Version 2.0 MSDS Number: Revision Date: SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Skin-care, Biocidal product Recommended restrictions on use : For professional users only. 1.3 Details of the supplier of the safety data sheet Company : Kimberly-Clark Europe Limited 40 London Road Reigate Surrey RH2 9QP United Kingdom Telephone : Telefax : address Responsible/issuing person : sdscontact@kcc.com 1.4 Emergency telephone number This telephone number is available during office hours only GMT SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Eye irritation, Category 2 H319: Causes serious eye irritation. Classification (67/548/EEC, 1999/45/EC) Highly flammable R11: Highly flammable. 1 / 11

2 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word : Danger Hazard statements : H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. Precautionary statements : Prevention: P210 P233 Keep away from open flames/hot surfaces. - No smoking. Keep container tightly closed. 2.3 Other hazards This product is a mixture. Health hazard information is based on its components. SECTION 3: Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical Name CAS-No. EC-No. Registration number propan-2-ol Ethanol WEL substance : Glycerol Classification (67/548/EEC) F; R11 Xi; R36 R67 For explanation of abbreviations see section 16. Classification (REGULATION (EC) No 1272/2008) Flam. Liq.2; H225 Eye Irrit.2; H319 STOT SE3; H336 F; R11 Flam. Liq.2; H225 Eye Irrit.2; H319 Concentration (%) < 10 >= 50 - <= 100 < 10 SECTION 4: First aid measures 4.1 Description of first aid measures General advice : No hazards which require special first aid measures. If inhaled In case of skin contact : Not required under normal use. : No hazards which require special first aid measures. 2 / 11

3 In case of eye contact If swallowed : Immediately flush eye(s) with plenty of water. : If large quantities of this material are swallowed, call a physician immediately. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : No hazards which require special first aid measures. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : No hazards which require special first aid measures. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Highly flammable liquid and vapour. Hazardous combustion products : Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). 5.3 Advice for firefighters Special protective equipment for firefighters Further information : In the event of fire, wear self-contained breathing apparatus. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Ensure adequate ventilation. Remove all sources of ignition. Material can create slippery conditions. 6.2 Environmental precautions Environmental precautions : No special environmental precautions required. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece). 3 / 11

4 6.4 Reference to other sections For personal protection see section 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion Hygiene measures : Keep away from fire (No Smoking). Take precautionary measures against static discharges. : Keep away from sources of ignition - No smoking. : Handle in accordance with good industrial hygiene and safety practice. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep away from sources of ignition - No smoking. Keep containers tightly closed in a dry, cool and well-ventilated place. Other data : No decomposition if stored and applied as directed. 7.3 Specific end use(s) Specific use(s) : Skin-care Biocidal product SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type (Form Control parameters Basis of exposure) Ethanol TWA 1,000 ppm 1,920 mg/m3 GB EH40 Further information Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used propan-2-ol TWA 400 ppm GB EH mg/m3 propan-2-ol STEL 500 ppm GB EH40 1,250 mg/m3 Glycerol TWA (Mist) 10 mg/m3 GB EH40 Further information Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used 8.2 Exposure controls Personal protective equipment Eye protection : Not required under normal use. 4 / 11

5 Skin and body protection Respiratory protection Protective measures : Not required under normal use. : Not required under normal use. : No special protective equipment required. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour Odour : milky : alcohol-like ph : 5.0 Flash point : 13 C Method: closed cup Upper explosion limit Lower explosion limit Vapour pressure : 19.0 %(V) : 2.0 %(V) : hpa Relative vapour density : 1.6(Air = 1.0) Relative density : Solubility(ies) Water solubility : completely soluble 9.2 Other information No data available SECTION 10: Stability and reactivity 10.1 Reactivity Stable under recommended storage conditions Chemical stability No decomposition if used as directed Possibility of hazardous reactions Hazardous reactions : No hazards to be specially mentioned Conditions to avoid 5 / 11

6 Conditions to avoid : Heat, flames and sparks Incompatible materials Materials to avoid : No information available Hazardous decomposition products Hazardous decomposition : Stable under recommended storage conditions. products SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity propan-2-ol: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Ethanol: Acute oral toxicity Acute oral toxicity Acute dermal toxicity : LD50 Oral (Rat): 5,840 mg/kg : LC50 (Rat): ppm : LD50 Dermal (Rabbit): 12,800 mg/kg : LD50 (Rat, female): 15,000 mg/kg : LD50 Oral (Mouse, male): 23,000 mg/kg : LD50 Dermal (Guinea pig, male and female): 56,750 mg/kg Skin corrosion/irritation Remarks: According to the classification criteria of the European Union, the product is not considered as being a skin irritant. Species: Rabbit Exposure time: 24 h Result: No skin irritation Serious eye damage/eye irritation Species: Rabbit Exposure time: 16 min Method: Draize Test 6 / 11

7 Result: Severe eye irritant Remarks: Contact with eyes may cause irritation. Species: Rabbit Exposure time: 20 s Result: No eye irritation Respiratory or skin sensitisation Remarks: Based on available data, the classification criteria are not met. Germ cell mutagenicity Germ cell mutagenicity- Assessment : Contains no ingredient listed as a mutagen Genotoxicity in vitro : Method: OECD Test Guideline 482 Result: negative Carcinogenicity Carcinogenicity - Assessment : Contains no ingredient listed as a carcinogen Species: Rat, (male and female) Application Route: Oral Exposure time: 24 month(s) Frequency of Treatment: 1 daily Reproductive toxicity Reproductive toxicity - Assessment : Contains no ingredient listed as toxic to reproduction Effects on foetal development : Test Type: Two-generation study Species: Rat, male and female Application Route: Oral 7 / 11

8 Dose: 2000 milligram per kilogram Frequency of Treatment: 1 daily STOT - single exposure Remarks: No data available STOT - repeated exposure Remarks: No data available Aspiration toxicity May be harmful if swallowed and enters airways. Further information Remarks: Health injuries are not known or expected under normal use. SECTION 12: Ecological information 12.1 Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae : Remarks: No information available. : Remarks: No information available. : Remarks: No information available. propan-2-ol: Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Ethanol: Toxicity to fish Toxicity to daphnia and other : LC50 : 9,640 mg/l Exposure time: 96 h : EC50 : 10,000 mg/l Exposure time: 24 h : LC50 (Pimephales promelas (fathead minnow)): 14.2 g/l Exposure time: 96 h Test Type: flow-through test : EC50 (Ceriodaphnia dubia (water flea)): 5,012 mg/l 8 / 11

9 aquatic invertebrates Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Exposure time: 48 h Test Type: static test : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Test Type: static test : LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h GLP: see user defined free text : EC50 : 1,955 mg/l Exposure time: 48 h 12.2 Persistence and degradability Biodegradability : Remarks: Expected to be biodegradable Biodegradability : Result: Readily biodegradable 12.3 Bioaccumulative potential Bioaccumulation : Remarks: No information available Mobility in soil Mobility : Remarks: No information available Results of PBT and vpvb assessment Assessment : Based on available data, the classification criteria are not met Other adverse effects Additional ecological information : We have no quantitative data concerning the ecological effects of this product. SECTION 13: Disposal considerations 13.1 Waste treatment methods 9 / 11

10 Product Contaminated packaging : Dispose of in accordance with local regulations. : Dispose of as unused product. Do not re-use empty containers. SECTION 14: Transport information 14.1 UN number ADR : UN 1987 IMDG : UN 1987 IATA : UN UN proper shipping name ADR IMDG IATA 14.3 Transport hazard class(es) : ALCOHOLS N.O.S (Ethanol, Isopropanol) : ALCOHOLS N.O.S (Ethanol, Isopropanol) : Alcohols N.O.S (Ethanol, Isopropanol) ADR : 3 IMDG : IATA : 14.4 Packing group ADR Packing group : II Classification Code : F1 Labels : 3 IMDG Packing group : II IATA Packing group 14.5 Environmental hazards ADR Environmentally hazardous IMDG Marine pollutant : II : no : yes 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 10 / 11

11 Remarks : No information available. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Quantity 1 Quantity 2 7b Highly flammable 5,000 t 50,000 t The components of this product are reported in the following inventories: REACH : This mixture contains only ingredients which have been subject to a pre-registration according to Regulation (EC) No. 1907/2006 (REACH) Chemical Safety Assessment No information available. SECTION 16: Other information Full text of R-Phrases R11 R36 R67 Full text of H-Statements H225 : Highly flammable. : Irritating to eyes. : Vapours may cause drowsiness and dizziness. : Highly flammable liquid and vapour. Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 11 / 11