SAFETY DATA SHEET. Section 1: Identification of the substance/mixture and of the company/undertaking. Section 2: Hazards identification
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1 Page: 1 Compilation date: 22/11/2013 Revision No: 1 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: CAS number: Product code: OR Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Company name: Apollo Scientific Ltd Units 3 & 4 Parkway Denton Manchester M34 3SG UK Tel: Fax: david.tideswell@apolloscientific.co.uk 1.4. Emergency telephone number Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CHIP: Classification under CLP: Most important adverse effects: T: R25; Xi: R37/38; Xi: R41 Acute Tox. 3: H301; STOT SE 3: H335; Eye Dam. 1: H318; Skin Irrit. 2: H315 Toxic if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes Label elements Label elements under CLP: Hazard statements: Signal words: Hazard pictograms: H301: Toxic if swallowed. H315: Causes skin irritation. H318: Causes serious eye damage. H335: May cause respiratory irritation. Danger GHS05: Corrosion GHS06: Skull and crossbones
2 Page: 2 Precautionary statements: Label elements under CHIP: Hazard symbols: P280: Wear protective gloves/protective clothing/eye protection/face protection. P : IF exposed or if you feel unwell: Call a POISON CENTER or doctor. Toxic. Risk phrases: R25: Toxic if swallowed. R37/38: Irritating to respiratory system and skin. R41: Risk of serious damage to eyes Other hazards PBT: This substance is not identified as a PBT substance. Section 3: Composition/information on ingredients 3.1. Substances Chemical identity: Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Eye contact: Ingestion: Inhalation: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning. Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination. Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as possible. Remove casualty from exposure ensuring one's own safety whilst doing so. If conscious, ensure the casualty sits or lies down. If unconscious and breathing is OK, place in the recovery position. If unconscious, check for breathing and apply artificial respiration if necessary. If breathing becomes bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible Most important symptoms and effects, both acute and delayed Skin contact: There may be redness or whiteness of the skin in the area of exposure. Irritation or pain may occur at the site of contact. Absorption through the skin may be fatal.
3 Eye contact: Ingestion: Inhalation: There may be severe pain. The eyes may water profusely. There may be soreness and redness of the mouth and throat. There may be vomiting. There may be shortness of breath with a burning sensation in the throat. Absorption through the lungs can occur causing symptoms similar to those of ingestion. Page: Indication of any immediate medical attention and special treatment needed Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Carbon dioxide, dry chemical powder, foam. Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers Special hazards arising from the substance or mixture Exposure hazards: Toxic. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Nitrogen oxides (NOx). Hydrogen bromide (HBr) Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Notify the police and fire brigade immediately. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to take action without suitable protective clothing - see section 8 of SDS. Do not create dust Environmental precautions Environmental precautions: Do not discharge into drains or rivers Methods and material for containment and cleaning up Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Transfer to a closable, labelled salvage container for disposal by an appropriate method Reference to other sections Section 7: Handling and storage
4 Page: Precautions for safe handling Handling requirements: Avoid direct contact with the substance. Ensure there is exhaust ventilation of the area. Avoid the formation or spread of dust in the air. Only use in fume hood Conditions for safe storage, including any incompatibilities Storage conditions: Suitable packaging: Store in cool, well ventilated area. Keep container tightly closed. Light Sensitive. Must only be kept in original packaging Specific end use(s) Specific end use(s): Section 8: Exposure controls/personal protection 8.1. Control parameters Workplace exposure limits: 8.2. Exposure controls Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: Ensure there is exhaust ventilation of the area. Self-contained breathing apparatus must be available in case of emergency. Particle filter class P1 (EN143). Protective gloves. Safety glasses with side-shields. Ensure eye bath is to hand. Protective clothing. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Powder Melting point/range C: Part.coeff. n-octanol/water: log Pow: Other information Other information: Section 10: Stability and reactivity Reactivity Reactivity: Stable under recommended transport or storage conditions Chemical stability Chemical stability: Stable under normal conditions Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
5 Page: Conditions to avoid Conditions to avoid: Heat. Light Incompatible materials Materials to avoid: Strong oxidising agents. Strong acids Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Nitrogen oxides (NOx). Hydrogen bromide gas (HBr). Section 11: Toxicological information Information on toxicological effects Relevant hazards for substance: Hazard Route Basis Acute toxicity (ac. tox. 3) ING Based on test data Skin corrosion/irritation DRM Based on test data Serious eye damage/irritation OPT Based on test data STOT-single exposure INH Based on test data Symptoms / routes of exposure Skin contact: Eye contact: Ingestion: Inhalation: There may be redness or whiteness of the skin in the area of exposure. Irritation or pain may occur at the site of contact. Absorption through the skin may be fatal. There may be severe pain. The eyes may water profusely. There may be soreness and redness of the mouth and throat. There may be vomiting. There may be shortness of breath with a burning sensation in the throat. Absorption through the lungs can occur causing symptoms similar to those of ingestion. Section 12: Ecological information Toxicity Ecotoxicity values: Persistence and degradability Persistence and degradability: Bioaccumulative potential Bioaccumulative potential: Mobility in soil Mobility:
6 Page: Results of PBT and vpvb assessment PBT identification: This substance is not identified as a PBT substance Other adverse effects Other adverse effects: Section 13: Disposal considerations Waste treatment methods Disposal operations: Disposal of packaging: NB: MATERIAL SHOULD BE DISPOSED OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS Dispose of as special waste in compliance with local and national regulations Observe all federal, state and local environmental regulations. The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. Section 14: Transport information UN number UN number: UN UN proper shipping name Shipping name: TOXIC SOLID, ORGANIC, N.O.S Transport hazard class(es) Packing group Transport class: 6.1 Packing group: III Environmental hazards Environmentally hazardous: No Marine pollutant: No Special precautions for user Tunnel code: E Transport category: 2 Section 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
7 Page: 7 Section 16: Other information Other information Other information: Phrases used in s.2 and 3: Legal disclaimer: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * Data predicted using computational software. Toxtree - Toxic Hazard Estimation by decision tree approach. c=toxtree ~ Data predicted using computatioanl software ACD/ToxSuite v Copyright ACD/labs, Copyright Pharma Algorithms, Inc, Advanced Chemistry Development, Inc (ACD/Labs). H301: Toxic if swallowed. H315: Causes skin irritation. H318: Causes serious eye damage. H335: May cause respiratory irritation. R25: Toxic if swallowed. R37/38: Irritating to respiratory system and skin. R41: Risk of serious damage to eyes. The material is intended for research purposes only and should be handled exclusively by those who have been fully trained in safety, laboratory and chemical handling procedures. The above information is believed to be correct to the best of our knowledge. The above information is believed to be correct to the best of our knowledge at the date of its publication, but should not be considered to be all inclusive. It should be used only as a guide for safe handling, storage, transportation and disposal. We cannot guarantee that the hazards detailed in this document are the only hazards that exist for this product. This is not a warranty and Apollo Scientific Ltd shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]
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