SAFETY DATA SHEET PIG PLASTIC REPAIR PUTTY

Transcription

1 Revision Date SAFETY DATA SHEET According to Regulation (EU) No 453/2010 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Repair putty Details of the supplier of the safety data sheet Supplier New Pig Ltd. Hogs Hill Watt Place Hamilton International Technology Park Blantyre, G72 0AH, UK T: +44 ( 0) E: pigpen@newpig.com Web: Emergency telephone number +44 (0) Monday - Friday 08:00-17:00 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Physical and Chemical Hazards Human health Environment Classification (1999/45/EEC) The Full Text for all R-Phrases and Hazard Statements are Displayed in Section Label elements Label In Accordance With (EC) No. 1272/2008 No pictogram required. Supplemental label information 2.3. Other hazards EUH210 Safety data sheet available on request. Not Classified as PBT/vPvB by current EU criteria. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures TALC 30-60% CAS-No.: EC No.: Substance with a Community workplace exposure limit. Classification (67/548/EEC) 1 / 9

2 TITANIUM DIOXIDE 5-10% CAS-No.: EC No.: Substance with a Community workplace exposure limit. Classification (67/548/EEC) 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 5-10% CAS-No.: EC No.: Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Classification (67/548/EEC) Xn;R22 Xi;R36/38 QUARTZ < 1% CAS-No.: EC No.: STOT RE 2 - H373 Classification (67/548/EEC) Xn;R48/20. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move into fresh air and keep at rest. Ingestion Immediately rinse mouth and drink plenty of water ( ml). Get medical attention immediately! Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention Most important symptoms and effects, both acute and delayed Inhalation Unlikely route of exposure during normal use. Ingestion May cause discomfort if swallowed. Skin contact Prolonged skin contact may cause redness and irritation. Eye contact Irritation of eyes and mucous membranes Indication of any immediate medical attention and special treatment needed The severity of the symptoms described will vary dependant of the concentration and the length of exposure. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Use fire-extinguishing media appropriate for surrounding materials. 2 / 9

3 Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products When heated and in case of fire, irritating vapours/gases may be formed. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Avoid breathing fire vapours. Move container from fire area if it can be done without risk. Keep run-off water out of sewers and water sources. Dike for water control. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures For personal protection, see section Environmental precautions Do not allow ANY environmental contamination Methods and material for containment and cleaning up Wear necessary protective equipment. Ventilate well. Collect spillage with shovel, broom or the like and reuse, if possible. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Wash thoroughly after dealing with a spillage. Use appropriate containment to avoid environmental contamination Reference to other sections For personal protection, see section 8. See section 11 for more detailed information on health effects and symptoms. Collect and dispose of spillage as indicated in section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear protective clothing as described in Section 8 of this safety data sheet. Wear impervious gloves when mixing or handling uncured product. Read and follow manufacturer's recommendations. Avoid contact with skin and eyes. Avoid discharge to the aquatic environment Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Store below 35 C Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes QUARTZ WEL 0,1 mg/m3 TALC WEL 1 mg/m3 TITANIUM DIOXIDE WEL 10 mg/m3 WEL = Workplace Exposure Limit Exposure controls Engineering measures Provide adequate ventilation. Respiratory equipment Respiratory protection not required. If dust generated: Wear suitable respiratory protection. 3 / 9

4 Hand protection Protective gloves are recommended. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye protection Wear approved safety goggles. Other Protection Wear appropriate clothing to prevent reasonably probable skin contact. Hygiene measures Wash hands after handling. Wash contaminated clothing before reuse. When using do not eat, drink or smoke. Environmental Exposure Controls Avoid release to the environment. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Initial boiling point and boiling range ( C) Melting point ( C) Repair putty. Blue. Sulphur. Insoluble in cold and hot water. >150 C Relative density 1.79 Bulk Density Vapour density (air=1) Vapour pressure Evaporation rate Evaporation Factor ph-value, Conc. Solution ph-value, Diluted Solution Viscosity Solubility Value (G/100G H2O@20 C) Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) 9.2. Other information Not known. >93 C Sh CC (Setaflash closed cup). 4 / 9

5 SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not known. Hazardous Polymerisation Will not polymerise Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid No incompatible groups noted Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Nitrogen. Sulphur. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Skin Corrosion/Irritation: Irritating. Serious eye damage/irritation: Irritating. Respiratory or skin sensitisation: Germ cell mutagenicity: Genotoxicity - In Vitro Carcinogenicity: Carcinogenicity Reproductive Toxicity: Reproductive Toxicity - Fertility 5 / 9

6 Specific target organ toxicity - repeated exposure: Not classified as a specific target organ toxicant after repeated exposure. Inhalation Dust irritates the respiratory system, and may cause coughing and difficulties in breathing. Ingestion May cause discomfort if swallowed. Skin contact Prolonged contact may cause redness, irritation and dry skin. Eye contact Particles in the eyes may cause irritation and smarting. Toxicological information on ingredients. Toxicological information Information for: CAS (EC ). QUARTZ (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) > 2000 mg/kg Rabbit Acute Toxicity (Inhalation LC50) > 0.69 mg/l (dust/mist) Rat 4 hours 6 / 9

7 TITANIUM DIOXIDE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) 5.09 mg/l (dust/mist) Rat 4 hours Skin Corrosion/Irritation: Not irritating. Serious eye damage/irritation: Not Irritating. Respiratory or skin sensitisation: Skin sensitisation Buehler test: Guinea Pig Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Chromosome aberration: Negative. Carcinogenicity: Carcinogenicity NOAEL 5 mg/m3 Inhalation. Rat Reproductive Toxicity: Reproductive Toxicity - Fertility Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEC 50 mg/m3 Inhalation. Rat Not classified as a specific target organ toxicant after repeated exposure. TALC (CAS: ) Toxicological information No data available. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment Toxicity Acute Fish Toxicity Not considered toxic to fish. 7 / 9

8 Ecological information on ingredients. QUARTZ (CAS: ) Acute Toxicity - Fish Aquatic Toxicity is unlikely to occur. Acute Toxicity - Aquatic Invertebrates EL50 24 hours > 1000 mg/l Daphnia magna TITANIUM DIOXIDE (CAS: ) Acute Toxicity - Fish LC50 96 hours > 100 mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates LC50 48 hours > 100 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EC50 72 hours 61 mg/l Pseudokirchnerella subcapitata (Raphidocelis subcapitata) TALC (CAS: ) Acute Fish Toxicity No data available Persistence and degradability Degradability There are no data on the degradability of this product. Ecological information on ingredients. Degradability Not Applicable - Inorganic chemical. Degradability Not Applicable - Inorganic chemical. Degradability No data available. QUARTZ (CAS: ) TITANIUM DIOXIDE (CAS: ) TALC (CAS: ) Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Mobility in soil Mobility: The product is partly miscible with water and may spread in the aquatic environment Results of PBT and vpvb assessment Not Classified as PBT/vPvB by current EU criteria Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 8 / 9

9 General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Date Safety Data Sheet Status Risk Phrases In Full R22 R48/20 R36/38 NC Hazard Statements In Full H302 H315 H319 H373 EN_GB_SDS_S134.pdf Harmful if swallowed. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Irritating to eyes and skin. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause damage to organs <<Organs>> through prolonged or repeated exposure. 9 / 9