or with suitable absorbents. Dispose collected material according to regulations. 7. Handling and storage: 7.1. Handling: Safety measures: Technical measures: Ambient ventilation Recommended and forbidden measures: No special measures required

3 Cinkarna Celje, SAFETY DATA SHEET Page 3 of Storage: Conditions for safe storage: Ambient temperature and atmospheric pressure Separating incompatible products: Strong oxidants Special packaging: Protection against static electricity: Specific use: Additive for printing inks for printing on offset printing machines. 8. Exposure control/personal protection: 8.1. Exposure limit values: Komponenta CAS- številka Vrednost Ortofosforjeva kislina MDK = 1 mg/m Exposure control: Health and safety measures at the workplace: Personal protection: - Respiratory system protection: - Skin and body protection: Hand protection: Eye protection: General work hygiene: Protective work clothing Protective gloves Protective glasses. The usual precautionary measures for handling with chemicals Environment exposure control: - 9. Physical and chemical properties: 9.1. General information: - appearance Red liquid. - odour ether 9.2. Important health, safety and ecological information: - ph: Boiling point: Above C - Melting point: N.a. - Flash point: > 75 C

4 Cinkarna Celje, SAFETY DATA SHEET Page 4 of 6 - Ignition point ( for solids and gases): N.a. -Explosive properties (upper/lower border): N.a. - Oxidation properties: N.a. - Vapour pressure: - - Relative density: 1,075 1,085 g/cm 3 (pri 20 C) - Solubility ( in water and fats): Soluble in water. - Partition coefficient: n-octanol/water - - Other data: - - Note: Stability and reactivity: Stability and reactivity: Stable under recommended storage conditions Conditions to avoid: High temperatures,sun Incompatibility with other substances: Hazardous products of decomposition: Strong oxidants. When exposed to high temterature may produce carbon dioxide Other data: Toxicological information: Acute effects (acute toxicity, irritation and corrosivity): - inhalation: - skin contact - ingestion: Chronic toxicity or repeated dose toxicity: Ortofosforic acid Sulfaminic acid - - LD 50 = 2740mg/kg (rabbit) - LD 50 = 1530 mg/kg (rats) LD 50 (rats) = 3150 mg/kg Slightly irritation of skin, eyes Oversensibility: Specific effects(cmr effectscarcinogenity,mutagenicity and toxicity for reproduction: None 12. Ecological information: Ecotoxicity: WKG 1 Harmful for water ( weak ) Mobility: Soluble in water.

5 Cinkarna Celje, SAFETY DATA SHEET Page 5 of Persistence and degradability: biodegradable Bioaccumulative potential: Not expected to accumulate in biological organisms Results of PBT assessment: Slightly hazardous for water Other adverse effects: toxicity For sulfamin acid: For fosforic acid: - fish: LC50 (96 hours) = 70,3 mg/l LC50 = mg/l - bakteries: EC10 (16hurs) > 1000 mg/l 13. Disposal considerations: Product: Waste and unused materials should be disposed in accordance with Local and National regulations Contaminated packaging: Contaminated packaging should be disposed in accordance with Local and National regulations. 14. Transport information: 14.1 ADR, RID: / UN number: / Name: P-105 GUMINOVA Class: Not classified Classification code: Not classified Packaging group: Not classified Hazard label: Not classified as hazardous cargo Tunnel restriction code ( TRC): Regulatory information: EC classification, letter, hazard labels, S and R (with the text), special regulations: Classification: Classification not required Labelling: None Risk Phrases: None Safety Phrases: None Special provisions: None Regulations /Standards: Waste and unused materials should be disposed in accordance with Local and National regulations.

6 Cinkarna Celje, SAFETY DATA SHEET Page 6 of Other information: Write out the full text of any R phrases referred to under heading 2 and 3 of the SDS: R34 ; Causes burns. R36 ; Irritating to eyes. R52/53; Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Staff training: No Recommended or restricted use of product: One year Instructions: No Sources: UL RS,No.: 110/03,16/08,104/03,35/05,67/05,84/06,106/06,137/06,53/07,54/07,34 /08 (ES) No.: 1907/06 Directive No.:67/548/EGS Directive No.: 2006/8/ES Revised issue: REACH legislation The information presented here is based on our present knowledge and experienced on current EEC and national laws and is intended to describe our product with respect to possible safety demands.