Pictograms GHS GHS. Symbol in the GHS pictogram. GHS Pictogram. hazard classes. Means. Flammable. Flame over circle. and peroxides.

Transcription

1 GHS Pictograms GHS Pictogram Symbol in the GHS pictogram GHS hazard classes Means Skull and crossbones Acute toxicity (for oral, skin and inhalation); skin corrosion; respiratory sensitizer Toxic Flame Flammable gases; flammable aerosols; flammable liquids; flammable solids; self-reactive substances and mixtures; pyrophoric liquids; pyrophoric solids; self-heating substances and mixtures; substances and mixtures which, in contact with water, emit flammable gases; organic peroxides Flammable Flame over circle Oxidising gases; oxidising liquids; oxidising solids Oxidising Exploding bomb Explosives; self-reactive substances and mixtures; organic peroxides Explosive

2 Corrosion Corrosive to metals; serious eye damage Corrosive Gas cylinder Compressed gas; liquefied gas; refrigerated liquefied gas; dissolved gas; Compressed gas Exclamation mark Skin irritation; eye irritation; skin sensitizer Harmful Environment Acute and chronic hazards to the aquatic environment Environmental hazards Health hazards Germ cell mutagenicity; carcinogenicity; reproductive toxicity; specific target organ toxicity single exposure; specific targett organ toxicity repeated exposure Health hazards 2

3 GHS HAZARD STATEMENTS INFORMATION Table A-.: Physical Hazards H-code () Hazard statement (2) Hazard classification () H200 Unstable explosive Unstable explosive H20 Explosive; mass explosion hazard Explosive division. H202 Explosive; severe projection hazard Explosive division.2 H20 Explosive; fire, blast or projection hazard Explosive division. H204 Fire or projection hazard Explosive division.4 H205 May mass explode in fire Explosive division.5 H220 Extremely flammable gas Flammable gas category H22 Flammable gas Flammable gas category 2 H222 Extremely flammable aerosol Flammable aerosol category H22 Flammable aerosol Flammable aerosol category 2 H224 Extremely flammable liquid and vapour Flammable liquid category H225 Highly flammable liquid and vapour Flammable liquid category 2 H226 Flammable liquid and vapour Flammable liquid category H227 Flammable liquid Flammable liquid category 4 H228 Flammable solid Flammable solid category Flammable solid category 2 H240 H24 H242 Heating may cause an explosion Heating may cause a fire or explosion Heating may cause a fire Self-reactive chemicals type A Organic peroxides type A Self-reactive chemicals type B Organic peroxides type B Self-reactive chemicals type C and D Self-reactive chemicals type E and F Organic peroxides type C and D Organic peroxides type E and F H250 Catches fire spontaneously if exposed to air Pyrophoric liquid category Pyrophoric solid category H25 Self-heating; may catch fire Self-heating chemicals category H252 Self-heating in large quantities; may catch fire Self-heating chemicals category 2

4 H-code () H260 H26 Hazard statement (2) In contact with water releases flammable gases which may ignite spontaneously In contact with water releases flammable gases Hazard classification () Chemicals which, in contact with water, emit flammable gas category Chemicals which, in contact with water, emit flammable gas category 2 and H270 May cause or intensify fire; oxidiser Oxidizing gas category H27 May cause fire or explosion; strong oxidiser Oxidizing liquid category H272 May intensify fire; oxidiser Oxidizing liquid category 2 Oxidizing liquid category H280 H28 Contains gas under pressure; may explode if heated Contains refrigerated gas; may cause cryogenic burns or injury Gases under pressure, compressed gas Gases under pressure, liquefied gas Gases under pressure, dissolved gas Gases under pressure, refrigerated liquefied gas H290 May be corrosive to metals Corrosive to metal category 4

5 H-code () H00 Table A-.2: Health Hazards Hazard statement (2) Fatal if swallowed 5 Hazard classification () Acute toxicity category (oral) Acute toxicity category 2 (oral) H0 Toxic if swallowed Acute toxicity category (oral) H02 Harmful if swallowed Acute toxicity category 4 (oral) H0 Can be harmful if swallowed Acute toxicity category 5 (oral) H04 May be fatal if swallowed and enters airways Aspiration hazard category H05 May be harmful if swallowed and enters airways Aspiration hazard category 2 H0 Fatal in contact with skin Acute toxicity category (dermal) Acute toxicity category 2 (dermal) H Toxic in contact with skin Acute toxicity category (dermal) H2 Harmful in contact with skin Acute toxicity category 4 (dermal) H May be harmful in contact with skin Acute toxicity category 5 (dermal) H4 Causes severe skin burns and eye damage Skin corrosion/irritation category (A/B/C) H5 Causes skin irritation Skin corrosion/irritation category 2 H6 Causes light skin irritation Skin corrosion/irritation category H7 May cause an allergic skin reaction Skin sensitization category H8 Causes serious eye damage Serious eye damage/eye irritation category H9 Causes serious eye irritation Serious eye damage/eye irritation category 2A H20 Causes eye irritation Serious eye damage/eye irritation category 2B H0 H Fatal if inhaled Toxic if inhaled Acute toxicity category (inhalation) Acute toxicity category 2 (inhalation) Acute toxicity category (inhalation) H2 Harmful if inhaled Acute toxicity category 4 (inhalation) H Can be harmful if inhaled Acute toxicity category 5 (inhalation) H4 May cause allergy or asthma symptoms or breathing difficulties if inhaled Respiratory sensitization category H5 May cause respiratory irritation toxicity-single exposure category H6 May cause drowsiness or dizziness toxicity-single exposure category H40 May cause genetic defects (state route of exposure Germ cell mutagenicity category (A/B)

6 H-code () H4 H50 H5 Hazard statement (2) if it is conclusively proven that no other routes of exposure cause the hazard) Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Hazard classification () Germ cell mutagenicity category 2 Carcinogenicity category (A/B) Carcinogenicity category 2 May damage fertility or the unborn child (state Reproductive toxicity category (A/B) H60 specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Suspected of damaging fertility or the unborn child H6 (state specific effect if known) (state route of Reproductive toxicity category 2 exposure if it is conclusively proven that no other routes of exposure cause the hazard) H62 May cause harm to breast-fed children Effect on or via lactation H70 H7 H72 H7 Causes damage to organs (or state all organs effected if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) May cause damage to organs (or state all organs effected if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Causes damage to organs through prolonged or repeated exposure May cause damage to organs prolonged or repeated exposure 6 toxicity-single exposure category toxicity-single exposure category 2 toxicity- repeated exposure category toxicity- repeated exposure category 2

7 Table A-.: Environmental Hazards H-code () Hazard statement (2) Hazard classification () H400 Very toxic to aquatic life Hazardous to the aquatic environment acute toxicity category H40 Toxic to aquatic life Hazardous to the aquatic environment acute toxicity category 2 H402 Harmful to aquatic life Hazardous to the aquatic environment acute toxicity category H40 H4 H42 H4 Very toxic to aquatic life with long lasting effects Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment chronic toxicity category Hazardous to the aquatic environment chronic toxicity category 2 Hazardous to the aquatic environment chronic toxicity category Hazardous to the aquatic environment chronic toxicity category 4 7

8 GHS PRECAUTIONARY STATEMENTS INFORMATION Code () P20 General precautionary statements (2) Table A-2.: Precautionary statements - Prevention Hazard class Hazard category () (4) Obtain special instructions before use. Explosives Unstable explosive Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 Conditions for use (5) P202 P20 P2 Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Reproductive toxicity 8 Effects on or via lactation Explosives Unstable explosive Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 Explosives Divisions.,.2,.,.4,.5 Flammable gases Flammable aerosols Flammable liquids, Flammable solids Self-reactive chemicals Types A, B, C, D, E, F Pyrophoric liquids Pyrophoric solids Organic peroxides Types A, B, C, D, E, F Manufacturer/supplier to specify applicable ignition source(s). Oxidising liquids, Specify to keep away from heat. Oxidising solids, Flammable aerosols

9 Code () P220 P22 General precautionary statements (2) Keep/Store away from clothing/ /combustible materials. Take any precaution to avoid mixing with combustibles/ Hazard class Hazard category P222 Do not allow contact with air. Pyrophoric liquids Pyrophoric solids P22 Keep away from any possible contact with water, because of violent reaction and possible flash fire. Conditions for use () (4) (5) Oxidising gases Manufacturer/supplier Self-reactive chemicals Types A, B, C, to specify incompatible D, E, F materials. Oxidising liquids Manufacturer/supplier to specify incompatible materials. specify to keep away from clothing as well as other incompatible materials. 2, Manufacturer/supplier to specify incompatible materials. Oxidising solids Manufacturer/supplier to specify incompatible materials. specify to keep away from clothing as well as other incompatible materials. 2, Manufacturer/supplier Oxidising solids Types A, B, C, D, E, F to specify incompatible materials. Oxidising liquids, Manufacturer/supplier Oxidising solids, to specify incompatible materials. Chemicals which, in contact with water, emit flammable gases P20 Keep wetted with Explosives Divisions., Manufacturer/supplier 9

10 Code () General precautionary statements (2) Hazard class () Hazard category Conditions for use (4) (5).2,.,.5 to specify appropriate material. if drying out increases explosion hazard, except as needed for manufacturing or operating processes (e.g. nitrocellulose). P2 Handle under inert gas. Chemicals which, in contact with water, emit flammable gases P22 Protect from moisture. Chemicals which, in contact with water, emit P2 P24 Keep container tightly closed. Keep only in original container.,, flammable gases Flammable liquids, Acute toxicity (inhalation), if product is volatile toxicity single exposure (respiratory tract Irritation) so as to generate hazardous atmosphere. toxicity single exposure (narcosis) Self-reactive chemicals Types A, B, C, D, E, F Organic peroxides Types A, B, C, D, E, F Corrosive to metals P25 Keep cool. Flammable liquids, Self-reactive chemicals Types A, B, C, D, E, F Self-heating chemicals 0

11 Code () General precautionary statements (2) Hazard class () Hazard category (4) Conditions for use (5) P240 P24 Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ / equipment. Organic peroxides Types A, B, C, D, E, F Explosives Divisions.,.2,., if the explosive is.4,.5 electrostatically sensitive. Flammable liquids, if electrostatically sensitive material is for reloading. if product is volatile so as to generate hazardous atmosphere. Flammable solids if electrostatically sensitive material is for reloading. Flammable liquids, Manufacturer/supplier to specify other equipment. Flammable solids Manufacturer/supplier to specify other equipment. if dust clouds can occur. P242 Use only non-sparking tools. Flammable liquids, P24 Take precautionary measures against static discharge. Flammable liquids, P244 Keep reduction valves free from grease and oil. Oxidising gases P250 Do not subject to grinding/shock/ /friction. Explosives Divisions.,.2,.,.4,.5 P25 Pressurized container: Do not Flammable aerosols Manufacturer/supplier to specify applicable rough handling.

12 Code () General precautionary statements (2) pierce or burn, even after use. Hazard class () Hazard category (4) Conditions for use (5) P260 P26 P262 P26 P264 Do not breathe dust/fume/gas/mist/ vapours/spray. Avoid breathing dust/fume/ gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing Avoid contact during pregnancy/ while nursing. Wash thoroughly after handling. Acute toxicity (inhalation) 2 Manufacturer/supplier to specify applicable conditions. toxicity single exposure toxicity repeated exposure Skin corrosion Reproductive toxicity A, B, C Effects on or via Specify do not breathe dusts or mists. lactation if inhalable particles of dusts or mists may occur during use. Acute toxicity (inhalation), 4 Manufacturer/supplier Respiratory sensitisation to specify applicable Skin sensitisation conditions. toxicity single exposure; (respiratory tract irritation) toxicity single exposure; (narcosis) Acute toxicity (dermal) Reproductive toxicity Effects on or via lactation Acute toxicity (oral),, 4 Manufacturer/supplier Acute toxicity (dermal) to specify parts of the Skin corrosion A, B, C body to be washed after

13 Code () P270 General precautionary statements (2) Do not eat, drink or smoke when using this product. Hazard class Hazard category Conditions for use () (4) (5) Skin irritation 2 handling Eye irritation 2 Reproductive toxicity Effects on or via lactation toxicity single exposure toxicity repeated exposure Acute toxicity (oral),, 4 Acute toxicity (dermal) Reproductive toxicity Effects on or via lactation P27 P272 P27 Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace Avoid release to the environment. toxicity single exposure toxicity repeated exposure Acute toxicity (inhalation),, 4 toxicity single exposure; (respiratory tract irritation) toxicity single exposure; (narcosis) Skin sensitisation Hazardous to the aquatic environment acute if this is not the intended use.

14 Code () P280 General precautionary statements (2) Wear protective gloves/protective clothing/eye protection/face protection. Hazard class Hazard category () (4) aquatic hazard Hazardous to the aquatic,, 4 environment chronic aquatic hazard Hazardous to the ozone layer Explosives Divisions.,.2,.,.4,.5 Conditions for use (5) Manufacturer/supplier to specify type of equipment. Specify face protection. Flammable liquids, Manufacturer/supplier to specify type of Flammable solids equipment. Specify protective gloves and eye/face protection. Self-reactive chemicals Types A, B, C, D, E, F Pyrophoric liquids Pyrophoric solids Self-reactive chemicals Chemicals which, in, contact with water, emit flammable gases Oxidising liquids, Oxidising solids, Organic peroxides Types A, B, C, D, E, F Acute toxicity (dermal),, 4 Manufacturer/supplier to specify type of equipment. Specify protective gloves/clothing. 4

15 Code () General precautionary statements (2) Hazard class Hazard category Conditions for use () (4) (5) Skin corrosion A, B, C Manufacturer/supplier to specify type of equipment. Specify protective gloves/clothing and eye/face protection. Skin irritation 2 Manufacturer/supplier Skin sensitisation to specify type of equipment. Specify protective gloves. Serious eye damage/eye irritation Manufacturer/supplier to specify type of equipment. Specify eye/face protection. P28 P282 Use personal protective equipment as required. Wear cold insulating gloves/face shield/eye protection. Wear fire/flame resistant/retardant clothing. Explosives Unstable explosive Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 Gases under pressure Refrigerated liquefied gas P28 Oxidising liquids Oxidising solids P284 Wear respiratory protection. Acute toxicity (inhalation) Manufacturer/supplier P285 In case of inadequate ventilation wear respiratory protection. to specify equipment. Respiratory sensitisation Manufacturer/supplier to specify equipment. 5

16 Table A-2.2: Precautionary statements - Prevention Code General precautionary statements Hazard class Hazard category Conditions for use P2 P22 P25 P40 Handle under inert gas. Protect from moisture. Chemicals which in contact with water, emit flammable gases, Keep cool. Protect from sunlight. Self-heating chemicals Table A-2.: Precautionary statements - Response Code General precautionary statements Hazard class Hazard category Conditions for use P0 IF SWALLOWED: Acute toxicity (oral),, 4 Skin corrosion/irritation A, B, C Aspiration Hazard P02 IF ON SKIN: Pyrophoric liquids Acute toxicity (dermal),, 4 Skin corrosion/irritation 2 Skin sensitisation P0 IF ON SKIN (or hair): Flammable liquids, Skin corrosion/irritation A, B, C P04 IF INHALED: Acute toxicity,, 4 (inhalation) Skin corrosion/irritation A, B, C Respiratory sensitisation toxicity single exposure; (respiratory tract irritation) toxicity single exposure; (narcosis) P05 IF IN EYES: Skin corrosion/irritation A, B, C 6

17 Serious eye damage/ eye irritation P06 IF ON CLOTHING: Oxidising liquids Oxidising solids P07 IF exposed: toxicity single exposure P08 IF exposed or concerned: Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 Reproductive toxicity Effects on or via lactation P09 P0 P P2 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. 2 toxicity single exposure Acute toxicity (oral), Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation A, B, C Serious eye damage/eye irritation Aspiration hazard Acute toxicity (inhalation) Respiratory sensitisation toxicity single exposure Acute toxicity (oral) 4 Acute toxicity (dermal), 4 7

18 Acute toxicity 4 (inhalation) toxicity single exposure; (respiratory tract Irritation) toxicity single exposure; (narcosis) P Get medical advice/attention. Skin corrosion/irritation 2, Serious eye 2 damage/eye irritation Skin sensitisation Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 Reproductive toxicity Effects on or via lactation P4 Get medical advice/attention if you feel unwell. toxicity repeated P5 Get immediate medical advice/attention. exposure Gases under pressure Refrigerated liquefied gas P20 P2 Specific treatment is urgent (see on this label). Specific treatment (see on this label). Acute toxicity (inhalation) 8.Reference to supplemental first aid instruction. if immediate administration of antidote is required Acute toxicity (oral),.reference to supplemental first aid instruction. if immediate administration of antidote is required Acute toxicity (inhalation) Reference to supplemental first aid instruction.

19 P22 Specific measures (see on this label). 9 if immediate specific measures are required. toxicity single exposure Reference to supplemental first aid instruction. if immediate measures are required. Skin sensitisation Reference to supplemental Skin corrosion/irritation A, B, C, 2 first aid instruction. manufacturer/supplier may specify a cleansing agent if appropriate. Acute toxicity (dermal),, 4 Reference to supplemental first aid instruction. if immediate measures such as specific cleansing agent is advised. P0 Rinse mouth. Acute toxicity (oral),, 4 Skin corrosion/irritation A, B, C P Do NOT induce vomiting. Skin corrosion/irritation A, B, C Aspiration hazard P2 If skin irritation occurs: Skin corrosion/irritation 2, P If skin irritation or rash occurs: Skin sensitisation P4 Immerse in cool water/wrap in wet Pyrophoric liquids bandages. Pyrophoric solids Chemicals which, in contact with water, emit flammable gases P5 Brush off loose particles from skin. Pyrophoric solids Chemicals which, in contact with water, emit flammable gases

20 P6 Thaw frosted parts with lukewarm water. Do not rub affected area. Gases under pressure Refrigerated liquefied gas P7 If eye irritation persists: Serious eye 2 damage/eye irritation P8 Remove contact lenses, if present Skin corrosion/irritation A, B, C and easy to do. Continue rinsing. Serious eye damage/ eye irritation P40 Remove victim to fresh air and Acute toxicity,, 4 keep at rest in a position comfortable for breathing. (inhalation) Skin corrosion/irritation A, B, C toxicity single exposure; (respiratory tract irritation) P4 P42 P50 P5 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Gently wash with plenty of soap and water. Rinse cautiously with water for several minutes. toxicity single exposure; (narcosis) Respiratory sensitisation Respiratory sensitisation Acute toxicity (dermal) Skin corrosion/irritation A, B, C Serious eye damage/eye irritation P52 Wash with plenty of soap and Acute toxicity (dermal), 4 water. Skin corrosion/irritation 2 Skin sensitisation P5 Rinse skin with water/shower. Flammable liquids, 20

21 P60 P6 P62 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Remove/Take off immediately all contaminated clothing. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Skin corrosion/irritation A, B, C Oxidising liquids Oxidising solids Flammable liquids, Acute toxicity (dermal), Skin corrosion/irritation A, B, C Skin corrosion/irritation 2 P6 Acute toxicity (dermal),, 4 Skin corrosion/irritation A, B, C Skin sensitisation P70 In case of fire: Explosives Divisions.,.2,.,.4,.5 Oxidising gases Flammable liquids, Flammable solids Self-reactive chemicals Types A, B, C, D, E, F Pyrophoric liquids Pyrophoric solids Chemicals which, in contact with water, emit flammable gases, Oxidising liquids, Oxidising solids, Oxidising liquids Oxidising solids P7 In case of major fire and large quantities: P72 Explosion risk in case of fire. Explosives Unstable explosives and Divisions.,.2,.,.4,.5 except if explosives are.4s AMMUNITION AND COMPONENTS THEREOF 2

22 P7 P74 P75 DO NOT fight fire when fire reaches explosives. Fight fire with normal precautions from a reasonable distance. Fight fire remotely due to the risk of explosion. Explosives 22 Unstable explosives and Divisions.,.2,.,.4,.5 P76 Stop leak if safe to do so. Oxidising gases Explosives Division.4 if explosives are.4s AMMUNITION AND COMPONENTS THEREOF Self-reactive chemicals Types A, B Oxidising liquids Oxidising solids P77 Leaking gas fire: Do not extinguish, Flammable gases unless leak can be stopped safely. P78 Use for extinction. Flammable liquids, Manufacturer/supplier Flammable solids to specify appropriate Self-reactive chemicals Types A, B, C, D, E, F media if water increases risk. Pyrophoric liquids Pyrophoric solids chemicals which, in, contact with water, emit flammable gases Oxidising liquids, Oxidising solids, P80 Evacuate area. Explosives Unstable explosives Explosives Divisions.,.2,.,.4,.5 Self-reactive chemicals Types A, B Oxidising liquids P8 Eliminate all ignition sources if safe to do so. Oxidising solids Flammable gases

23 P90 Absorb spillage to prevent material Corrosive to metals damage. P9 Collect spillage. Hazardous to the aquatic environment acute hazard Hazardous to the aquatic environment chronic hazard Table A.4: Precautionary statements - Response Code General precautionary statements Hazard class Hazard category Conditions for use P0 P0 P0 P2 P0 P0 P P02 P4 P02 P50 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN: Immerse in cool water/wrap in wet bandages. IF ON SKIN: Gently wash with plenty of soap and water. Acute toxicity (oral), Aspiration hazard Acute toxicity (oral) 4 Skin corrosion/irritation A, B, C Pyrophoric liquids Acute toxicity (dermal) 2

24 P02 P52 P0 P6 P5 P04 P40 P04 P4 P05 P5 P8 P06 P60 IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before Acute toxicity (dermal), 4 Skin corrosion/irritation 2 Skin sensitisation Flammable liquids, Skin corrosion/irritation Acute toxicity (inhalation) Skin corrosion/irritation toxicity single exposure; (respiratory tract irritation) toxicity single exposure; (narcosis) Respiratory sensitisation 24 A, B, C,, 4 A, B, C Skin corrosion/irritation A, B, C Serious eye damage/eye irritation Oxidising liquids Oxidising solids

25 P07 P removing clothes. IF exposed: Call a POISON CENTER or doctor/physician. toxicity single exposure P08 P IF exposed or concerned: Get medical advice/attention. Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 P09 P IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. Reproductive toxicity toxicity single exposure Effects on or via lactation 2 P2 P P P P5 P4 P7 P If skin irritation occurs: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/ attention. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. If eye irritation persists: Get medical advice/attention. Skin corrosion/irritation 2 Skin sensitisation Pyrophoric solids Chemicals which, in contact with water, emit flammable gases Serious eye damage/ eye irritation 2 P42 If experiencing respiratory symptoms: Call a POISON CENTER Respiratory sensitisation 25

26 P or doctor/physician. P70 P76 In case of fire: Stop leak if safe to do so. Oxidizing gases P70 P78 In case of fire: Use for extinction. Flammable liquids,...manufacturer/supplier to Flammable solids specify appropriate media. if water increases risk. Self-reactive chemicals Types A, B, C, D, E, F Pyrophoric liquids Pyrophoric solids Chemicals which, in, contact with water, emit flammable gases Oxidising liquids, Oxidising solids, P70 P80 In case of fire: Evacuate area. Explosives Divisions.,.2,.,.4,.5 P70 P80 P75 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Self-reactive chemicals Types A, B P7 In case of major fire and large Oxidising liquids 26

27 P80 P75 quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Oxidising solids Table A.2.5: Precautionary statements - Storage Code General precautionary statements Hazard class Hazard category Conditions for use P40 Store Explosives Unstable explosives and Divisions.,.2,.,.4,.5 in accordance with local/regional/national/ international regulations (to be specified). P402 Store in a dry place. Chemicals which, in contact with water, emit flammable gases P40 Store in a well-ventilated place., Flammable gases if product is volatile so as to Oxidising gases generate hazardous atmosphere. Gases under pressure Compressed gas 27 Liquefied gas Refrigerated Liquefied gas Dissolved gas Flammable liquids, Self-reactive chemicals Types A, B, C,D, E, F

28 Acute toxicity, (inhalation) toxicity single exposure; (respiratory tract irritation) toxicity single exposure; (narcosis) P404 Store in a closed container. Chemicals which, in, contact with water, emit flammable gases P405 Store locked up. Acute toxicity (oral), Acute toxicity (dermal), Acute toxicity, (inhalation) Skin corrosion/skin A, B, C irritation Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 toxicity single exposure toxicity single exposure; (respiratory tract irritation) toxicity single 28

29 P406 P407 Store in corrosive resistant/ container with a resistant inner liner. Maintain air gap between stacks/pallets. exposure; (narcosis) Aspiration hazard Corrosive to metals Manufacturer/supplier to specify other compatible materials. Self-heating chemicals P40 Protect from sunlight. Flammable aerosols Gases under pressure Compressed gas Liquefied gas Dissolved gas Self-heating chemicals P4 Store at temperatures not exceeding o C/ o F. Organic peroxides Types A, B, C, D, E, F Self-reactive chemicals Types A, B, C, D, E, F Manufacturer/supplier to specify temperature Organic peroxides Types A, B, C, D, E, F P42 Do not expose to temperatures exceeding 50 o C/22 o F. Flammable aerosols P4 Store bulk masses greater than kg/ lbs at temperatures not exceeding o C/ o F. Self-heating chemicals Manufacturer/supplier to specify mass and temperature. P420 Store away from other materials. Self-reactive chemicals Types A, B, C, D, E, F Self-heating chemicals 29

30 Organic peroxides Types A, B, C, D, E, F P422 Store contents under Pyrophoric liquids Manufacturer/supplier to specify appropriate Pyrophoric solids liquid or inert gas Table A.2.6: Precautionary statements - Storage Code General precautionary statements Hazard class Hazard category Conditions for use P402 P404 Store in a dry place. Store in a closed container. Chemicals which, in contact with water, emit flammable gases, P40 P2 Store in a well-ventilated place. Keep container tightly closed. Acute toxicity (inhalation) toxicity atmosphere. single exposure; (respiratory tract irritation), if product is volatile so as to generate hazardous P40 P25 Store in a well-ventilated place. Keep cool. toxicity single exposure; (narcosis) Flammable liquids, Self-reactive chemicals Types A, B, C, D, E, F P40 Protect from sunlight. Store in a well-ventilated place. Gases under pressure Compressed gas Liquefied gas 0

31 P40 Dissolved gas P40 P42 Protect from sunlight. Do not expose to temperatures exceeding 50 o C/22 o F. Flammable aerosols P4 P25 Store at temperatures not exceeding o C/ o F. Keep cool. Organic peroxides Types A, B, C, D, E, F Manufacturer/supplier to specify temperature. Table A.2.7: Precautionary statements - Disposal Code General precautionary statements Hazard class Hazard category Conditions for use P50 Dispose of contents/container to Explosives Unstable explosives and Divisions.,.2,.,.4,.5 Flammable liquids, in accordance with local/regional/national/ international regulation (to be specified). Self-reactive chemicals Types A, B, C, D, E, F Chemicals which, in, contact with water, emit flammable gases Oxidising liquids, Oxidising solids, Organic peroxides Types A, B, C, D, E, F

32 Acute toxicity (oral),, 4 Acute toxicity (dermal),, 4 Acute toxicity (inhalation) Skin corrosion/irritation A, B, C Respiratory sensitisation Skin sensitisation Germ cell mutagenicity A, B, 2 Carcinogenicity A, B, 2 Reproductive toxicity A, B, 2 toxicity single exposure toxicity single exposure; (respiratory tract irritation) toxicity single exposure; (narcosis) toxicity repeated exposure Aspiration hazard Hazardous to the 2

33 aquatic environment acute hazard Hazardous to the aquatic environment chronic hazard Hazardous to the ozone layer,, 4