MATERIAL SAFETY DATA SHEET

Transcription

1 Page 1 of 5 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: CHEMICAL FAMILY: Alkylalkoxysilane PRODUCT USE: Primer/ Water repellent MANUFACTURER: KEIM Mineral Coatings of America, Inc Texland Boulevard, #600 Charlotte, NC Phone: Emergency Phone: only in US and Canada (INFOTRAC) 2. HAZARD IDENTIFICATION POTENTIAL HEALTH EFFECTS: (Also see section 11) EMERGENCY OVERVIEW: WARNING! IRRITANT TO SKIN, EYES AND RESPIRATORY PASSAGES INHALATION OF AEROSOL MIST MAY CAUSE LUNG DAMAGE. ROUTES OF ENTRY: Skin and eye contact and inhalation. Appearance: Colorless liquid with a slight odor CARCINOGENICITY: NTP: No, IARC: No, OSHA: No Harmful to aquatic organisms. May have long term adverse effects in the aquatic environment. This material is considered hazardous by the OSHA Hazard Communication Standard. (29CFR ) 3. COMPOSITION/ INFORMATION ON INGREDIENTS Component CAS# % by wt. Octyltriethoxylsilane

2 Page 2 of 5 4. FIRST AID MEASURES: SKIN: Wash with soap or mild detergent and large amounts of water. Do not use solvents or thinners. Get medical attention if irritation occurs EYES: Hold eyes open and flush for at least 15 minutes with large amounts of water. Get immediate medical attention if irritation occurs. INGESTION: Do not induce vomiting. Give two glasses of water to dilute stomach contents. Never give anything by mouth to an unconscious person. Get immediate medical attention. INHALATION: Remove to fresh air. If breathing is difficult administer oxygen. Consult physician if irritation of respiratory passage occurs. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Alcohol foam, carbon dioxide, or dry powder. Water may be used to cool tanks and containers in fire area. SPECIAL FIRE FIGHTING PROCEDURES: Use self-contained breathing apparatus and full protective clothing. 6. ACCIDENTAL RELEASE MEASURES: SPILL AND LEAK PROCEDURES: Wear personal protective equipment. Contain spills using inert absorbent and place in suitable containers. Spilled material is a slipping hazard. 7. HANDLING AND STORAGE STORAGE: Store in closed original containers. Protect from moisture. HANDLING: Use in a well ventilated area. Wear clothing, gloves and glasses to avoid contact with skin and eyes. Keep away from sources of ignition.

3 Page 3 of 5 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS: Component CAS# Exposure limits Ethanol* PPM TWA ACGIH *Forms due to reaction or decomposition of silicate. ENGINEERING CONTROLS: Use in a well ventilated area. RESPIRATORY PROTECTION: For exposure to vapor or mist, or If airborne concentration become irritating, use a NIOSH approved respirator in accordance with OSHA Respirator Protection requirements under 29 CFR SKIN PROTECTION: Clothing and gloves suitable to avoid skin contact. Use butyl rubber or Nitrile rubber gloves and protective clothing. EYE PROTECTION: Safety glasses with side shields. 9. PHYSICAL AND CHEMICAL PROPERTIES Property Value Appearance Colorless liquid Odor Slight Flashpoint >104 o F (40 o C) Boiling Point 456 o F (236 o C) Vapor pressure at 25 C 6.0 hpa Density at 25 C g/cm 3 Lower Explosion Limit 3.5 vol.%* Upper Explosion Limit 15 vol.%* Solubility in Water Insoluble Partition Coeficient-octanol/water 6.1 (Log pow) Thermal Decomposition >302 o F (150 o C) *Limits are for released ethanol 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: Decomposes and releases ethanol on contact with water. HAZARDOUS DECOMPOSITION PRODUCTS: Ethanol. POLYMERIZATION: Will not occur. INCOMPATIBILITIES: Reacts with water, acids and bases and forms ethanol.

4 Page 4 of TOXICOLOGICAL INFORMATION Acute oral toxicity: LD50 rat >2000 mg/kg Acute dermal: LD50 rat >2000 mg/kg Subacute: NOAL rat: 150mg/kg/h/d 28 day Product was a mild skin irritant but not an eye irritant when tested on rabbits. Product was not a sensitizer when tested on guinea-pigs 12. ECOLOGICAL INFORMATION Product is not easily biodegradable: 0% (28 days) Manometric Respirometry Fish toxicity: LC50 Oncorhynchus mykiss 41 mg/l 96 h Daphnia toxicity: EC50 Daphnia magna 12 mg/l 48 h Harmful to aquatic organisms. May have long term adverse effects in the aquatic environment. Hydrolysis will form ethanol, silanol and/or siloxanol compounds. Silicon compounds are adsorbed in activated sludge. 13. DISPOSAL CONSIDERATIONS Dispose of or incinerate in accordance with Federal, State or Local regulations. 14. TRANSPORT INFORMATION DOT SHIPPING NAME: Not regulated. Material does not sustain combustion. 15. REGULATORY INFORMATION All components of this product are on the TSCA Inventory. SARA Title III: This product contains no toxic chemicals which are subject to the supplier notification requirements of Section 313 of the Superfund Amendments and Reauthorization Act (SARA/EPCRA) and the requirements of 40 CFR Part 372. Note: Entries under this section cover only those regulations typically addressed in the MSDS generating process, such as, TSCA, and EPCRA/SARA Title III.

5 Page 5 of OTHER INFORMATION HAZCOM LABEL: WARNING! IRRITANT TO SKIN, EYES AND RESPIRATORY PASSAGES INHALATION OF AEROSOL MIST MAY CAUSE LUNG DAMAGE. rtk Silan-100(v3).doc Version 2 contains changes to almost all sections of the MSDS. This MSDS conforms to the American National Standard, ANSI Z To the best of our knowledge, the information contained in this MSDS is accurate. It is intended to assist the user in his evaluation of the product's hazards, and safety precautions to be taken in its use. The data on this MSDS relate only to the specific material designated herein. We do not assume any liability for the use of, or reliance on this information, nor do we guarantee its accuracy or completeness. Version 3 - Reviewed Version 3 November 18, 2011 Version 2 September 14, 2007 Version 1 January 25, 2006 (v3).doc