Product Name: Surface cleanser Article No.: Print Date: 29 March 2005 last alteration:

Transcription

1 1. Chemical Product and Company Identification 1.1 Product name: Surface cleanser 1.2 Manufacturer / distributor identification company: Egger Otoplastik+Labortechnik GmbH Aybühlweg 59 D Kempten Phone: Fax: Internet: sales@-labor.de Poison emergency: Munich (Germany) (Toxicological department of the II. Med. Hospital) Phone: Composition / Information on Ingredients 2.1 Chemical characterization (preparation): Alcohol (Propan-2-ol) Synonyms: iso-propanol, Isopropylalcohol, Dimethylcarbinol, sek-propanol 2.2 Hazardous ingredients: Additional advice: CAS-No.: EC-No.: EC Index-No.: Molecular formula: C3H8O = g/mol 3. Possible Hazards Critical hazards to man and environment: Highly flammable. Irritating to eyes. Vapours may cause drowsiness and dizziness. 4. First-Aid Measures General information: --- After inhalation: Remove from exposure, rest and keep warm. In severe cases obtain medical attention. After skin contact: Wash off thoroughly with soap and water. Remove contaminated clothing and wash before re-use. In severe cases, obtain medical attention. After eye contact: Irrigate thoroughly with water for at least 10 minutes. If discomfort persists, obtain medical attention. After swallowing: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain medical attention. Advice to doctor: --- Page 1 of 6

2 5. Fire-Fighting Measures Suitable extinguishing material: Water spray, dry powder or vaporising liquids Extinguishing material which must not be used for safety reasons: full water jet Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: --- Special protective equipment for fire fighting: --- Additional information: Highly flammable. Vapour/air mixture explosive. 6. Accidental Release Measures Personal precautions: Wear appropriate protective clothing. Environmental precautions: --- Methods for cleaning up: Small amounts: Absorb on an inert absorbent, transfer to a suitable container and arrange removal by disposal company. Wash site of spillage thoroughly with water and detergent. For large spillages liquids should be contained with sand or earth and both liquids and solids transferred to salvage containers. Any residues should be treated as for small spillages. Further information: Shut off all sources of ignition. Inform others to keep at a safe distance. Ensure supply of fresh air in enclosed rooms. 7. Handling and Storage 7.1 Handling: Precautions for safe handling: Avoid contact with skin and eyes. Wash hands and face thoroughly after working with material. Contaminated clothing should be removed and washed before re-use. Precautions against fire and explosion: All electrical equipment must be flame-proofed. 7.2 Storage: Conditions for storage rooms and vessels: Store only in original containers. Advice for storage of incompatible materials: --- Further information for storage: Store at room temperature (15 C to 25 C (59 F 77 F) recommended). Keep well closed and protected from direct sunlight and moisture. Store small containers in suitable flammable liquid storage cabinets when not in use. Page 2 of 6

3 8. Exposure Controls / Personal Protection 8.1 Additional advice on system design: Ingredients with occupational exposure limits to be monitored: UK Exposure Limits: OES-Propan-2-ol: Long term: 999 mg/m³ (400 ppm) Short term: 1250 mg/m³ (500 ppm) 8.3 Personal protection equipment General protection and hygienic measures: Engineering methods to control or prevent exposure are preferred. Methods could include process enclosure or mechanical ventilation. Respiratory protection: Self-contained breathing apparatus when vapours are generated. Hand and skin protection: Butyl rubber, Viton or PE/EVAL. Gloves subjected to permeation or any sign of degradation must be removed and replaced immediately. Eye protection: Goggles or face-shield. Hygienic measures: Plastic apron, sleeves, boots if handling large quantities. 9. Physical and Chemical Properties 9.1 Appearance: Form: Colour: Odour: fluid colourless characteristic 9.2 Data relevant for safety Method ph-value: ---) Changes in physical state: --- Melting point: - 89 C ( F) Boiling point: 82 C (179.6 F) Flash Point: 12 C (53.6 F)) Ignition temperature: 425 C (797 F) Danger of explosion: lower: 2.3 % v/v upper: 12 % v/v Vapour pressure: 33 mm Hg at 20 C (68 F) Rel. vapour densitiy: 2.07 Viscosity: ,Pa.s at 20 C (68 F) Density: 0.78 g/ml at 20 C (68 F) 9.3 Further information Solubility in water: miscible in all proportions Log P(o/w): 0.05 Page 3 of 6

4 10. Stability and Reactivity General information: Formation of peroxides possible Thermal decomposition: --- Dangerous reactions: The possibility of reaction with other substances cannot be excluded. Conditions to avoid: --- Materials to avoid: alkali metals, alkaline earth, aluminium, oxidizing agents, organic nitro compounds Hazardous decomposition: Toxicological Information Acute oral toxicity (LD50): species rat 5045 mg/kg Acute inhalative toxicity (LC50 / 4 h): species rat 16,000 ppm/8 h Irritation of skin: species rabbit slight irritation symptoms Irritation of eye: species rabbit moderate irritant effect Additional information: After inhalation: Irritation symptoms in the respiratory tract. After eye contact: Severe irritation After skin contact: Slight irritation. Degreasing effect on the skin, possibly by secondary inflammation. After absorption: headache, dizziness, inebriation, unconsciousness, narcosis. After the uptake of large quantities: respiratory paralysis, coma. 12. Ecological Information 12.1 Data on elimination (persistence and degradability): Bioaccumulation potential: low. Biological degradability: good 12.2 Behavior in environmental compartments: Adverse ecological effects cannot be excluded in the event of improper handling or disposal Ecotoxicological effects: Fish toxicity: LC50 (Pimephales promelas): mg/l/96 h Daphnia toxicity: EC50 (Daphnia magna): 3010 mg/l NOEC: 757 mg/l Algeal toxicity: EC0 (Microcystis aeruginosa): mg/l/8 d Bacterical toxicity: EC0 (Pseudomonas putida): 1050 mg/l/16 h ThOD: 2.4 BOD: % von T 12.4 Further ecological information: Low aquatic toxicity Page 4 of 6

5 13. Disposal Considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty containers thoroughly before returning for recycling. When recovery and recycling is not possible, incineration in a high temperature incinerator is the recommended method of disposal. 14. Transport Information 14.1 Regulations for land (ADR/RID/GGVS/GGVE) ADR/RID-GGVS/E class: --- No./letter: --- LQ land: Regulations for inland waterways (ADN/ADNR ADR/ADNR class: --- No./letter: --- category: Regulations for see (IMDG/GGV See) IMDG/GGVSea-class: --- EmS: --- MFAG: --- Marine pollutant: no 14.4 Regulations for air (ICAO/IATA) ICAO/IATA-class: --- UN-no.: 1213 class: 3 PG: II Proper name: ISOPROPANOL 14.5 Transport / further information: Regulatory Information 15.1 Labelling according to EC-regulations: Labelling: F Xi Symbols and hazard classification: Irritant, Highly flammable EEC/R: Highly flammable. Irritating to eyes. Vapours may cause drowsiness and dizziness. EEC/S: /25-26 Keep container tightly closed. Keep away from sources of ignition No smoking. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Special labelling for certain preparations: EC-No.: National regulations: Within the UK, the use of this material must be assessed under the Dangerous Substances and Explosive Atmospheres (DSEAR) regulations. UK transport category 2 Within the UK, the use of this material must be assessed under the Control of Substances Hazardous to Health (COSHH) regulations. page 5 of 6

6 15.3 Other regulations, restrictions and prohibition regulations: Other information n. a. = not applicable n. s. = not subject to These data are given here according to our current knowledge on experience. The data does not signify any warranty with regard to the product's properties. Page 6 of 6