Safety data sheet. according to 1907/2006/EC, Article 31. Printing date Revision:

Transcription

1 Page 1/6 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the preparation Auxiliary for manufacture of dental prothesis Details of the supplier of the safety data sheet Manufacturer/Supplier: Heraeus Kulzer GmbH Grüner Weg 11, D Hanau Tel.: Informing department: Fax: msds@kulzer-dental.com Emergency telephone number: Emergency CONTACT (24-Hour-Number):K GmbH +49 (0) * 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R65: Harmful: may cause lung damage if swallowed. Xi; Irritant R38: Irritating to skin. F; Highly flammable R11: Highly flammable. N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67: Vapours may cause drowsiness and dizziness. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. Label elements Labelling according to EU guidelines: The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV) Code letter and hazard designation of product: Xn Harmful F Highly flammable N Dangerous for the environment Risk phrases: 11 Highly flammable. 38 Irritating to skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. (Contd. on page 2)

2 Page 2/6 (Contd. of page 1) 67 Vapours may cause drowsiness and dizziness. Safety phrases: 9 Keep container in a well-ventilated place. 16 Keep away from sources of ignition - No smoking. 23 Do not breathe vapour. 24 Avoid contact with skin. 33 Take precautionary measures against static discharges. 43 In case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water. Other hazards - Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description: - Dangerous components: CAS: Naphtha (petroleum), hydrotreated light EINECS: CAS: EINECS: Reg.nr.: xxxx Xn R65 ethanol F R11 Additional information For the wording of the listed risk phrases refer to section 16. > 90% < 1% * 4 First aid measures Description of first aid measures After inhalation Supply fresh air; consult doctor in case of symptoms. After skin contact Instantly wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. After eye contact Rinse opened eye for several minutes under running water. Call a doctor immediately. After swallowing Do not induce vomiting; instantly call for medical help. Information for doctor Most important symptoms and effects, both acute and delayed Headache Dizziness Unconsciousness Sickness Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Firefighting measures Extinguishing media Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents Water. Special hazards arising from the substance or mixture Can form explosive gas-air mixtures. Carbon monoxide (CO) (Contd. on page 3)

3 Page 3/6 Advice for firefighters Protective equipment: Wear self-contained breathing apparatus. Wear full protective suit. Additional information - (Contd. of page 2) * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Prevent material from reaching sewage system, holes and cellars. Methods and material for containment and cleaning up: Absorb with liquid-binding material (diatomite, universal binders, for small amounts tissues). Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections See Section 8 for information on personal protection equipment. - 7 Handling and storage Handling Precautions for safe handling Keep containers tightly sealed. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and containers: Store in cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Store in cool, dry conditions in well sealed containers. Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with critical values that require monitoring at the workplace: ethanol OES () Long-term value: 1920 mg/m³, 1000 ppm Additional information: The lists that were valid during the compilation were used as basis. Exposure controls Personal protective equipment General protective and hygienic measures Keep away from foodstuffs, beverages and food. Wash hands during breaks and at the end of the work. Do not inhale gases / fumes / aerosols. (Contd. on page 4)

4 Page 4/6 (Contd. of page 3) Breathing equipment: Not neccessary with efficient local exhaust. If exposition to vapours is possible, use breathing protective mask (filter A). Protection of hands: Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. For the permanent contact of a maximum of 15 minutes gloves made of the following materials are suitable: Nitrile rubber, NBR Butyl rubber, BR Eye protection: Safety glasses Body protection: Light weight protective clothing * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Colour: Colourless Smell: Benzen-like Change in condition Melting point/melting range: <-50 C Boiling point/boiling range: 60 C Flash point: -20 C Ignition temperature: 260 C Self-inflammability: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/ vapour mixtures is possible. Critical values for explosion: Lower: 1.2 Vol % Upper: 7 Vol % Steam pressure at 20 C: 133 hpa Density at 20 C g/cm³ Solubility in / Miscibility with Water at 20 C: 0.01 g/l Other information No further relevant information available. 10 Stability and reactivity Reactivity Chemical stability Conditions to be avoided: No decomposition if used and stored according to specifications. Possibility of hazardous reactions No dangerous reactions known Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. (Contd. on page 5)

5 Page 5/6 Hazardous decomposition products: None (Contd. of page 4) * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Naphtha (petroleum), hydrotreated light Oral LD50 >6000 mg/kg (rat) Dermal LD50 >3000 mg/kg (rab) Inhalative LC50/4 h >60 mg/l (rat) Primary irritant effect: on the skin: Irritant for skin and mucous membranes. on the eye: No irritant effect. Sensitization: No sensitizing effect known. Additional toxicological information: Irritant * 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Do not allow product to reach ground water, water bodies or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. European waste catalogue chemicals consisting of or containing dangerous substances Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. * 14 Transport information UN-Number ADR, IMDG, IATA 1208 (Contd. on page 6)

6 Page 6/6 (Contd. of page 5) UN proper shipping name ADR 3295 HYDROCARBONS, LIQUID, N.O.S. (vapor pressure at 50 C at most 110 kpa) (Naphtha (petroleum), hydrotreated light) IMDG, IATA HEXANES Transport hazard class(es) ADR Class 3 (F1) Flammable liquids. Label 3 IMDG, IATA Class 3 Flammable liquids. Label 3 Packing group ADR, IMDG, IATA II Environmental hazards: Marine pollutant: No Special precautions for user Warning: Flammable liquids. Kemler Number: 33 EMS Number: F-E,S-D Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: - Not applicable. * 15 Regulatory information Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases R11 Highly flammable. R65 Harmful: may cause lung damage if swallowed. * Data compared to the previous version altered.