Safety Data Sheet. No WHMIS Controled Not a dangerous substance according to GHS.

Transcription

1 Safety Data Sheet Section 1- Product and Company Identification Product Name: DL Methionine Material Use: Animal Feed Distributed by: Pestell Minerals & Ingredients, 141 Hamilton Road New Hamburg, ON - N3A 2H1 Canada. Phone: Fax: Emergency Response: CANUTEC: (24 Hrs) 613: Section 2. Hazards Identification Emergency Overview WHMIS Classification: HMIS Classifications Wealth Hazard 0 Flammability: 0 Physical Hazard: 0 No WHMIS Controled Not a dangerous substance according to GHS. Potential Health Effects Inhalations: Skim: Eye: Ingestion: May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. May be harmful if swallowed Section 3. Composition/Information on Ingredients Synonymous: S)-2-Amino-4-(methylmercapto)butyric acid L-2-Amino-4-(methylthio)butanoic acid Formula: C5H11 NO2S Molecular Weight: g/mol L-Methionine CAS-No. EC-No. Index-No. Concentration Section 4. First Aid Measures Inhalation: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Skin Contact: Wash off with soap and plenty of water. Eye Contact: Flush eyes with water as a precaution. Ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water. SDS Methionine Page 1 of 6

2 Section 5. Fire Fighting Measures Conditions of flammability: Conditions of flammability Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment Wear self contained breathing apparatus for fire fighting if necessary. for firefighters Hazardous combustion Hazardous decomposition products formed under fire conditions. - Carbon oxides, products nitrogen oxides (NOx), Sulphur oxides Explosion data - sensitivity to No data available mechanical impact Explosion data - sensitivity to No data available static discharge Section 6. Accidental Release Measures Personal precautions Avoid dust formation. Avoid breathing vapors, mist or gas. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Sweep up and shovel. Keep in suitable, closed containers for disposal. Section 7. Handling and Storage Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Section 8. Exposure Controls/Personal Protection Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Immersion protection Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: > 480 min Material tested:dermatril (Aldrich Z677272, Size M) SDS Methionine Page 2 of 6

3 Splash protection Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: > 30 min Material tested:dermatril (Aldrich Z677272, Size M) data source: KCL GmbH, D Eichenzell, phone +49 (0) , test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Eye protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures General industrial hygiene practice. Specific engineering controls Use mechanical exhaust or laboratory fume hood to avoid exposure. Section 9. Physical and Chemical Properties Appearance Form Colour solid white Safety data ph Melting Melting point/range: 284 C (543 F) point/freezing point Boiling point Flash point Ignition temperature Autoignition temperature Lower explosion limit Upper explosion limit Vapour pressure Density Water solubility Partition coefficient: n-octanol/water SDS Methionine Page 3 of 6

4 Relative vapour density Odour Odour Threshold Evaporation rate Section 10. Stability and Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Conditions to avoid Materials to avoid Strong oxidizing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx), Sulphur oxides Other decomposition products - Section 11. Toxicological Information: Acute toxicity Oral LD50 LD50 Oral - rat - 36,000 mg/kg Remarks: Behavioral:Change in motor activity (specific assay). Skin and Appendages: Allergic (Multiple organ involvement) Anaphylaxix. Inhalation LC50 Dermal LD50 Other information on acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity SDS Methionine Page 4 of 6

5 Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Reproductive toxicity Teratogenicity Specific target organ toxicity - single exposure (Globally Harmonized System) Specific target organ toxicity - repeated exposure (Globally Harmonized System) Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects Additional Information RTECS: PD Section 12. Ecological Information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment SDS Methionine Page 5 of 6

6 Other adverse effects Section 13. Disposal Considerations Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. Section 14. Transport Information DOT (US) Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods Section 15. Regulatory Information WHMIS Classification Not WHMIS controlled. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. RISK OF SERIOUS DAMAGE TO EYES Section 16 Other Information Notice To Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 17 Validity Information Issuing Date: 08 January 2016 SDS Methionine Page 6 of 6

7