Murphy and Son Ltd SAFETY DATA SHEET. Section 1: Identification of the substance/mixture and of the company/undertaking

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1 Page: 1 Compilation date: 02/01/2013 Revision date: 22/01/2015 Revision No: 2 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: REACH registered name: CAS number: EINECS number: Product code: Synonyms: REACH ANNEX IV EXEMPTION CALPAN VITAMIN B Relevant identified uses of the substance or mixture and uses advised against Use of substance / mixture: Beverage Processing Aids and Other Usages 1.3. Details of the supplier of the safety data sheet Company name: Alpine Street Nottingham Nottinghamshire NG6 0HQ United Kingdom Tel: technical@murphyandson.co.uk 1.4. Emergency telephone number Emergency tel: (office hours only) Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CLP: 2.2. Label elements This product has no classification under CLP. Label elements: This product has no label elements Other hazards PBT: This product is not identified as a PBT/vPvB substance. Section 3: Composition/information on ingredients

2 Page: Substances Chemical identity: CAS number: EINECS number: Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Eye contact: Wash immediately with plenty of soap and water. For at Least 15 Minutes. If inflammation develops, receive medical attention. Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination. Ingestion: Wash out mouth with water. If a large amount has been swallowed, drink one or two glasses of water and put fingers in throat to induce vomiting. Seek medical attention if ill effect develops If unconscious, check for breathing and apply artificial respiration if necessary. If breathing is difficult, give oxygen. Inhalation: Move to fresh air in case of accidental inhalation of vapours. Persons developing hypersensitivity reactions must receive immediate medical attention. If breathing is difficult, give oxygen. If not breathing, give artificial respiration Most important symptoms and effects, both acute and delayed Skin contact: Eye contact: Ingestion: Inhalation: There may be irritation and redness at the site of contact. There may be irritation and redness. May cause digestive tract irritation. May cause respiratory irritation Indication of any immediate medical attention and special treatment needed Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Water spray. Dry chemical powder. Carbon dioxide Special hazards arising from the substance or mixture Exposure hazards: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In combustion emits toxic fumes of nitrogen oxides Advice for fire-fighters Advice for fire-fighters: As for all fires, evacuate personnel to safe area, remove the container to a safe place and fire fighters should use self-contained breathing equipment and protective clothing and extinguish from the windward. Section 6: Accidental release measures

3 Page: Personal precautions, protective equipment and emergency procedures Personal precautions: Evacuate the area immediately. Do not attempt to take action without suitable protective clothing - see section 8 of SDS Environmental precautions 6.3. Methods and material for containment and cleaning up Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Transfer to a suitable container. Wash the spillage site with large amounts of water Reference to other sections Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Avoid contact with skin, eyes and clothing. Do not breathe dust or fumes 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: 7.3. Specific end use(s) Specific end use(s): Store in an airtight container. Beverage Processing Aids and Other Usages Section 8: Exposure controls/personal protection 8.1. Control parameters Workplace exposure limits: DNEL/PNEC Values DNEL / PNEC 8.2. Exposure controls Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Colour: Odour: Evaporation rate: Oxidising: Solubility in water: Viscosity: Powder White Odourless Highly soluble Not applicable. Boiling point/range C: Not applicable. Melting point/range C: Flammability limits %: lower: upper: Flash point C: Part.coeff. n-octanol/water: Autoflammability C:

4 Vapour pressure: Not applicable. Relative density: ph: VOC g/l: Not applicable. Page: Other information Other information: Section 10: Stability and reactivity Reactivity Chemical stability Chemical stability: Possibility of hazardous reactions Conditions to avoid Conditions to avoid: Incompatible materials Materials to avoid: Stable under normal conditions. Heat. Flames. Sources of ignition. Oxidising agents Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In combustion emits toxic fumes of nitrogen oxides. Section 11: Toxicological information Information on toxicological effects Toxicity values: Route Species Test Value Units ORAL MUS LD10 10 g/kg Symptoms / routes of exposure Skin contact: Eye contact: Ingestion: Inhalation: Section 12: Ecological information Toxicity There may be irritation and redness at the site of contact. There may be irritation and redness. May cause digestive tract irritation. May cause respiratory irritation. Ecotoxicity values: Persistence and degradability

5 Page: Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment PBT identification: This product is not identified as a PBT/vPvB substance Other adverse effects Section 13: Disposal considerations Waste treatment methods Disposal operations: Dispose in a safe manner in accordance with local/national regulations. NB: regulations regarding disposal. Section 14: Transport information Transport class: The user's attention is drawn to the possible existence of regional or national This product does not require a classification for transport. Section 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has been carried out for the substance or the mixture by the supplier. Section 16: Other information Other information Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * indicates text in the SDS which has changed since the last revision. Legend to abbreviations: PNEC = predicted no effect level DNEL = derived no effect level LD50 = median lethal dose LC50 = median lethal concentration EC50 = median effective concentration IC50 = median inhibitory concentration dw = dry weight bw = body weight cc = closed cup oc = open cup MUS = mouse GPG = guinea pig

6 RBT = rabbit HAM = hamster HMN = human MAM = mammal PGN = pigeon IVN = intravenous SCU = subcutaneous SKN = skin DRM = dermal OCC = ocular/corneal PCP = phycico-chemical properties Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. Page: 6 [final page]

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