COSSIL 18 SAFETY DATA SHEET

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY 1.1. Product Description Product Name:Cossil Relevant identified uses of the substance or mixture and uses advised against Industrial use Component in personal care products 1.3. Company Information Latro Kimya Dış Ticaret Ltd. Şti. EGS Business Park Blokları B-2 Blok Kat: 6 No: 234 (DTM) Bakırköy 34149, İstanbul Telefon : Fax : cfermanci@latro.com.tr Related contact person : Cansun Şura Fermancı 1.4. Emergency telephone number First Aid: 112 Fair Station : 110 Poison information center : HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture The product has not been classified as hazardous according to the legislation in force. Clasification accosrding to Regulation (EC) No 1272/2008 as amended. Not classified 2.2. Label elements 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature: Aqueous emulsion with Polysiloxane and emulsifier 3.1. Containing the hazardous materials Chemical Name Concentrate CAS-No. Fatty alcohol ethoxylates 5-<10% Ethoxylated Isoalcohols 3-<5% Decamethylcy clopentasiloxane 0,1-<1% Dodecamethyl cyclohexasiloxane 0,1-<1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Page : 1/7

2 4. FIRST AID MEASURES 4.1. General advice If you feel unwell, seek medical advice (show the label where possible). Take off all contaminated clothing immediately If inhaled Remove from exposure, lie down. If breathing is irregular or stopped, administer artificial respiration. Monitor breathing, give oxygen if necessary. Consult a physician In case of skin contact Wash off immediately with plenty of water. Consult a physician if necessary In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician If swallowed Consult a physician. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. 5. FIREFIGHTING MEASURES 5.1. General Information Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Do not use water jet as an extinguisher, as this will spread the fire Extinguishing media All standard extinguishing agents are suitable Non suitable extinguishing media Avoid water in straight hose stream; will scatter and spread fire Specific hazards during firefighting Vapors are heavier than air and may spread near ground to sources of ignition Hazardous combustions products Keep away from sources of ignition-no smoking. All equipment used when handling the product must be grounded. Wear self-contained breathing apparatus and protective clothing. 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Remove all sources of ignition. Avoid breathing vapours, mist or gas. Ensure adequate ventilation, especially in confined areas. Immediately evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Page 2/7

3 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Pre-vent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Avoid release to the environment. Refer to special instructions / Safety data sheets Methods for cleaning up Caution: Contaminated surfaces may be slippery. Collect spillage with granulates, sawdust, rags or other absorbent. Remove sources of ignition. Sweep up spilled substance and remove to safe place. 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Keep away from food, drink and animal feeding stuffs. Use only in well-ventilated areas. When using do not eat, drink or smoke. Container must be kept tightly closed. Do not get in eyes, on skin, on clothing. Remove sources of ignition Conditions for safe storage, including any incompatibilities In original package, keep tightly closed in a dry and cool place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters None of the components have assigned exposure limits Suitable engineering parameters Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location Personal Protection Equipment General protection and hygiene applications. General protection and hygiene applications. Keep away from the foods, drinks and animal feed. Take off your dirty clothes directly. Wash your hands after handling. Keep away from contact eye and skin directly. Don t smoke. Page 3/7

4 Protection the body Eye-Face Protection Avoid contact with the skin and the eyes. Tightly fitting safety goggles, Safety glasses with side-shields compatible with EN Hand Protection Please take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Be aware that in daily use the durability of a chemical resistant protective glove can be notably shorter than the break through time measured according to EN 374, due to the numerous outside influences (e.g. temperature) Skin and body protection Body protection must be chosen based on level of activity and exposure. Protective suit should be durable for chemical and physical conditions Respiratory protection No personal respiratory protective equipment normally required. In inadequately ventilated areas, where workplace limits are exceeded, where unpleasant odors dexist or where aerosols are in use, or smoke and mist occur, use self-contained breathing apparatus or breathing apparatus with a type of filter or appropriate combined filter in compliance with EN Heat effects If the material heat-critical, the personal protective equipment must be chosen more carefully. The obligations around the existing legislation for the protection of the environment must be met in full. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless Liquid Odor Mild Freezing Point ph 6-10 Boiling Point 99 C (1,013 hpa) Flash Point Aqueous Solution; can't be detected up to the boiling point, neither by electro- nor gas ignition. Evaporation Rate Flammability (solid,gas) Vapor Pressure 35 hpa (20 C) (EU A4) 99 hpa (50 C) (EU A4) 119 hpa (55 C) (EU A4) Density 0,999 g/cm3 (20 C) Autoignition Temperature Explosive properties Page 4/7

5 10. STABILITY AND REACTIVITY Chemical stability : Material is stable under normal conditions. Possibility of hazardous reactions : Conditions to avoid : Do not freeze Incompatible materials to avoid : Strong Acids, Strong Bases Hazardous decomposition products : Measurements at temperatures above 150 C in presence of air (oxygen) have shown that small ampunts of formaldehyde are formed due to oxidative degradation. 11. TOXICOLOGICAL INFORMATION Aerosols of this product have a high inhalation toxicity potential. Therefore, when spraying this product and mixtures thereof with other components, exposure must be completely avoided. The use of respiratory equipment is mandatory for all spray applications. Eye irritation : Skin Irritation : Long term effect : 12. ECOLOGICAL INFORMATION Acute toxicity Oral : LD 50 (Rat) >2000 mg/kg Acute toxicity Dermal : LD 50 (rat) >2000 mg/kg Eco toxicity Data :. Mobility in Soil :. Bioaccumulative potential :. Other adverse effect : 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local, state and federal government regulations. All materials that come in contact with the product must either be set aside for recovery or disposed of as a hazardous substance/material. Do not let the product enter waters, waste water or soil. The raw material MSDSs are taken into consideration while preparing the document. Page : 5/7

6 14. TRANSPORT INFORMATION Not regulated. Special precautions for user: This product is not regarded as dangerous goods according to the national and international regulations on the transport of dangerous goods. Keep away from foodstuffs and animal feed. ADR/RID Land Transport Not dangerous goods Packaging Group: - UN No : REGULATORY INFORMATION Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: none Regulation (EC) No. 850/2004 on persistent organic pollutants: none Regulation (EC) No. 649/2012 Import and export of dangerous chemicals: none Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended: none Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use: 2-Propanol ,1-1,0% Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work.: none Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breast feeding.: none Directive 96/82/EC (Seveso III): on the control of major accident hazards involving dangerous substances: none 2-Propanol ,1-1,0% EU. Regulation No. 166/2006 PRTR (Pollutant Release and Transfer Registry), Annex II: Pollutants: none Directive 98/24/EC on the protection of workers from the risks related to chemical agents at work: 2-Propanol ,1-1,0% 2-Phenoxyethanol ,1-1,0% EU. REACH Candidate List of Substances of Very High Concern for Authorization (SVHC): Decamethylcyclopentasiloxane <=0,2999% Dodecamethylcyclohexasiloxane <=0,2999% Page 6/7

7 16. OTHER INFORMATION Full text of H-Statements referred to under sections 2 and Text of P-phrases mentioned in Section Key information source used in the safety data sheet The raw material MSDSs and national/international regulations are taken into consideration while preparing the document Abbreviations LC... (Lethal Concentration, 50%) LD (Lethal Dose, 50%) DNEL (Derived No-Effect Level) NOAEL (No observable adverse effect level) NOEL/NOEC (No Observed-effect level/concentration) EC (Effect concentration,... %) ADR :European Agreement Concerning the International Carriage of Dangerous Goods by Road IATA (International Air Transport Association) IMDG (International Maritime Dangerous Goods) Preparing and Revision Information Revision Number : - Revision Date : '- Prepared by; Name : Cansun Şura Fermancı Document Number : NBC Validity Date: Communication information : cfermanci@latro.com.tr General Using Information The information provided in this Safety Data Sheet is correct to the best of our knowledge information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. This safety datasheet only contains information relating to safety and does not replace any product information or product specification. Page 7/7